Degradation of dipyrone via advanced oxidation processes using a cerium nanostructured electrocatalyst material

This work studied the degradation of dipyrone, via electrochemical processes and via electro-Fenton reaction using a 4% CeO2/C gas diffusion electrode (GDE) prepared via modified polymeric precursor method. This material was used to electrochemically generate H2O2 through oxygen reduction. The mean crystallite sizes estimated by the Scherrer equation for 4% CeO2/C were 4 nm for CeO2-x (0 4 4) and 5 nm for CeO2 (1 1 1) while using transmission electron microscopy (TEM) the mean nanoparticle size was 5.4 nm. X-ray photoelectron spectroscopy (XPS) measurements revealed nearly equal concentrations of Ce(III) and Ce(IV) species on carbon, which contained high oxygenated acid species like CO and OCO. Electrochemical degradation using Vulcan XC 72R carbon showed that the dipyrone was not removed during the two hour electrolysis in all applied potentials by electro-degradation. Besides, when the Fenton process was employed the degradation was much similar when using cerium catalysts but the mineralization reaches just to 50% at -1.1 V. However, using the CeO2/C GDE, in 20 min all of the dipyrone was degraded with 26% mineralization at -1.3 V and when the Fenton process was employed, all of the dipyrone was removed after 5 min with 57% mineralization at -1.1 V. Relative to Vulcan XC72R, ceria acts as an oxygen buffer leading to an increase in the local oxygen concentration, facilitating H2O2 formation and consequently improving the dipyrone degradation © 2013 Elsevier B.V. All rights reserved.

A ressonância magnética no estudo da desintegração de comprimidos marcados com açaí (Euterpe oleracea)

Pós-graduação em Biologia Geral e Aplicada - IBB

Efeitos da matéria orgânica sobre óxidos de ferro em um latossolo vermelho

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Avaliação de extratores químicos na determinação de silício disponível em solos cultivados com cana-de-açúcar

Pós-graduação em Agronomia (Energia na Agricultura) - FCA

Hibridos siloxano-polímero no comportamento hidrofilico de diferentes materiais

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Estudo da ação de nanopartículas magnéticas de ferro no câncer oral

Pós-graduação em Genética - IBILCE

Identificação de pigmentos em artefatos arqueológicos via espectroscopia Micro-Raman

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Desenvolvimento de metodologias eletroanalíticas para determinação de potássio e fósforo em biodiesel

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Utilização do método de Taguchi na modelagem e otimização de vazios relacionados à solidificação em processo de fundição de aço ABNT 1030

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Estudo da redução fotocatalítica e fotoeletrocatalítica de 'CO IND. 2' em meio aquoso sobre 'CU'/'CU IND. 2 'O'', 'TI' 'O IND. 2'/'PT', 'CU''NB' 'O IND. 3' - 'CU''O' e 'CU IND. 0,85''ZN IND. 0,15''NB IND. 2''O IND.6' como catalisadores para formação de metanol

Pós-graduação em Química - IQ

Nanopartículas magnéticas de 'FE''CO'@'AU': preparação, caracterização e funcionalização com complexo de 'RU'(II) luminescente

Pós-graduação em Química - IQ

Atividade antibacteriana de cimentos de ionômero de vidro modificados por nanopartículas de óxido de zinco

Pós-graduação em Odontologia - FOAR

Litofácies e relações estratigráficas da formação Aquidauana no nordeste da Bacia do Paraná - São Sebastião do Paraíso (MG)

The Aquidauana Formation is characterized by sandstones of variable granulation, mudstones and diamectites abundant in clay, typical colors like brick red (vermelho tijolo) of glacial, fluvial and lacustrine origin. It’s chronostratigraphic equivalent to the Itarará group from the Neo Carboniferous age, that under the exploratory view, such units represent important intervals in the basin, occurring together with them minerals as well as energy resources as petroleum, underground water and coal – what requires a great paleogeography and stratigraphy knowledge for its exploration. By gathering information from the columnar sections of the area, it was possible to characterize the sedimentary facies, the stacking pattern as well as the association. It was also made an attempt of stratigraphic correlation, which showed great difficulties since glacial environments present a great lateral discontinuity of the facies besides the complex relationship process of formation. As a result, it was obtained 8 sedimentary facies, the lateral and vertical relations and genesis process. It is proposed that the sedimentary environment in the study area is the fluvio glacial, characterized by alluvial systems formed by defrosted water which transport the sediments that are deposited in plains in front of the glacier (distal outwash). Petrographic thin section analysis showed that the transportation process was ineffective. The grains present punctual to lobular contacts, characterizing good porosity and permeability to the rock, varying these qualities according to more or less existence of matrix. The presence of Iron Oxide deposited between the recrystallization border and feldspathic mineral indicates that this rock has possibly presented a primary rubefaction, intensified by alkaline fluid percolation

Marginal deterioration of the silicone for facial prosthesis with pigments after effect of storage period and chemical disinfection

The failure of facial prostheses is caused by limitations in the properties of existing materials, especially flexibility and durability. Therefore, this study evaluated the marginal deterioration of a silicone used for fabrication of facial prostheses (Silastic MDX4-4210, Dow Corning Corporation, Midland, MI, USA) according to the influence of artificial aging, daily disinfection, and 2 types of pigmentation. Thirty specimens were fabricated and subdivided in 6 groups: without pigmentation, pigmented with make-up powder and iron oxide, and evaluated with and without the action of the disinfectant. Analysis of marginal deterioration was performed on a scanning electron microscope (magnification, ×5000) immediately 6 months and 1 year after fabrication of specimens, following the guidelines of ASTM International. After visual analysis of the photomicrographs, it was noticed that all groups presented marginal deterioration and alterations in surface texture with time. The use of disinfection did not contribute to the marginal deterioration of polymer (silicone), regardless of the pigmentation and artificial aging.

Desenvolvimento de detector eletroquímico para cromatografia líquida de alta eficiência baseado em um eletrodo modificado com nanopartículas metálicas para determinação de ácidos carboxílicos em vinhaça de cana-de-açúcar

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)