Amostragem de poluentes particulados emitidos pela queima de biomassa em correntes confinadas

It is clear today the ever-accelerating search for new fuels that will eventually replace those that will survive in our society, which are fossil fuels. For this reason, a fuel used since the dawn of humanity and much studied since then, considered the generator of clean, renewable energy, can earn more and more space in the power generation sector, which is biomass. We performed two experiments with two different types of biomass, one from the Amazon rainforest and other pine and eucalyptus as waste from the sawmill UNESP Itapeva. In the first experiment, conducted at the Laboratory of Combustion and Propulsion INPE Cachoeira Paulista were conducted three tests in a chimney with a fan creating forced ventilation, where the biomass was burned and deposited on a support beneath the hood. In the second experiment was conducted to analyze the emission of particulate matter using biomass (waste) from the sawmill on the campus of UNESP experimental Itapeva the burning of it in a burner for heating water for a wood oven. In these experiments we used a particle called DATARAM4 sampler that is capable of sampling both outdoors and inside of pipelines, which is the focus of this work. With this equipment it was possible to measure the concentration of particulate matter in all the firings as above, and compare them to levels acceptable in the current law, always trying to analyze the so-called fine particles, which are those with diameters less than 2.5 μm. Using data obtained from the equipment was also possible to evaluate the diametral distribution of particulate matter in question, and verify which phases of the flares in the concentration and the diameters of the particles are the most critical. In this work we concluded that in all firings conducted concentrations of particulate matter were higher than that allowed by the law, and the diameters were found that are more harmful to human health

Smart Grid e Carros Elétricos - Influência da Carga de Carros Elétricos Sobre o Sistema Elétrico

The technologies are advancing at a pace so expressive that allow the increase of the power quality from generation until the distribution to end customers. This improvement has been made possible through the automation of the energy that follows to a better quality of the energy provided, a lower energy supply disruptions and a very short recovery time. The trend of today and the near future is the distributed energy generation. To keep the automated control of the chain, the presence of Smart Grids is needed and that will be the most efficient and economical way to manage the entire system. Within this theme, is going to be necessary analyze the electric cars that promise to promote a more sustainable transport because it doesn’t uses fossil fuels, and more healthy because it does not emit pollutants into the atmosphere. The popularization of this type of vehicle is estimated to happen in a few decades and the case study analyzing its influence on the demand of the electrical system is something that will be very important in the near future. This paper presents a study of the influence of the inclusion of charges refering to electric cars

Análise energética da aplicação de torta de filtro na substituição parcial da adubação inorgânica sintética da cana-de-açúcar

Pós-graduação em Agronomia (Energia na Agricultura) - FCA

Bioconversion of Cellulose to Hydrogen by dark fermentation

Hydrogen is known as a clean energy resource. The biological production of hydrogen has been attracting attention as an environmentally friendly processs that does not consume fossil fuels. Cellulosic plant and waste materials are potential resources for fermentative hydrogen production. Cellulose is a linear biopolymer of glucose molecules, connected by β-1,4-glycosidic bonds. Enzymatic hydrolysis of cellulose requires the presence of cellulase. The present study aimed to investigate the efficiency of acid pretreatment on ruminal fluid in order to enrich H2 producing bacteria consortia to enhance biohydrogen rate and substrate removal efficiency. In this study, fermentative hydrogen producers were enriched on cellulose (2g/L) in a modificated Del Nery medium (DNM) at 37ºC and initial pH 7.0 using rumen fluid (10% v/v) as inoculum. To increase the hydrogen production it was added cellulose (10mL) to the medium. The gas products (mainly H2 and CO2) was analyzed by gas chromatography (Shimadzu GC 2010) using a thermal conductivity detector. The volatile fatty acids and ethanol were also detected by GC using a flame ionization detector. Cellulose degradation was quantified by using the phenolsulfuric acid method. Analysis showed that the biogas produced from the anaerobic fermentation contained only hydrogen and carbon dioxide, without detectable methane after acid pretreatment test. On DNM the hydrogen production started with 4 h (5,3 x 105 mmol H2/L) of incubation, and the maximum H2 concentration was observed with 34 h (7,1 x 106 mmol H2/L) of incubation. During the process, it was observed a predominance of acetic acid and butyric acid as well as a low production of acetone, ethanol and nbutanol in all experimental phases. Butyrate accounted for more than 77% of total. As a result of the accumulation of volatile fatty acids (VFAs), the pH value in anaerobic digestion system was reduced to 4,0. On microscopy analyses there were observed rods with endospores. The batch anaerobic fermentation assays performed on anaerobic mixed inoculum from rumen fluid demonstrated the feasibility of H2 generation utilizing cellulose as substrate. Based on the results, it can be concluded that the acid treatment was efficient to inhibit the methanogenic archaea cells present in rumen fluid. The rumen fluid cells present a potential route in converting renewable biomass such as cellulose into hydrogen energy.

