Síntese hidrotermal assistida por micro-ondas como metodologia sintética eficiente para obtenção da rede metalorgânica [ZN(BDC)(H2O)2]n

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Comportamento fotofísico do antraceno em sistemas micro-heterogêneos argila-surfactantes-íons metálicos

Argilas constituem uma classe de complexos micro-heterogêneos e podem ser utilizados como substrato para adsorção. O seu comportamento de sorção em fase sólida intensificada pela presença de surfactantes, argilas organofílicas, é um importante fenômeno explorado pela tecnologia ambiental para a remoção de compostos orgânicos policíclicos (hidrocarbonetos aromáticos policíclicos, HPA) da água, introduzidos no ambiente por fontes antropogênicas. Este trabalho tem por objetivo estudar o comportamento fotofísico do antraceno, como modelo de HPA, em sistemas micro-heterogêneos argila-surfactantes-íons metálicos (M(II)= Cd(II), Cu(II), Hg(II), Ni(II) e Pb(II); surfactantes: CTACl; SDS; TR-X100). Os estudos foram conduzidos pelo monitoramento na mudança das propriedades de fluorescência estática e na supressão da emissão do antraceno utilizado como sonda fluorescente. Como supressores foram utilizados os cátions metálicos: Cd(II), Cu(II), Hg(II), Ni(II) e Pb(II). O perfil do espectro de fluorescência e os resultados dos ensaios de supressão da fluorescência da sonda permitiram inferir na localização do sítio de solubilização do antraceno nos sistemas micro-heterogêneos estudados e na conseqüente organização dos mesmos.

A esportivização do skate (1960-1990): relações entre o macro e o micro

O objetivo deste estudo foi apresentar elementos da esportivização da prática cultural skate (1960-1990), como conhecimento para o entendimento da relação entre o micro e o macro processo sócio-histórico do skate. Como fonte de pesquisa histórica para a esportivização do skate no Brasil, dimensão macro, utilizamos a Revista Tribo Skate e para a de Piracicaba/SP, dimensão micro, entrevistamos dois colaboradores a partir do método da história oral. Os resultados evidenciaram que o skate surgiu para gerar fortes tensões agradáveis, suas formas de lazer precedem as formas esportivas e, guardadas as particularidades, os seus processos macro e micro-históricos são interdependentes.

Influência da estrutura do hábitat sobre a ictiofauna de um riacho em uma micro-bacia de pastagem, São Paulo, Brasil

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Time analysis for temporary gravitational capture - Stable orbits

In a previous work, Vieira Neto & Winter (2001) numerically explored the capture times of particles as temporary satellites of Uranus. The study was made in the framework of the spatial, circular, restricted three-body problem. Regions of the initial condition space whose trajectories are apparently stable were determined. The criterion adopted was that the trajectories do not escape from the planet during an integration of 10(5) years. These regions occur for a wide range of orbital initial inclinations (i). In the present work it is studied the reason for the existence of such stable regions. The stability of the planar retrograde trajectories is due to a family of simple periodic orbits and the associated quasi-periodic orbits that oscillate around them. These planar stable orbits had already been studied (Henon 1970; Huang & Innanen 1983). Their results are reviewed using Poincare surface of sections. The stable non-planar retrograde trajectories, 110 degrees less than or equal to i < 180, are found to be tridimensional quasi-periodic orbits around the same family of periodic orbits found for the planar case (i = 180 degrees). It was not found any periodic orbit out of the plane associated to such quasi-periodic orbits. The largest region of stable prograde trajectories occurs at i = 60 degrees. Trajectories in such region are found to behave as quasi-periodic orbits evolving similarly to the stable retrograde trajectories that occurs at i = 120 degrees.

