Amostragem de poluentes gasosos e particulados emitidos pela queima de biomassa vegetal

The use of biomass as an energy source has been increasing in Brazil, with emphasis on the use of wood biomass, such as bark, wood chips and sawdust, that after receiving the appropriate treatment can be used in burners for power generation. However, from this burning are emitted fine particles known as particulate matter and a wide range of toxic organic and inorganic components in the form of gases that contribute greatly to air pollution and global warming, affecting human health, the environment and climate. The objective of this project was the quantification of gaseous and particulate, using and evaluating the equipment DR4000 ( Dataram 4 ) sampling of particulates smaller than 2.5μm and EUROTRON ( Ecoline 4000 ) when sampling gaseous pollutants, emitted from the burning of biomass in real time in the firing burner to a chimney attached biomass . We note that there are no specific rules that establish emission limits for particulate matter with diameter less than 2.5μm that are most harmful to human health and the highest concentrations reached about 800000μg/m3, for smaller diameters. It is noticeable the need for sampling of pollutants especially in industries that use biomass to fuel that could be implanted emission control equipment

Simulação de ciclo combinado utilizando software comercial

In Brazil, The power generation has always depended on the rivers, in other words, there are moments that the power generation can vary, which can cause variations in energy supply and even blackout according to the level of water in the reservoirs of the hydroelectric plants. For this reason, many options has been studied, like our example, which is about a combined cycle power plant in Canas. The use of combined cycle is interesting from the point o view of energy, because its efficiency is between 50 and 60%, and from the point of view of environment, because it can burn natural gas, which is cleaner than coal, it reduces the emission of gases that influence on the greenhouse effect. This work aims to perform a technical analysis of a case study of a power plant proposed to be built in Canas by the AES/AES Tietê Group. For the analysis will be used the commercial software GateCycle 6.0.0 from GE, this software has the power of simulating power generation cycles (nuclear, combined, etc.). The energy department of UNESP has the license, which makes possible the academic use of this tool. Two combined cycles were simulated, one using one pressure level HRSG, and another one closer to the real power plant, which is a combined cycle with a three pressure level HRSG. The results were close to expected, for the combined cycle with one pressure HRSG the power was 513,9 MW and a efficiency of 53,27%, in the case with the three pressure level HRSG the power was 517,1 MW and a efficiency of 53,5%. We conclude that the software requires that the user must have the knowledge about the subjects involved in the use of GateCycle in problems resolutions

Avaliação dos impactos ambientais gerados pelos automóveis na cidade de Ilha Solteira-SP

Pós-graduação em Engenharia Civil - FEIS

Programação térmica fetal e duração da fase de eclosão: efeitos sobre a qualidade na eclosão, variáveis sanguíneas, preferência térmica e resposta ao desafio térmico de pintos fêmeas

Pós-graduação em Zootecnia - FCAV

Total sugars in atmospheric aerosols: an alternative tracer for biomass burning

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Aspectos técnicos, econômicos e de sustentabilidade da produção de hidrogênio renovável

Pós-graduação em Engenharia Mecânica - FEG

Jogo digital e analogias: uma proposta para o ensino de Cinética Química

Pós-graduação em Educação para a Ciência - FC

Qualidade da operação na cultura da cana-de-açúcar utilizando cartas de controle

Pós-graduação em Agronomia (Ciência do Solo) - FCAV

Conservação refrigerada de abacate 'hass' e 'fuerte' submetidos à atmosferas modificadas ativas

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Distribuição de espécies com folhas homobáricas e heterobáricas no Cerrado e na Floresta Estacional Semidecídua

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Estrutura e algumas propriedades ópticas de difenilfosfinatos de terras-raras

Coordination compounds of trivalent lanthanides cations with diphenylphosphinate are originated from direct reaction between a lanthanide salt and diphenylphosphinic acid. These complexes have peculiar and intriguing features, as (i) quickly obtainment through wet process precipitation, (ii) appreciable thermal stability, similar to inorganic phosphates, (iii) polymeric structure, and consequently, (iv) low solubility in both polar and non-polar solvents. Nowadays, coordination polymers are classified as coordination networks or, in case of porous materials, as metal-organic frameworks (MOFs). By this study, we aim to determine some optical properties of rare-earth diphenylphosphinate (RE = La3+, Eu3+, Gd3+, Lu3+) and conduct an updated classification of these compounds, bringing more details of its structure and the possible proposal of new materials with applications in lighting, detection of ionizing radiation and magnetism. The complexes of trivalent rare-earth cation with diphenylphosphinate were prepared by direct mixture of diphenylphosphinic acid with rare-earth metal chloride, both in ethanolic solution. The solution of diphenylphosphinic acid was kept in a beaker under constant stirring with pH measurements of the solution and gadolinium chloride solution was then dripped slowly with the aid of a burette until its complete addition; the following metal:ligand molar ratios were tested: 1:1, 1:2, 1:3, 2:1 e 3:1. The compounds were characterized by spectroscopic and structural techniques. By Fourier Transform Infrared Spectroscopy (FT-IR), it was possible to check the total ionization of diphenylphosphinic acid in synthesized complexes, confirmed by the absence of the band type A, B, C related to ѵ(O-H) of the acid (2663 cm-1, 2168 cm-1, 1684 cm-1), as well as the disappearance of ѵ(P-OH)=961 cm-1. Furthermore, the occurrence of bands shifts of ѵ(POO-) [symmetrical and asymmetrical] of...

Chemical Composition of Lipids Present in Cat and Dog Oocyte by Matrix-Assisted Desorption Ionization Mass Spectrometry (MALDI- MS)

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Larynx and cervical trachea in humidification and heating of inhaled gases

To evaluate the participation of the larynx and cervical trachea in conditioning inspired gases, we randomly allocated 16 mixed-breed dogs to two groups: group TT (tracheal tube; n = 8) and group LMA (laryngeal mask airway; n = 8). The dogs were anesthetized with pentobarbital sodium and mechanically ventilated for 3 hours. The parameters studied were temperature and absolute humidities of ambient, inhaled, and tracheal air. There was a small increase in tracheal air temperature compared to inhaled air temperature, but no significant difference between groups. The absolute humidity of tracheal air was greater in group LMA than in group TT (23 mg H2O center dot L-1 and 14 mg H2O center dot L-1, respectively; p < .0001). The difference in absolute humidity between the tracheal air and the inhaled air was higher in group LMA at all times (p < .0001). We conclude that the larynx and cervical trachea of the dog participate in humidification and heating of inhaled air by means of air contact with mucosa in this airway segment.

Advantages of using nested collision induced dissociation/post-source decay with matrix-assisted laser desorption/ionization time-of-flight mass spectrometry: sequencing of novel peptides from wasp venom

We have examined the applicability of the 'nested' collision induced dissociation/post-source decay (CID/PSD) method to the sequencing of novel peptides from solitary wasps which have neurotoxic venom for paralyzing other insects. The CID/PSD spectrum of a ladder peptide derived from an exopeptidase digest was compared with that of the intact peptide. The mass peaks observed only in the CID/PSD spectrum of a ladder peptide were extracted as C-terminal fragment ions. Assignment of C-terminal fragment ions enabled calculation of N-terminal fragment masses, leading to differentiation between N-terminal fragment ions and internal fragment ions. This methodology allowed rapid and sensitive identification by removing ambiguity in the assignment of the fragment ions, and proved useful for sequencing unknown peptides, in particular those available as natural products with a limited supply. Copyright (C) 2000 John Wiley & Sons, Ltd.