DEVELOPMENT OF A BIOMIMETIC SENSOR MODIFIED WITH HEMIN AND GRAPHENE OXIDE FOR MONITORING OF CARBOFURAN IN FOOD

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Electroanalytical determination of bumetanide employing a biomimetic sensor for detection of doping in sports

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Quantificação de CO2 e vapor de água nas interfaces bairro-cultura de eucalipto da reserva Floresta Estadual Navarro de Andrade no município de Rio Claro - SP

Environrnental issues are in focus lately, mainly due to climate change that have been registered in recent decades. Some of these changes are attributed to the increased atmospheric concentration of greenhouse gases induce, main1y due to anthropogenic emissions. These gases act by absorbing heat in the form of electromagnetic radiation emitted by the planet, and after a time interval, reissuing such radiation in various directions, including back to the surface, causing overheating of the same. Projections indicate that climate change wiIl tend to increase even more. Because of this, in recent years a number of studies are being conducted on the dynamics of inducers of greenhouse gases, especially C02, because that is primarily responsible for the development of that phenomenon. To better understand the flow of C02 are studied specific areas, as regions bordering the forests, soils that are under preparation for agriculture, urban areas, among others. Forests are an important sink for C02, because during the process of photosynthesis, this molecule is captured and used to obtain glucose. Thus, studies of the regions bordering the forests contribute enough to the understanding of the dynamics of C02. Because it requires a large amount of factors, the concentration of CO2 in a given location is very variable and this makes it much more difficult to understand their dynamics and, consequently, the action of the enhanced greenhouse effect. Being a relatively new area of study, there are many controversies about the consequences of the greenhouse effect, so that the community does not believe that climate change resulting from human action. According to them, such changes are merely natural phenomena and periodicals

Espaço de coworking e a arquitetura: modificações dos suportes, interfaces e espaços de trabalho

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As interfaces entre linguagens audiovisuais e práticas pedagógicas em História e Geografia: experiências, possibilidades e limites no curta metragem como uma outra compreensão do local e do vivido

Specifically in the teaching practices of History and Geography notes a concern with the construction of school knowledge based on observance of categories such as 'everyday' and 'place', which emphasize a look intensively focused on the local context of the students - element (res) significance, situated in time and space, the representations and actions of individuals, the (re) defining their identities (individual and / or collective) and rights to citizenship. However, both educators in history, as in geography, should be alert to some limits of a strictly pedagogical 'localist'. When it comes to use of language technology audiovisual in line with the pedagogical existing in “PCN's” history and geography, one must keep in mind that not just resize the movie to local level (whether in the classroom or outside), or elect the 'localism' as the new panacea of a certain 'pedagogy' of audiovisual language. With the desire to promote the development of new methods of teaching history and geography is that we designed a research project. This is creating opportunity with the possibility of graduating videos reflect on the teaching of history and geography, according to the use of a new technological language and art (cinema), the association with the reality of the students (hence the site survey and urban) as well as the promotion of an active and critical dialogue with the PCNs’s recommendations.

Infiltração bacteriana nas interfaces entre implantes e pilares: efeito do desenho das conexões protéticas

Pós-graduação em Odontologia Restauradora - ICT

On-line monitoring of electrochemical degradation of paracetamol through a biomimetic sensor

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Development of biomimetic sensor for fast and sensitive detection of Norfloxacin

A biomimetic sensor is proposed as a promising new analytical method for determination of norfloxacin (NF) in pharmaceuticals. The sensor was prepared by modifying a glassy carbon electrode surface with a Nafion® membrane doped with poly(copper phthalocyanine) complex [poly-CuPc]. Amperometric measurements carried out with the sensor under an applied potential of -0.05 V vs Ag|AgCl in 0.1 mol L-1 acetic acid containing 1.5 × 10-3 mol L-1 hydrogen peroxide showed a linear response range from 2.0 × 10-4 to 1.2 × 10-3 mol L-1. Selectivity and interference studies were also performed. A sensor response mechanism is proposed, based on the experimental evidence. Recovery studies were carried out using environmental samples, in order to evaluate the sensor’s potential for use with these sample classes. Finally, sensor performance was evaluated using analyses of commercial formulations.

