Oxygen mobility in Bi:Sr:Ca:Cu:O ceramic measured using anelastic relaxation methods

Since the discovery of YBaCuO, experiments have shown that its superconducting properties are strongly affected by the oxygen content. More recently, anelastic relaxation measurements in La2CuO4+δ, showed that the decrease in the oxygen content can be related to two events. One is the decrease in mobility between two adjacent CuO planes, and the other is the increase in the number of tilting patterns of the CuO6 octahedra. In the case of the bismuth-based ceramic, it is known that the oxygen content, within some limits, does not affect its superconducting properties. In order to evaluate the mobility and the effect of the oxygen content on this material we have prepared BSCCO ceramic and tested regarding its internal friction and electrical resistivity as a function of the temperature while the oxygen content was being reduced by a sequence of vacuum annelaing at 620 K. The samples were prepared in the Bi:Sr:Ca:Cu = 2212 and 2223 proportion, using powder obtained by the sol-gel route and conventional solid state reaction. The anelastic relaxation measurements were performed using a torsion pendulum operating with frequency about 15-35 Hz between 77 to 700 K. The diffraction pattern of the as sintered and the vacuum annealed material were also presented. The results have shown complex anelastic relaxation structures that were associated to the jump of interstitial oxygen atoms between two adjacent CuO planes. The vacuum annealing showed to be deleterious to the critical temperature of the superconducting ceramic.

Oxygen Interstitial Dynamics in Bi(2)Sr(2)CaCu(2)O(8+delta) Oxides Measured by Mechanical Spectroscopy

Many researchers became interested in the discovery of Bi(2)Sr(2)CaCu(2)O(8+delta) oxides with critical temperature of around 80 K. It is known that the critical temperature is related to the CuO2 planes of the material. For this reason, the study of the interstitial oxygen in these oxides is of great relevance. The samples were prepared by means of conventional solid state reactions, through the stoichiometric mixture of precursory powders. After the sinterization, the samples were submitted to measurements of density, electrical resistivity, x-ray diffraction, scanning electron microscopy and energy dispersion spectroscopy, with the objective of performing their characterization. The measurements of mechanical spectroscopy were performed by a torsion pendulum. The results show three relaxation processes in the temperature range of 200 and 700 K, with activation energy of approximately 0.9 eV, which has been attributed to the dynamics of the interstitial oxygen present in the material.

Métodos geoelétricos aplicados ao diagnóstico ambiental subsuperficial do Cemitério Municipal de Rio Claro, SP

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Variação da resistividade elétrica para três solos não saturados

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Estudo geofísico em aterro controlado disposto sobre rochas fraturadas

Geophysical survey is an important method for investigation of contaminated areas used in the characterization of contrasting physical properties in the presence of pollutants. This work applied the geophysical methods of Electrical Resistivity and Self Potential in waste landfill, located in Caçapava do Sul city, RS. The landfill is located over fractured metamorphic rocks. Eight lines of electrical profiling with 288 measures of self potential were done. In addition, 83 measurements of direction and dip of fractures were taken. The application of spontaneous potential method permitted to detect the direction of groundwater flow. The electrical resistivity measurements allowed the identification of low-intensity anomalies associated with the presence of leachate. There is a relationship between anomalous zones and the directions of fractures.

Monitoramento da atenuação natural de álcool etílico hidratado combustível em escala laboratorial por meio de métodos geofísicos

Currently has few studies today concerning the behavior of the ethyl alcohol hydrated combustible in the geological environment, results of eventual spill or leaks in a wide transport chain and distribution. This work discusses the results of an experiment in laboratorial scale, that involves the monitoring of alterations in physical properties a simulate leak of alcohol in a tank with sand saturated in water, during 4920 hours. Are applied electrical resistivity, induced polarization and spontaneous potential geophysical methods. The electric resistivity is clearly correlating to the ethanol degradation pattern. The chargeability demonstrated sensibility to this pattern, while the natural electric potential revealed direct association with the oscillations of groundwater level. The variability of the physical parameters monitoring probable control for ethanol degradation process in environment study.

