Evolution of CaCu3Ti4O12 varistor properties during heat treatment in vacuum

Calcium copper titanate (CaCu3Ti4O12) ceramic varistors were prepared by solid-state method. The samples were several times heat treated in vacuum and the evolution of electrical characteristics were monitored by current density versus electric field measurements and impedance spectroscopy. Repeated heat treatments in vacuum (900 degrees C for 1 h, 0.01 Torr) lead to a desorption of oxygen adsorbed at the grain boundaries and consequently to a degradation of the varistor properties. During further successive heat treatments some oxygen from the grain interior moves to the grain boundary thereby partially restoring the varistor properties. (c) 2006 Elsevier Ltd and Techna Group S.r.l. All rights reserved.

Crystal structure of a novel myotoxic Arg49 phospholipase A(2) homolog (zhaoermiatoxin) from Zhaoermia mangshanensis snake venom: Insights into Arg49 coordination and the role of Lys122 in the polarization of the C-terminus

The venom of Zhaoermia mangshanensis, encountered solely in Mt Mang in China's Hunan Province, exhibits coagulant, phosphodiesterase, L-amino acid oxidase, kallikrein, phospholipase A(2) and myotoxic activities. The catalytically inactive PLA(2) homolog referred to as zhaoermiatoxin is highly myotoxic and displays high myonecrotic and edema activities. Zhaoermiatoxin possesses a molecular weight of 13,972 Da, consists of 121 amino-acid residues crosslinked by seven disulfide bridges and shares high sequence homology with Lys49-PLA(2)s from the distantly related Asian pitvipers. However, zhaoermiatoxin possesses an arginine residue at position 49 instead of a lysine, thereby suggesting a secondary Lys49 -> Arg substitution which results in a catalytically inactive protein. We have determined the first crystal structure of zhaoermiatoxin, an Arg49-PLA(2), from Zhaoermia mangshanensis venom at 2.05 A resolution, which represents a novel member of phospholipase A(2) family. In this structure, unlike the Lys49 PLA(2)s, the C-terminus is well ordered and an unexpected non-polarized state of the putative calcium-binding loop due to the flip of Lys122 towards the bulk solvent is observed. The orientation of the Arg-49 side chain results in a similar binding mode to that observed in the Lys49 PLA(2)s; however, the guadinidium group is tri-coordinated by carbonyl oxygen atoms of the putative calcium-binding loop, whereas the N zeta atom of lysine is tetra-coordinated as a result of the different conformation adopted by the putative calcium-binding loop. (c) 2008 Elsevier Ltd. All rights reserved.

Contribution of an extrinsic mechanism for the electrical polarization in BiMn2O5 ceramics

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Kinetics of the polarization reversal process in a non-constant applied electric field and the generalized superposition principle

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Polarization in fermion scattering

The behaviour of the helicity of an initially left-handed beam of massive fermions first interacting with a Coulomb field and then with a charged scalar particle via a photon exchange is analysed. It is found that in both cases the massive fermions have their helicity flipped, while massless fermions seeem to be unaffected by the electromagnetic field as far as their helicity is concerned.

Discriminating new physics scenarios at the Next Linear Collider: The role of polarization

We explore the potential of the Next Linear Collider, operating in the e γ mode, to disentangle new physics scenarios in single W production. We study the effects related to the exchange of composite fermions in the reaction e γ→Wνe, and compare them with those arising from trilinear gauge boson anomalous couplings. We stress the role played by the initial state polarization to increase the reach of this machine and to discriminate the possible origin of the new phenomena.

Fixed points and vacuum energy of dynamically broken gauge theories

We show that if a gauge theory with dynamical symmetry breaking has nontrivial fixed points, they will correspond to extrema of the vacuum energy. This relationship provides a different method to determine fixed points.

Note on the point-splitting procedure to evaluate vacuum fluctuation in certain cylindrically symmetric backgrounds

We reexamine the two-point function approaches used to study vacuum fluctuation in wedge-shaped regions and conical backgrounds. The appearance of divergent integrals is discussed and circumvented. The issue is considered in the context of a massless scalar field in cosmic string spacetime.

Squeezed gluon vacuum and the global color model of QCD

We discuss how the vacuum model of Celenza and Shakin with a squeezed gluon condensate can explain the existence of an infrared singular gluon propagator frequently used in calculations within the global color model. In particular, it reproduces a recently proposed QCD-motivated model where low energy chiral parameters were computed as a function of a dynamically generated gluon mass. We show how the strength of the confining interaction of this gluon propagator and the value of the physical gluon condensate may be connected.

CP violation in vacuum neutrino oscillation experiments

We discuss the use of the CP asymmetry parameter (ACP) as a possible observable of CP violation in the leptonic sector. In order to do this, we study for a wide range of values of LIE the behavior of this asymmetry for the corresponding maximal value of the CP violation factor allowed by all the present experimental limits on neutrino oscillations in vacuum and the recent Super-Kamiokande atmospheric neutrino result. We work in the three neutrino flavor framework. ©1999 The American Physical Society.

Optimized delta expansion for relativistic nuclear models: Renormalization of vacuum fluctuations

We use the optimized linear δ expansion and functional methods to study vacuum contributions in nuclear matter up to the lowest non-trivial order which includes exchange terms. We show that well known results (MFT, RHA and HF) can be easily reproduced when appropriate limits are taken. Neglecting vacuum contributions we explicitly show that the δ expansion goes beyond the traditional loop approximation previously used to study two loop vacuum contributions in nuclear matter. We then evaluate and renormalize vacuum exchange contributions showing that they are numerically very large, as predicted by the ordinary loop approximation.

Effects of vacuum structure on neutron stars

We study the equation of state for neutron matter using the Walecka model including quantum corrections for baryons and sigma mesons through a realignment of the vacuum. We next use this equation of state to calculate the radius, mass, and other properties of rotating neutron stars.

Relating the quark and gluon condensâtes through the QCD vacuum energy

Using the Cornwall-Jackiw-Tomboulis effective potential for composite operators we compute the QCD vacuum energy as a function of the dynamical quark and gluon propagators, which are related to their respective condensâtes as predicted by the operator product expansion. The identification of this result to the vacuum energy obtained from the trace of the energy-momentum tensor allows us to study the gluon self-energy, verifying that it is fairly represented in the ultraviolet by the asymptotic behavior predicted by the operator product expansion, and in the infrared it is frozen at its asymptotic value at one scale of the order of the dynamical gluon mass. We also discuss the implications of this identity for heavy and light quarks. For heavy quarks we recover, through the vacuum energy calculation, the relation nij{filif)-îi(asl'n)GlivGllv obtained many years ago with QCD sum rules. ©2000 The American Physical Society.

The use of pulsed electric acoustic technique for measuring the polarization reversal in ferroelectric ceramic samples

The pulsed electric acoustic technique, PEA, has been usually applied to probe space charge profiles in polymers. Preliminary PEA results using a ferroelectric ceramic are presented. If the reverse applied electric field i of the order of the coercive field the switching polarization process occurs in a period larger than hundreds of seconds. Such a slow process allows one to use the PEA setup to follow the polarization switching dynamics and determine the electric field profile. The PEA signal obtained in the lead zirconate-titanate doped with niobium ceramic, PZTN, indicates that the polarization distribution and field are not uniform during the switching period. We were also able to observe that the acoustic wave velocity and attenuation depends on the stage of the polarization switching, which agrees with results obtained using the ultrasonic method.