Desenvolvimento, validação, avaliação da incerteza de medição e análise de custos de método baseado em espectroscopia no infravermelho e análise multivariada para previsão de parâmetros de qualidade de amostras de E85

Pós-graduação em Química - IQ

Biodessulfurização do biogás gerado no processo de digestão anaeróbia da estação de tratamento de efluentes de uma indústria cervejeira

Pós-graduação em Química - IQ

Caracterização físico-química da biomassa produzida em sistemas florestais de curta rotação para geração de energia

Pós-graduação em Agronomia (Energia na Agricultura) - FCA

Bioenergy from stillage anaerobic digestion to enhance the energy balance ratio of ethanol production

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Relação entre poluição do ar e internações hospitalares por doenças respiratórias e cardiovascular em uma cidade do interior do Estado de São Paulo

Pós-graduação em Fisioterapia - FCT

Thermodynamic, Economic and Emissions Analysis of a Micro Gas Turbine Cogeneration System operating on Biofuels

Pós-graduação em Engenharia Mecânica - FEG

Determinação de fósforo em biodiesel utilizando eletrodo quimicamente modificado com nanopartículas de ferro

Once petroleum is na exhaustible source of energy, alternative fuels are having more prominence. A much discussed option for replacing fossil fuels is the use of biofuels derived from oils or fats, especially biodiesel. The biodiesel preparation is through a reaction named transesterification, a reaction of triglycerides with a short chain alcohol with a catalyst, producing a mixture of fatty acid esters and glycerol. According to ANP (National Petroleum Agency) specifications, biodiesel can have contaminants due to the catalyst or oil used on its synthesis, such as phosphorus, wich can damage the catalytic converter and cause significant increase in the particles emission. This project aims to develop na alternative method using chemically modified electrodes with iron nanoparticles for determination of phosphorus in biodiesel. For the formation of the iron nanoparticles film on the surface of a glassy carbon electrode, was used a iron sulfate solution. The film was formed after 10 successive cycles, with a scanning speed of 50 mV s-1 and a potential range of -0,9 to -1,25 V. To reduce possible oxides on the surface and activate the electrode, it has been subjected to a cathodic polarization with a potential of -1,25 V for 15 minutes in a sodium hydroxide solution. In cyclic voltammograms obtained in the study of the speed of scanning, there is an increase in the intensity of the anodic and cathodic current peaks. The cathodic peak current varied linearly with the square root of scan rate, showing that the electrode is controlled by diffusion. After successive additions of phosphate there is a linear variation in the current peak in the concentration range of 1,0 x 10-7 a 1,0 x 10-6 mol L-1. To determine if the concentration of phosphorus in real sample, the method of adding standard was used by adding aliquots of phosphate ions in the solution containing soy biodiesel extracted with ....

Crescimento econômico e desacoplamento do uso de recursos naturais e de impactos ambientais: evidências para o Brasil

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Ethanol production using hemicellulosic hydrolyzate and sugarcane juice with yeasts that converte pentoses and hexoses

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Greenhouse gas balance associated with sugarcane production in South-Central Brazil, considering the management and expansion

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

A modernização da agricultura no Brasil e a produção do biocombustível como energia alternativa: uma reflexão crítica

This article discusses the policy implications of agricultural modernization implemented by the military - after 1964. This policy, which became known as the Green Revolution, on the one hand contributed to the development of big business, but another caused serious social and environmental impacts. Currently, not only in Brazil but all over the world, have been in a great debate about the need to find alternatives to contain the problems caused to the environment resulting from the use of high technology in the field. One alternative proposed by several researchers is to replace fossil fuels by biofuels. As we believe that the error is in the current model of agricultural production based on mass production, which serves the major markets, the attention in this article, the need to develop an agricultural model designed for small property, with the use of family work and agroecology.