Generalização de um modelo linear de impedância eletroquímica

Em geral, a função de um modelo de impedância para processos de eletrodo simples é deduzida de um modelo elétrico equivalente, denominado circuito de Randles. Neste trabalho estudou-se a generalização dessa função, mediante a introdução de um parâmetro não-elétrico, relacionado com a flexibilidade do ângulo de fase e da magnitude. A função foi ajustada às medidas experimentais de impedância obtidas de um sistema constituído de uma liga Ti-10%Al (m/m) em solução de cloreto de sódio 0,9%, variando-se a amplitude de perturbação. Verificou-se que a função generalizada foi adequada para descrever a impedância do sistema analisado, reduzindo as distorções entre a curva experimental e a curva teórica. Além disso, os melhores resultados foram obtidos para sinais de perturbação do sistema com amplitude igual a 10 mV.

Aproveitamento da água de umidificação de malte da moagem úmida como matéria prima na fabricação de cerveja

A água de umidificação de malte, resultante da moagem úmida, pode ser usada como matéria prima na fabricação de cerveja. Há, entretanto, cervejarias que descartam esse subproduto, e conseqüentemente, o extrato nele contido. em função disso, o presente trabalho teve por objetivo avaliar a possibilidade de ganho de rendimento na mosturação e alterações nas características químicas e sensoriais da bebida, em virtude do uso dessa água. Cervejas do tipo Pilsen foram produzidas de duas formas: com e sem água de umidificação de malte. Utilizou-se como matéria prima malte, lúpulo, xarope de maltose, água destilada e água de umidificação de malte. O mosto foi produzido pelo processo de infusão, separado do bagaço de malte por filtração convencional e fervido durante 60 minutos. Após seu resfriamento e clarificação o mosto foi inoculado com levedura de baixa fermentação (1,3g/l, ps) e colocado para fermentar a 10°C. A fermentação foi encerrada com 90% da atenuação limite. em seguida, a cerveja foi engarrafada e maturada a 0°C por 14 dias. Os resultados mostraram que o aumento do rendimento de mosturação, em função do uso da água de umidificação de malte, foi estatisticamente não significativo. A utilização dessa água praticamente não alterou as características químicas e sensoriais da cerveja, havendo apenas um leve aumento na intensidade de cor da bebida (7,1 x 8,0 EBC). Considerando, no entanto, que a água de umidificação de malte obtida em nível industrial apresenta maior concentração de extrato em relação àquela produzida em laboratório, espera-se que o uso da primeira traga ganho de rendimento industrial sem alterações significativas nas características da cerveja.

ON NUCLEON-NUCLEUS SCATTERING AND THE RELATIVISTIC EIKONAL APPROXIMATION

We introduce a generalization of the relativistic eikonal amplitude originally developed to describe elastic scattering between structureless particles. The coherent and incoherent proton-nucleus scattering processes are analysed and closed-form expressions for elastic and inelastic amplitudes are derived. In particular, for the incoherent case, an energy-conserving version of Glauber's theory is obtained.

Reversible equivariant Hopf bifurcation

In this paper we study codimension-one Hopf bifurcation from symmetric equilibrium points in reversible equivariant vector fields. Such bifurcations are characterized by a doubly degenerate pair of purely imaginary eigenvalues of the linearization of the vector field at the equilibrium point. The eigenvalue movements near such a degeneracy typically follow one of three scenarios: splitting (from two pairs of imaginary eigenvalues to a quadruplet on the complex plane), passing (on the imaginary axis), or crossing (a quadruplet crossing the imaginary axis). We give a complete description of the behaviour of reversible periodic orbits in the vicinity of such a bifurcation point. For non-reversible periodic solutions. in the case of Hopf bifurcation with crossing eigenvalues. we obtain a generalization of the equivariant Hopf Theorem.