Análise das relações entre parâmetros geolétricos e vazões para o aquífero livre de Caçapava do Sul - RS

The geophysical methods may be employed in aquifer system studies, as determination of groundwater level, soil/rock contact, beyond estimative of the aquifer thickness horizon. The geoeletric methods are particularly relevant in evaluations of the oilfields systems, due to directs relations between porosity and electrical resistivity, which allow inferences about oil and gas production. The indirect estimative of the productions in free aquifers system is something complex before of the diverse variables responsible for factors or physical phenomena, as clays minerals, which conditioned the physical parameters by electric geophysical methods. This paper present analyzed correlation among electrical resistivity, chargeability and direct measure flow in shallow wells, for determination of statistical relationships between parameters and evaluation of the geological constraints evolved. The study count with the 23 shallow wells located in free aquifer, constituted by alteration materials of the granites localized in Caçapava do Sul (RS). The geophysical data are acquired by vertical electric sounding in Schlumberger array. The correlations between electrical resistivity and flow, chargeability and flow, thickness of the soil/saprolite and flow indicated relationships between physical and hydrogeologic parameters, with variations conditioned by factors as porosity, permeability, besides intrinsic geological heterogeneities such soil variable thickness and rock fragments with several alteration degrees.

Investigação geofísica em aterro municipal de resíduos sólidos domiciliares, Cordeirópolis, Brasil

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Al2O3 Obtained through resistive evaporation for use as insulating layer in transparent field effect transistor

Alumina thin films have been obtained by resistive evaporation of Al layer, followed by thermal oxidation achieved by annealing in appropriate atmosphere (air or O2-rich), with variation of annealing time and temperature. Optical and structural properties of the investigated films reveal that the temperature of 550°C is responsible for fair oxidation. Results of surface electrical resistivity, Raman and infrared spectroscopies are in good agreement with this finding. X-ray and Raman data also suggest the crystallization of Si nuclei at glass substrate-alumina interface, which would come from the soda-lime glass used as substrate. The main goal in this work is the deposition of alumina on top of SnO2 to build a transparent field-effect transistor. Some microscopy results of the assembled SnO2/Al2O3 heterostructure are also shown.

Investigação das propriedades ópticas, morfológicas e elétricas da heterojunção SnO2: Ce3+/ GaAs

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Identificação de cavidades naturais por meio de eletrorresistividade na região de São Pedro (SP)

The scope of this work is the study of natural cavities in gullies through geophysics. The studied area is located in the city of São Pedro (SP) more precisely in the gully of Tucunzinho. The historic of the area shows that, since the 60s there were problems with the high rate of erosion in the gully. In addition to increased erosion, there is the appearance of cavities inside responsible for rebates, aggravating the situation. Geophysical methods have been successfully applied in environmental studies since they are noninvasive, are fast and relatively inexpensive. In order to better understand the context of formation of the pipes in relation to local geology, three arrangements were compared for the method of Electrical Resistivity, Schlumberger, Wenner and Dipole-dipole. Then, it was possible to determine which one is the best for this type of study. According to the data obtained in the field, the Schlumberger array presents more consistent results in relation to the erosive context analyzed

Análiseda percolação de água em barragem de terra pelo método da eletrorresistividade

Interventions in nature made by man are very common since the beginnings of human history, especially in the case regarding the storage of water. The construction of dams have been and still are fundamental in maintaining human life due to the vital importance that water plays. The size of these structures vary according to need, such as water catchment, fish-farming or electricity generation. Embankment dams are the most common type of these structures. Can be defined as dams natural material obtained from loan chambers located near the dam site. This type of barrier may be divided into earth dams and rockfill dams. The study area covers an earth dam located in Cordeirópolis (SP) and is essentially composed of diabases altered soil of the Serra Geral Formation of the Paraná Basin. With the aid of geophysics, more specifically of the Electrical Resistivity method, the aim is to check any water infiltration zones in the dam's body. Given the risks associated with water seepage in earth dams, that may generate breakdown structures, erosion, and consequently accidents and / or harmful factors in the nearby areas. One of the main structural problems married by water infiltration is the possible generation of pipes that could jeopardize the dam structure. This work aims to contribute towards the evaluation of the effectiveness of using an indirect technique of research and monitoring in aid to direct research techniques such as piezometers and drive stakes. The results are presented in the form of 2D and 3D geophysical models, the analysis shows a low resistivity zone with typical values of the presence of humidity originating upstream of the dam and downstream bottleneck trend, that are the basis for interpretation by percolation or not water in the dam

Identificação de cavidades em voçoroca por meio da aplicação do método geofísico da eletrorresistividade

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Avaliação de contaminação com óleo diesel por meio dos métodos de Eletrorresistividade e Polarização Induzida em Santa Ernestina-SP

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Análise de integridade física de barragens de terra a partir da integração do método geofísico da eletrorresistividade com ensaios geotécnicos

Pós-graduação em Geociências e Meio Ambiente - IGCE