Nanocrystalline Ga1-xMnxN films grown by reactive sputtering

The growth of nanocrystalline Ga1-zMnxN (0.00 <= x <= 0.18) films grown by reactive RF-magnetron sputtering is focused here for the first time. The films were grown in a N-2 atmosphere by co-sputtering technique using a Ga target covered with small pieces of Mn onto c-GaAs (10 0), c-Si (10 0) and amorphous SiO2 substrates maintained at 500 K. Scanning electron microscopy and X-ray diffraction (XRD) experiments did not show any evidence for Mn segregation within the studied composition range. EDX measurements show that the Mn concentration is increased monotonically with the fraction of the target area covered by Mn. The XRD characterization show that the films are nanocrystalline, the crystallites having mean grain sizes in the 15-19 nm range and wurtzite structure with preferential growth orientation along the c-axis direction. The lattice parameters of alpha-GaN (a and c) increase practically linearly with the increase of Mn incorporation. The changes in the structural properties of our films due to the Mn incorporation are similar to those that occur in ferromagnetic GaMnN single-crystal films. (c) 2006 Elsevier B.V. All rights reserved.

Effect of reaction time on the particle size of ZnO and ZnO : Ce obtained by a sol-gel method

In this work particles of ZnO of size range 33-56 Angstrom were prepared by a sol-gel method. The effect of reaction time on the particle size of ZnO or ZnO:Ce was investigated by transmission electron microscopy measurements, UV-vis absorption and luminescence spectroscopy. A linear increase of the mean particle size is observed as a function of reaction time. The cerium-doped particles are bigger than the pure ZnO ones obtained at the same reaction time. A shift to lower energy at the maximum of the bands is observed in all absorption, emission and excitation spectra as a function of particle growth. From the absorption spectra the optical energy gap values (Eg) for these particles were determined. In the quantum size regime, Eg was found to decrease with particle growth.

Short Range Order Evolution in the Preparation of SnO2 Based Materials

The evolution of Eu3+ doped SnO2 xerogels to the cassiterite structure observed during sintering was studied by means of Eu3+ spectroscopy, XRD and EXAFS at the Sn K-edge. Eu3+ ions adsorbed at the surface of colloidal particles present a broad distribution of sites, typical of oxide glasses. With sintering at 300°C, this distribution is still broadened. Crystallization is clearly observed by the three techniques with increasing sintering temperature. It is found that the addition of Eu3+ limits the crystallite growth.

Non-isothermal study of the devitrification kinetics of fluoroindate glasses

The understanding of the kinetics of devitrification of a glass is important for anticipating its stability in a particular purpose, such as fiber-drawing processes. The crystallization kinetics of (BaF2)16(ZnF2)20(SrF 2)20(NaF)2 (GaF3)5(InF3)36(GdF 3)1 glass prepared by quenching were studied by differential scanning calorimetry (DSC). Avrami's exponent (n) obtained by a non-isothermal method was 4.3 for a solid and 2.4 for a powdered sample. According to the classical interpretation of n, these magnitudes correspond to an interface-controlled crystal growth and a diffusion-controlled crystal growth, respectively. The activation energies for crystallization (E) was 62 ± 1 kJ/mol for solid glass and 245 ± 2 kJ/mol for powdered glass. These results are discussed in terms of glass particle size. © 2000 Elsevier Science B.V. All rights reserved.

Corn root length density and root diameter as affected by soil compaction and soil water content

Negative effects of soil compaction have been recognized as one of the problems restricting the root system and consequently impairing yields, especially in the Southern Coastal Plain of the USA. Simulations of the root restricting layers in green house studies are necessary for the development of mechanism which alleviates soil compaction problems in these soils. The selection of three distinct bulk densities based on the standard proctor test is also an important factor to determine which bulk density restricts the root layer. The experiment was conducted to assess the root length density and root diameter of the corn (Zea mays L.) crop as a function of bulk density and water stress, characterized by the soil density (1.2; 1.4, and 1.6 g cm -3), and two levels of the water content, approximately (70 and 90% field capacity). The statistical design adopted was completely randomized design, with four replicates in a factorial pattern of (3 × 2). The PVC tubes were superimposed with an internal diameter of 20 cm with a height of 40 cm (the upper tube 20 cm, compacted and inferior tube 10 cm), the hardpan with different levels of soil compaction were located between 20 and 30 cm of the depth of the pot. Results showed that: the main effects of subsoil mechanical impedance were observed on the top layer indicating that the plants had to penetrate beyond the favorable soil conditions before root growth was affected from 3.16; 2.41 to 1.37 cm cm -3 (P<0.005). There was a significant difference at the hardpan layer for the two levels of water and 90% field capacity reduced the root growth from 0.91 to 0.60 cm cm -3 (P<0.005). The root length density and root diameter were affected by increasing soil bulk density from 1.2 to 1.6 g cm -3 which caused penetration resistance to increase to 1.4 MPa. Soil water content of 70% field capacity furnished better root growth in all the layers studied. The increase in root length density resulted in increased root volume. It can also be concluded that the effect of soil compaction impaired the root diameter mostly at the hardpan layer. Soil temperature had detrimental effect on the root growth mostly with higher bulk densities.

