72 resultados para Waste valorizations


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PURPOSE:To investigate the effects of occupational exposure to waste anesthetic gases on genetic material and antioxidant status in professionals during their medical residency. METHODS:The study group consisted of 15 medical residents from Anesthesiology and Surgery areas, of both genders, mainly exposed to isoflurane and to a lesser degree to sevoflurane and nitrous oxide; the control group consisted of 15 young adults not exposed to anesthetics. Blood samples were drawn from professionals during medical residency (eight, 16 and 22 months of exposure to waste anesthetic gases). DNA damage was evaluated by comet assay, and antioxidant defense was assessed by total thiols and the enzymes glutathione peroxidase (GPX), superoxide dismutase (SOD) and catalase (CAT). RESULTS:When comparing the two groups, DNA damage was significantly increased at all time points evaluated in the exposed group; plasma thiols increased at 22 months of exposure and GPX was higher at 16 and 22 months of exposure. CONCLUSION:Young professionals exposed to waste anesthetic gases in operating rooms without adequate scavenging system have increased DNA damage and changes in redox status during medical residency. There is a need to minimize exposure to inhalation anesthetics and to provide better work conditions.

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The disposal of chemical waste and the precision of analyses of the neutral (NDF) and acid (ADF) detergent fiber contents were evaluated utilizing conventional (Van Soest) and alternative methods of analyses. The recovery of acetone promoted both economic and environmental gains, with a recovery rate of 84.12%. The precision of the analyses was not observed in most of the determinations with reutilization of chemical waste in all the analytical methods tested, in spite of promoting decrease in cost, time invested in the preparation of solutions and the disposal of chemical waste.

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This study aimed to investigate physical performance of particleboards produced with waste from sawmills, containing different wood species, and two adhesives: urea-formaldehyde (UF) based resin and castor-oil (PU) based bi-component polyurethane resin. Panels were produced with nominal density 0.8gcm(-3); pressing temperature 110 degrees C; pressing time 10 min; specific pressure 5 MPa. Water absorption (2 and 24h); thickness swelling (2 and 24h); density; and moisture content were investigated. Results confirmed that the produced panels presented compatible physical properties in comparison with other researches referred in literature, proving the feasibility of inputs employed. Panels produced PU showed better performance than those produced with UF.

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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The influence of bovine rumen fluid inoculum during anaerobic treatment of the organic fraction of municipal solid waste (MSW) was studied in this work. The parameters adopted for evaluation were the biostabilization constant of total volatile solids (TVs) and the biostabilization time of the chemical oxygen demand (COD) applied to the reactors. The work was realized in four anaerobic batch reactors of 20 1 capacity each, during a period of 365 days. The proportions between MSW/inoculum loaded in the reactors were Reactor A (100%/0%), Reactor B (95%/5%), Reactor C (90%/10%) and Reactor D (85%/15%). The necessary time for biostabilization of half of the applied COD was 459, 347, 302 and 234 days and the average of methane concentration in the biogas produced was 3.6%, 13.0%, 25.0% and 42.6% for Reactors A, B, C and D, respectively. The data obtained affirm that the inoculum used substantially improved the performance of the process. (C) 2004 Elsevier Ltd. All rights reserved.

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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Techniques of production of enthomopatogenic bacteria are developed aiming to increase the productivity and to reduce the costs of the fermentative process. Like this, it has been using agroindustrial wastes or by-products as nutrient sources in culture medium, having been used, in this study, the manipueira, a by-product of the processing of the cassava flour. Fermentations were performed in flasks of Erlenmeyer of 500 mL containing 250 mL of culture media, conditioned in shaker at 180 r.p.m. and 28°C, and the media were composed by manipueira, in concentrations that varied between 400 and 1000 mL/L. The time of the process varied between 48 and 120 hours. They appraised the following parameters: cellular growth, the production of spores, the reduction of organic matter (COD analysis) and the variation of reduction sugar. Although there was a proportional cellular growth to the manipueira concentration, the production of spores was similar in all the cases, at the end of the process, in spite of the smallest speed of production of the same ones in the highest concentrations. In relation to the variation of COD, it has, also, a percentile minor of reduction in the highest concentrations. In the analysis of variation of reduction sugars, the higher concentrations are the ones that they present larger slowness in the reduction of this.

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This study aimed at evaluating the oils extracted from seeds originating from agro-industrial waste, in order to identify the presence of bioactive compounds. Therefore, determinations of fatty acid profile, triacylglycerols, tocopherol composition, phytosterols, phenolic compounds, total carotenoids, and antioxidant capacity were performed in the oils of grape, guava, melon, passion fruit, pumpkin, soursop, and tomato seeds. Antioxidant capacity analysis was performed by the methods DPPH• , ABTS•+, FRAP, and β-carotene/linoleic acid, besides measure of oxidative stability in the oils. The oils showed to be predominantly unsaturated with high percentage of linoleic essential fatty acid (38.8 to 79.4%), besides presenting significant quantities of tocopherols, phytosterols, and phenolic compounds. Tomato and guava oils showed better results in the antioxidant capacity tests and pumpkin oil had higher induction period in the oxidative stability test (65.3 h). The results obtained in this study collect information that enables the use of new alternative sources of vegetable oils, obtained from agroindustrial waste, which may serve as raw material for food, chemical, and pharmaceutical industries.

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The urban residues put in landfill of the city of Sa˜o Carlos-SP, Brazil, in 2004 represent 58.7 % of decomposed organic material. The aim of this research was to characterize samples of urban solid waste and its organic extracts targeting the use of this residue without damaging the environment. The curves were obtained in a nitrogen atmosphere, a heating rate of 20 C min-1 , the temperature of 30–600 C. In the original sample after humidity loss, an event occured concerning the water constitution in the TG curve with an endothermic peak in the DTA curve. There was a presence of inorganic residue in the ashes. The organic matter present in the USR sample disposed in the landfill is constituted by several polarity, organics compounds from the degradation of lignin, cellulose, lipids, and other materials which thermal stabilities are distinct. The hexane extract features in its constitution two fatty acids, stearic and triacontano´ic, which are nonpolar compounds originating from bacteria present in the residue. The acids groups in extract hexane also were evidenced by X-ray diffraction and FTIR.

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

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This article describes a new approach of recycling the leather waste (shavings) using it as filler in natural rubber foams composites. The foams were prepared using different amounts of leather waste (0-60 parts per hundred of rubber) and submitted to morphological (SEM microscopy) and mechanical analyses (cyclic stress-strain compression). The increase of leather shavings on the composite causes an increase of viscosity in the mixture, which reflects in the foaming process. This results in smaller and fairly uniform cells. Furthermore, expanded rubber has the biggest cell size, with more than 70% of cell with 1000 mu m, while the composite with the higher concentration of leather has around 80% of total number of cells with 100-400 mu m. The mechanical parameters were found to depend on the leather dust concentration. Moreover, the stiffness rises with the increase of leather shavings; consequently, the compression force for expanded rubber was 0.126 MPa as well as the composite with higher concentration of leather was 7.55 MPa. (c) 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 41636.