2-DIMENSIONAL QUANTUM GAS

Identical impenetrable particles in a 2-dimensional configuration space obey braid statistics, intermediate between bosons and fermions. This statistics, based on braid groups, is introduced as a generalization of the usual statistics founded on the symmetric groups. The main properties of an ideal gas of such particles are presented. They do interpolate the properties of bosons and fermions but include classical particles as a special case. Restriction to 2 dimensions precludes lambda points but originates a peculiar symmetry, responsible in particular for the identity of boson and fermion specific heats.

Remarks on immersions in the metastable dimension range

In this work we present a generalization of an exact sequence of normal bordism groups given in a paper by H. A. Salomonsen (Math. Scand. 32 (1973), 87-111). This is applied to prove that if h : M-n --> Xn+k, 5 less than or equal to n < 2k, is a continuous map between two manifolds and g : M-n --> BO is the classifying map of the stable normal bundle of h such that (h, g)(*) : H-i (M, Z(2)) --> H-i (X x BO, Z(2)) is an isomorphism for i < n - k and an epimorphism for i = n - k, then h bordant to an immersion implies that h is homotopic to an immersion. The second remark complements the result of C. Biasi, D. L. Goncalves and A. K. M. Libardi (Topology Applic. 116 (2001), 293-303) and it concerns conditions for which there exist immersions in the metastable dimension range. Some applications and examples for the main results are also given.

A generalized Jaynes-Cummings Hamiltonian and supersymmetric shape invariance

A class of shape-invariant bound-state problems which represent two-level systems are introduced. It is shown that the coupled-channel Hamiltonians obtained correspond to the generalization of the Jaynes-Cummings Hamiltonian.

The BCS-Bose crossover theory

We contrast four distinct versions of the BCS-Bose statistical crossover theory according to the form assumed for the electron-number equation that accompanies the BCS gap equation. The four versions correspond to explicitly accounting for two-hole-(2h) as well as two-electron-(2e) Cooper pairs (CPs), or both in equal proportions, or only either kind. This follows from a recent generalization of the Bose-Einstein condensation (GBEC) statistical theory that includes not boson-boson interactions but rather 2e- and also (without loss of generality) 2h-CPs interacting with unpaired electrons and holes in a single-band model that is easily converted into a two-band model. The GBEC theory is essentially an extension of the Friedberg-Lee 1989 BEC theory of superconductors that excludes 2h-CPs. It can thus recover, when the numbers of 2h- and 2e-CPs in both BE-condensed and non-condensed states are separately equal, the BCS gap equation for all temperatures and couplings as well as the zero-temperature BCS (rigorous-upper-bound) condensation energy for all couplings. But ignoring either 2h- or 2e-CPs it can do neither. In particular, only half the BCS condensation energy is obtained in the two crossover versions ignoring either kind of CPs. We show how critical temperatures T-c from the original BCS-Bose crossover theory in 2D require unphysically large couplings for the Cooper/BCS model interaction to differ significantly from the T(c)s of ordinary BCS theory (where the number equation is substituted by the assumption that the chemical potential equals the Fermi energy). (c) 2007 Published by Elsevier B.V.

Symplectic actions on coadjoint orbits

We present a compact expression for the field theoretical actions based on the symplectic analysis of coadjoint orbits of Lie groups. The final formula for the action density α c becomes a bilinear form 〈(S, 1/λ), (y, m y)〉, where S is a 1-cocycle of the Lie group (a schwarzian type of derivative in conformai case), λ is a coefficient of the central element of the algebra and script Y sign ≡ (y, m y) is the generalized Maurer-Cartan form. In this way the action is fully determined in terms of the basic group theoretical objects. This result is illustrated on a number of examples, including the superconformal model with N = 2. In this case the method is applied to derive the N = 2 superspace generalization of the D=2 Polyakov (super-) gravity action in a manifest (2, 0) supersymmetric form. As a byproduct we also find a natural (2, 0) superspace generalization of the Beltrami equations for the (2, 0) supersymmetric world-sheet metric describing the transition from the conformal to the chiral gauge.