Soluções nutritivas no desenvolvimento do crisântemo cultivado em vaso

Although the information about nutritive solution for potted chrysanthemum is still incongruent, the objective of this work was to evaluate the effect of nutritive solutions in the development of Miramar chrysanthemum cultivated in pots at FCAV-UNESP, Jaboticabal-SP. The experiment had a randomized block design with split-plot evaluation and treatments corresponding to four nutritive solutions consisting of commercial fertilizers (S1, S2, S3, S4) evaluated at 0, 14, 28, 42, 56 and 70 days after rooting (DAE), with five replications. The plant height, leaf area, number of leaves, stem diameter, total dry matter mass of aerial part and roots; number and diameter of inflorescences, and physiological indexes of growth analysis were evaluated. The nutritive solutions did not interfere significantly in stem diameter, number and diameter of inflorescences and dry matter of roots, although S3 and S4 provided the highest plants, leaf area, number of leaves, total dry matter of aerial part. The physiological indexes showed that plants presented an accelerated growth from 14 to 28 DAE with S4 and S3 solutions and therefore they were considered the best solutions.

Sprawling and Urban transportation system: Impacts in the city of Londrina, Parana, Brazil

After nearly 80 years since the construction of its core, represented today by the city's central area, Londrina, located in the state of Parana, has the appearance of a new city but its features and trends of planning policies depict the bad examples of Brazilian cities. With a booming urban growth, from north to south of the county, the urban interstices represented by big voids in the middle of the city created speculation and the concept of an ideal city slowly disappeared. With a metropolitan appearance and, at the same time, with small town aspects, Londrina stands out as an automobile-oriented city, a fact that has impacted the livelihood of the population, generating environmental impacts for all social classes. This paper discusses how the form of occupation in Londrina, characterized by the sprawl phenomenon and its relation to car preference as a mode of transportation has generated urban environmental impacts. It was concluded that the choice of using cars in Londrina, as well in other medium-sized Brazilian cities studied by the comparative method, has increased and has generated bottlenecks in traffic. As a consequence, there is a constant expropriation of properties for widening roads and at the same time, the presence of various densities and urban voids that form an uneven urban space and an obstacle to efficient urban planning. © 2012 WIT Press.

Electronic structure and magnetic properties of FeWO 4 nanocrystals synthesized by the microwave-hydrothermal method

This communication reports that FeWO 4 nanocrystals were successfully synthesized by the microwave-hydrothermal method at 443 K for 1 h. The structure and shape of these nanocrystals were characterized by X-ray diffraction, Rietveld refinement, and transmission electron microscopy. The experimental results and first principles calculations were combined to explain the electronic structure and magnetic properties. Experimental data were obtained by magnetization measurements for different applied magnetic fields. Theoretical calculations revealed that magnetic properties of FeWO 4 nanocrystals can be assigned to two magnetic orderings with parallel or antiparallel spins in adjacent chains. These factors are crucial to understanding of competition between ferro- and antiferromagnetic behavior. © 2012 Elsevier Inc.

Estudo do efeito de CdO e Bi2O3 no processo de nucleação e crescimento de cristais em matrizes vítreas [TeO2WO3] (CdO;Bi2O3)

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Determinação da atividade anti Mycobacterium tuberculosis de metabólitos bioativos de fungos endofíticos empregando a técnica do MABA

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

A expansão da cultura da cana-de-açúcar e de usinas canavieiras na microrregião de Paranaíba Mato Grosso do Sul

Pós-graduação em Agronomia - FEIS

Crescimento de Brachiaria subquadripara (Trin.) Hitchc. sob diferentes condições nutricionais e monitoramento sazonal de fatores ambientais no habitat natural

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Síntese e caracterização de vidros teluritos

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Morfologias de óxido de cobre (II) na mesoescala: síntese hidrotérmica assistida por micro-ondas, mecanismo de crescimento e atividade catalítica na reação de desidrogenação do etanol

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)