133 resultados para mRNA poly(A) tail


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Films made from a blend of poly(epsilon-caprolactone) and poly(vinyl chloride) (PCL/PVC) retained high crystallinity in a segregated PCL phase. Structural and morphological changes produced when the films were exposed to high potency ultraviolet (UV) irradiation for 10 h were measured by UV-Vis spectroscopy (UV-Vis), Fourier Transform Infrared Spectroscopy (FTIR), and Scanning Electron Microscopy (SEM). They were different to those observed with homopolymer PCL and PVC films treated under the same conditions. The FTIR spectra of the PCL/PVC blend suggest that blending decreased the susceptibility of the PCL to crystallize when irradiated. Similarly, although scanning electron micrographs of PCL showed evidence of growth of crystalline domains, particularly after UV irradiation, the images of PCL/PVC were fairly featureless. It is apparent that the degradation behavior is strongly influenced by the interaction of the two polymers in the amorphous phase.

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The photodegradation of a 1:1 w/w blend of polycaprolactone and poly(vinyl chloride) has been studied by following carbon dioxide emission during UV exposure. Similar measurements were performed for polycaprolactone and poly(vinyl chloride) homopolymers which were prepared and irradiated in the same way. It was found that the blend gave lower CO2 emission than either of the two homopolymers, indicating that the interaction of the two components in the blend provided a beneficial reduction of photodegradation. It is therefore deduced that the detailed morphological characteristics of the blend have a controlling influence over the photo-oxidation. (c) 2007 Elsevier Ltd. All rights reserved.