94 resultados para enthalpy


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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

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Pós-graduação em Biofísica Molecular - IBILCE

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The present research was undertaken to explore the influence of fructooligosaccharides (FOS) on the functional and thermal properties of sour cassava starch and the quality characteristics of gluten-free (GF) cheese bread. Fructooligosaccharides were used to replace sour cassava starch at substitution level of 9% (SF1), 17% (SF2), and 29% (SF3). The functional and thermal properties of the starch-FOS mixtures were determined by the water absorption index (WAI), water solubility index (WSI), pasting profile analysis, thermal transition temperatures and enthalpy of gelatinization. Moreover, the GF cheese breads with starch-FOS mixtures were analyzed for height, diameter, weight, specific volume and dough moisture content. The sample with the highest FOS content (SF3) presented the lowest WAI (1.44), peak (62.4 rapid visco units (RVU), breakdown (53.4 RVU), final (13.8 RVU), and setback (4.9 RVU) viscosities, dough moisture content (31.7%), and enthalpy of gelatinization (9.5 J/g) and the highest WSI (29.4%) and pasting temperature (69.1 degrees C). The height, diameter and specific volume of GF cheese bread samples made from sour cassava starch were 3.14 cm, 6.35 cm, and 1.49 cm(3)/g, respectively. The SF1 mixture samples resulted in a 3.01 cm height, 6.34 cm diameter, and 1.55 cm(3)/g specific volume. According to Brazilian food labeling regulations, the latter product cannot be categorized as a good source of fiber because the minimum level of fiber per portion was not reached.

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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

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In this study, the drug indomethacin, a non-steroidal anti-inflammatory indoleacetic acid derivative and the complex of indomethacin and lanthanum (III) in solid form were synthesized and characterized by Thermogravimetry (TGA), Differential Thermal Analysis (DTA), Differential Scanning Calorimetry (DSC) and powder X-ray diffractometry (XRD), infrared vibrational spectroscopy by diffuse reflectance (FTIR) and complexometric titration with EDTA. With the TG curves it was possible to determine the stoichiometry of the complex as La(Ind)3·3.5H2O where Ind is the drug indomethacin. The result of thermal analyzes provided information on the thermal stability, enthalpy of dehydration and thermal behavior of the compounds. The infrared spectrum and with the aid of theoretical calculations suggests that the indomethacin is coordinated by the carboxylate group in the bidentate mode

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This Final Paper had as it main goal to make a thermoanalytical study of lighter trivalent lanthanides (Lanthanum, Cerium, Praseodymium, Neodymium, Samarium and Europium) with the Ibuprofen ligand (nonsteroidal anti-inflammatory) that have a general formula LnL3.nH2O, on solid state, where Ln are the Lanthanides, L is the Ibuprofen ligand and n = number of water molecules of hydration that went from 1,0 to all the compounds. In order to characterize this compounds, it has been used the thermoanalytical techniques TG-DTA (thermogravimetry - Diferential Thermal Analysis) and DSC (Diferential Scanning Calorimetry), Fourier transformed infrared spectroscopy (FTIR) and complexometric titration with EDTA. Through the TG-DTA technique, it has been possible to set the thermal stability of the compounds, the number of thermal decomposition steps and temperatures that ocurred that also provided stoichiometry to the synthesized compounds. The DSC technique has shown the enthalpy of dehydration of the samarium and europium compounds, it was not possible to see it in the other compounds due to a endothermic peak on the DSC curve not being formed. In the case of neodymium, a thermal event ocurred, in which it could be a oxidative decarboxylation right after the dehydration. The infrared was utilised to study the carboxilate groups streches, and so, suggest a ligand metals compound coordination, that to this present paper has been a bidentade bridged coordenation. At last, the complexometric tritation was used to very the ammount of metal present in each compound, and so, verify if the proposed stoichiometry was according to the theory

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