A new biomimetic sensor based on molecularly imprinted polymers for highly sensitive and selective determination of hexazinone herbicide

A new selective sensor based on molecularly imprinted polymers (MIPs) was developed for the determination of hexazinone (HXZ) in environmental samples. MIPs were synthesized using a non-covalent approach, and selection of the monomers employed in the polymerization reaction was carried out by molecular modeling. Three functional monomers with high (2-vinylpyridine (MP17)) and intermediate (methacrylic acid (MP12) and acrylamide (MP5)) energies of binding to the template (HXZ) were selected for preparation of the MIPs, in order to conduct comparative studies and validate the theoretical data. For sensor construction, carbon pastes were modified with each MIP or NIP (non-imprinted polymer), and HXZ determination was performed using differential pulse adsorptive cathodic stripping voltammetry (DPAdCSV). All parameters affecting the sensor response were optimized. In HCl at pH 2.5, the sensor prepared with MP17 (5% w/w in the paste) showed a dynamic linear range between 1.9 × 10−11 and 1.1 × 10−10 mol L−1, and a detection limit of 2.6 × 10−12 mol L−1, under the following conditions: accumulation time of 200 s at a potential of −0.5V, scan rate of 50 mVs−1, pulse amplitude of 60 mV, and pulse width of 50 ms. The sensor was selective in the presence of other similar compounds, and was successfully applied to the analysis of HXZ in river water samples.

Esthetic and function improvement by direct composite resins and biomimetic concept

Aim: This case report describe a resin layering restorative technique based on biomimetic concept to improve esthetics in a patient with dental defects that affected both enamel and dentin in anterior teeth. Background: Severe structural defect in anterior teeth compromises esthetics and it is a high challenge to become the defect imperceptible after the restoration. Case description: A clinical sequence of applying different composite resin layers allowed the reproduction of the interaction between hard dental tissues and the restorative material. Conclusion: This technique achieved a satisfactory final esthetic outcome, preserving sound teeth structure and at same time, improved the quality of life of the young patient. Clinical significance: The utilization of the biomimetic concept to increase a disharmonic smile with dental defects is based in a conservative approach, which reached a satisfactory and esthetic outcome.

Participação política no Brasil: ação coletiva e interfaces socioestatais

Essa coletânea reúne alguns trabalhos apresentados e discutidos no “Encontro internacional participação, democracia e políticas públicas: aproximando agendas e agentes”, realizado na Faculdade de Ciências e Letras da Unesp de Araraquara em abril de 2013. O encontro foi organizado pelo Grupo de Pesquisa Participação, Democracia e Políticas Públicas, formado por docentes e pesquisadores ligados ao Departamento de Antropologia, Política e Filosofia e também ao Departamento de Administração Pública desta faculdade. A proposta do encontro partiu do diagnóstico de ambos os departamentos da necessidade de se ampliar os debates que relacionem as temáticas da participação, das políticas públicas e da democracia no Brasil e na América Latina, no atual contexto de insuficiência das instituições políticas calcadas no âmbito da democracia liberal e de uma notória “crise da representação”. O livro foi dividido em três partes, “Ação coletiva e institucionalização: interfaces socioestatais”, que trata dos processos de institucionalização dos movimentos sociais; “Instituições participativas da teoria à implementação: dilemas e desafios”, sobre estratégias de governança; e “Participação como política e a política da participação: difusão, impactos, poder”, sobre políticas públicas e o trabalho das ONGs nas ações governamentais.

Relações de gênero e sexualidade na educação infantil: interfaces que envolvem as práticas pedagógicas

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

A investigação apreciativa como metodologia participativa e as suas possíveis interfaces com comunicação organizacional: um estudo de caso na Nutrimental

This work aims to present Appreciative Inquiry as a participative methodology and seeks to establish possible relationships with organizational communication. For this, we make a literature review about topics such as participation, participative planning, appreciative inquiry, it's basic concepts, it's methodology and possibilities. It also presents the fundamental concepts of communication and organizational culture and public relations, searching to highlight the perceived interfaces through the interrelation of concepts, the main references, authors such as Demo (1999), Gandin (1994) Brose (2010), Cooperrider and Whitney (2006), Varona (2004), Bordenave (1999), Kunsch (2002) and Marchiori (2013). In order to verify the applicability of this methodology, this paper also develops a qualitative study, using the technique of indepth research with the first Brazilian organization using Appreciative Inquiry: Nutrimental, a food company. The results of the application of AI in the organization are presented and then seeks to make the possible connections with the concepts of communication and organizational culture

Effect of long-term storage on nanomechanical and morphological properties of dentin-adhesive interfaces

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)