Solutions to higher Hamiltonians in the Toda hierarchies

A method is presented for constructing the general solution to higher Hamiltonians (nonquadratic in the momenta) of the Toda hierarchies of integrable models associated with a simple Lie group G. The method is representation independent and is based on a modified version of the Lax operator. It constitutes a generalization of the method used to construct the solutions of the Toda molecule models. The SL(3) and SL(4) cases are discussed in detail. © 1990 American Institute of Physics.

Entropy, information and doubly stochastic transformations

I analyze two inequalities on entropy and information, one due to von Neumann and a recent one to Schiffer, and show that the relevant quantities in these inequalities are related by special doubly stochastic matrices (DSM). I then use generalization of the first inequality to prove algebraically a generalization of Schiffer's inequality to arbitrary DSM. I also give a second interpretation to the latter inequality, determine its domain of applicability, and illustrate it by using Zeeman splitting. This example shows that symmetric (degenerate) systems have less entropy than the corresponding split systems, if compared at the same average energy. This seemingly counter-intuitive result is explained thermodynamically. © 1991.

Quantum vacuum in hot nuclear matter: A non-perturbative treatment

We derive the equation of state for hot nuclear matter using the Walecka model in a non-perturbative formalism. We include here the vacuum polarization effects arising from the nucleon and scalar mesons through a realignment of the vacuum. A ground state structure with baryon-antibaryon condensates yields the results obtained through the relativistic Hartree approximation of summing baryonic tadpole diagrams. Generalization of such a state to include the quantum effects for the scalar meson fields through the σ -meson condensates amounts to summing over a class of multiloop diagrams. The techniques of the thermofield dynamics method are used for the finite-temperature and finite-density calculations. The in-medium nucleon and sigma meson masses are also calculated in a self-consistent manner. We examine the liquid-gas phase transition at low temperatures (≈ 20 MeV), as well as apply the formalism to high temperatures to examine a possible chiral symmetry restoration phase transition.

Variational method for excited states from supersymmetric techniques

We suggest a method for constructing trial eigenfunctions for excited states to be used in the variational method. This method is a generalization of the one that uses a superpotential to obtain the trial functions for the ground state. The construction of an effective hierarchy of Hamiltonians is used to determine excited variational energies. The first four eigenvalues for a quartic double-well potential are calculated for several values of the potential parameter. The results are in very good agreement with the eigenvalues obtained by numerical integration.

Pseudospin symmetry and the relativistic harmonic oscillator

A generalized relativistic harmonic oscillator for spin 1/2 particles is studied. The Dirac Hamiltonian contains a scalar S and a vector V quadratic potentials in the radial coordinate, as well as a tensor potential U linear in r. Setting either or both combinations Σ=5+V and δ=V-S to zero, analytical solutions for bound states of the corresponding Dirac equations are found. The eigenenergies and wave functions are presented and particular cases are discussed, devoting a special attention to the nonrelativistic limit and the case Σ=0, for which pseudospin symmetry is exact. We also show that the case U=δ=0 is the most natural generalization of the nonrelativistic harmonic oscillator. The radial node structure of the Dirac spinor is studied for several combinations of harmonic-oscillator potentials, and that study allows us to explain why nuclear intruder levels cannot be described in the framework of the relativistic harmonic oscillator in the pseudospin limit.

Invariant conserved currents in gravity theories with local Lorentz and diffeomorphism symmetry

We discuss conservation laws for gravity theories invariant under general coordinate and local Lorentz transformations. We demonstrate the possibility to formulate these conservation laws in many covariant and noncovariant(ly looking) ways. An interesting mathematical fact underlies such a diversity: there is a certain ambiguity in a definition of the (Lorentz-) covariant generalization of the usual Lie derivative. Using this freedom, we develop a general approach to the construction of invariant conserved currents generated by an arbitrary vector field on the spacetime. This is done in any dimension, for any Lagrangian of the gravitational field and of a (minimally or nonminimally) coupled matter field. A development of the regularization via relocalization scheme is used to obtain finite conserved quantities for asymptotically nonflat solutions. We illustrate how our formalism works by some explicit examples. © 2006 The American Physical Society.