71 resultados para Gated graphene
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Pós-graduação em Ciência dos Materiais - FEIS
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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
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In Brazil, the proliferation phenomenon of gated communities and land lots had its origins in big cities, such as Rio de Janeiro and Sao Paulo, since 1970. The implementation of these types of intramural housing are done in expanding are as of the city, based on the availability of bigger lots, lower land prices, and the search for are as closer to nature. The gated communities and land lots that, initially, had their architecture only accessible to the higher social classes, as a second home alternative away from urban problems, nowadays they can be reached by other social classes as well. Gated communities and land lots find their way to the center of larger cities, sustained mostly by the speech of real state entrepreneurs, and by its social “status”, a new emerging characteristic of this time period. The expansion of gated communities and land lots also change the cities lands cape and social spatial configuration. This work, therefore, attends the localization of gated communities and land lots spread out in the city of Rio Claro. It analyzes the scale in which the dynamics of the city’s urban expansion influenced the current distribution of these types of housing
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In materials science, the search for technological improvements have become one of the main subject of study of researchers. This is especially true in the case of materials with reduced sizes, in the nanometer scale. Important phenomena to be studied in these cases are the desorption and adsorption on two-dimensional materials, such as graphene. These phenomena are of great importance in the study of interactions between organic films, synthesis or catalysis of reactions on surfaces and even in the creation of nanoscale devices [1, 2, 3, 4]. Between the most important topics related to these phenomena are the storage of gases in low-dimensional systems and the study of nanostructured fuel cells or batteries. In this context we used two different parametrizations for the reactive force field ReaxFF to study the potential barriers and reaction barriers of our system. First we made a study about the Reaction Barriers and Energy Barriers for bonds between graphene and the following atoms: sulfur, fluorine, hydrogen, nitrogen and oxygen. It is important to have this information in order to make it possible to understand how these atoms react with the graphene sheet. Subsequently, we calculate reaction barriers for mixed structures where fluorine is a fixed element bonded to graphene and other element is simultaneously bonded to graphene. This other element (N, O, H or S) is varied in its possible relative positions (ortho, meta and para in relation to fluorine in either: the same side and in the opposite side of the graphene membrane)
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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
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Pós-graduação em Química - IQ
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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)