Phase transition in poly(vinylidene fluoride) investigated with micro-Raman spectroscopy

The phase transition from the non-polar a-phase to the polar beta-phase of poly(vinylidene fluoride) (PVDF) has been investigated using micro-Raman spectroscopy, which is advantageous because it is a nondestructive technique. Films of alpha-PVDF were subjected to stretching under controlled rates at 80 degrees C, while the transition to P-PVDF was monitored by the decrease in the Raman band at 794 cm(-1) characteristic of the a-phase, along with the concomitant increase in the 839 cm-1 band characteristic of the P-phase. The alpha ->beta transition in our PVDF samples could be achieved even for the sample stretched to twice (2 X -stretched) the initial length and it did not depend on the stretching rate in the range between 2.0 and 7.0 mm/min. These conclusions were corroborated by differential scanning calorimetry (DSC) and X-ray diffraction experiments for PVDF samples processed under the same conditions as in the Raman scattering measurements. Poling with negative corona discharge was found to affect the a-PVDF morphology, improving the Raman bands related to this crystalline phase. This effect is minimized for films stretched to higher ratios. Significantly, corona-induced effects could not be observed with the other experimental techniques, i.e., X-ray diffraction and infrared spectroscopy.

Electrical and micro structural properties of (Zn, Nb, Fe)-doped SnO2 varistor systems

The electrical and microstructural properties of SnO2-based varistors with the addition of 0.025 and 0.050 mol% of Fe2O3 have been characterised. Electric field (E) versus current density (J) curves showed that the effect of Fe2O3 addition is to increase both the non-linear coefficient and the breakdown voltage. Variations in the potential barrier height were inferred from impedance spectroscopy (IS) analysis. Through transmission electron microscopy (TEM), the presence of precipitates of secondary phases was confirmed. Samples with precipitates displayed poor electrical properties. (c) 2004 Elsevier Ltd and Techna Group S.r.l. All rights reserved.

GRAVITATIONAL LASER BACKSCATTERING

A possible way of producing gravitons in the laboratory is investigated. We evaluate the cross section for electron + photon --> electron + graviton in the framework of linearized gravitation, and analyze this reaction considering the photon coming either from a laser beam or from a Compton backscattering process.

Orbital maneuvers using gravitational capture times

Artificial satellites around the Earth can be temporarily captured by the Moon via gravitational mechanisms., How long the capture remains depends on the phase space region where the trajectory is located. This interval of time (capture time) ranges from less than one day (a single passage), up to 500 days, or even more. Orbits of longer times might be very useful for certain types of missions. The advantage of the ballistic capture is to save fuel consumption in an orbit transference from around the Earth to around the Moon. Some of the impulse needed in the transference is saved by the use of the gravitational forces involved. However, the time needed for the transference is elongated from days to months. In the present work we have mapped a significant part of the phase space of the Earth-Moon system, determining the length of the capture times and the origin of the trajectory, if it comes from the Earth direction, or from the opposite direction. Using such map we present a set of missions considering the utilization of the long capture times. (C) 2003 COSPAR. Published by Elsevier B.V. Ltd. All rights reserved.

Micro-Raman analysis of cubic GaN layers grown by MBE on (001) GaAs substrate

Cubic GaN layers are grown by molecular beam epitaxy on (001) GaAs substrates. Optical micrographs of the GaN epilayers intentionally grown at Ga excess reveal the existence of surface irregularities such as bright rectangular structures, dark dots surrounded by rectangles and dark dots without rectangles. Micro-Raman spectroscopy is used to study the structural properties of these inclusions and of the epilayers in greater detail. We conclude that the observed irregularities are the result of a melting process due to the existence of a liquid Ga phase on the growing surface.

FERMION HELICITY FLIP IN WEAK GRAVITATIONAL-FIELDS

The helicity flip of a spin-1/2 Dirac particle interacting gravitationally with a scalar field is analyzed in the context of linearized quantum gravity. It is shown that massive fermions may have their helicity flipped by gravity, in opposition to massless fermions which preserve their helicity.

Gravitational interactions of integrable models

We couple non-linear sigma-models to Liouville gravity, showing that integrability properties of symmetric space models still hold for the matter sector. Using similar arguments for the fermionic counterpart, namely Gross-Neveu-type models, we verify that such conclusions must also hold for them, as recently suggested.