Nanoparticles of La1-xSrxMnO3 compounds

A nanoparticles of La1-xSrxMnO3 were synthesized using homogenous coprecipitation method. The precipate was washed with water and dried at 80 °C. The samples were characterized by X-ray powder diffraction, transmission electron microscopy (TEM) and electrical resistivity as a function of temperature. The TEM results show that the particle size is in the nanometer scale.

Investigação de Intrusão de Água Salgada em Aqüífero Superficial a Partir de Medidas de Resistividade Elétrica

A site investigation program was carried out to detect salt-water intrusions in a shallow sedimentary aquifer based on electrical resistivity measurements. The site is located close to Paranaguá harbor, in the Paraná State, Brasil. At this site, high chloride concentration contaminated shallow water wells used to supply water for local industries. The site investigation program included a fieldwork, dipole-dipole electrical profiling, resistivity piezocone tests, physical-chemical analysis of sampled water and interpretation of borehole logs. The resistivity piezocone tests provided two simultaneous information; the soil stratigraphy at a very detailed level and a quasi-continuous resistivity profile. Both information adequately complemented dipole-dipole electrical profiling test data. The integration of all test data allowed identifying the contaminated areas as well as guided the location of new water wells to be installed in this area.

Metal-insulator transition in Nd1-xEuxNiO 3 compounds

Polycrystalline Nd1-xEuxNiO3 (0≤x≤0.5) compounds were synthesized in order to investigate the character of the metal-insulator (MI) phase transition in this series. Samples were prepared through the sol-gel route and subjected to heat treatments at ∼1000 °C under oxygen pressures as high as 80bar. X-ray diffraction (XRD) and neutron powder diffraction (NPD), electrical resistivity ρ(T), and magnetization M(T) measurements were performed on these compounds. The NPD and XRD results indicated that the samples crystallize in an orthorhombic distorted perovskite structure, space group Pbnm. The analysis of the structural parameters revealed a sudden and small expansion of ∼0.2% of the unit cell volume when electronic localization occurs. This expansion was attributed to a small increase of ∼0.003 of the average Ni-O distance and a simultaneous decrease of ∼-0.5° of the Ni-O-Ni superexchange angle. The ρ(T) measurements revealed a MI transition occurring at temperatures ranging from TMI∼193 to 336K for samples with x ≤ 0 and 0.50, respectively. These measurements also show a large thermal hysteresis in NdNiO3 during heating and cooling processes, suggesting a first-order character of the phase transition at TMI. The width of this thermal hysteresis was found to decrease appreciably for the sample Nd 0.7Eu0.3NiO3. The results indicate that cation disorder associated with increasing substitution of Nd by Eu is responsible for changing the first-order character of the transition in NdNiO3. © 2006 IOP Publishing Ltd.

Emprego da sondagem elétrica vertical com o método da eletroresistividade no estudo do lixão de Macapá-Ap

Vertical electrical soundings using eletroresistivity method were carried out in the public waste landfill in Macapá - AP, having as a goal to investigate the geoelectrical and hidrogeologic characteristics of the ground. The results of geophysics interpretation allowed obtaining a model of five geoelectrical layers until the depth of 14,6 m. This model is correlated to a sedimentary sequence of clay-silt-sandy with laterite. The main flow of the water table, also determined, is concordant to the topographical gradient.

Variação temporal da resistividade elétrica em contaminação por gasolina

The definition of models and base parameters for application of investigation tools in environment with high complexity are a basic premise to any sciences. The geophysics is a science with solid theoretical base and applications in diversified areas of the sciences geological, astronomical, meteorological, among many others. Its application in environmental studies is relatively recent and needs further research. To understand the behavior of resident contaminants in a dynamic and complex environment as the geological, it requests studies in scale laboratorial, under control of factors seasonality variable. This work simulates a leak of gasoline in soil, under conditions and in laboratory scale, with the objective of monitoring the temporary behavior of the hydrocarbon under the optics of variation of the parameter physical electric resistivity. The results indicate increase of the resistivity in recent periods the contamination, followed for stability in the values and finally fall and return tendency to the natural conditions.

Estimativa do tempo de produção de chorume em aterro controlado por meio de medidas de resistividade elétrica

Landfill is an engineering work that aims at to accommodate residues in the smallest possible space in the soil, with minimum damages to the environment and the public health. One in the constructive forms of a controlled landfill is the excavation of ditches with appropriate dimensions, for disposition of solid residues without compactation or impermeabilization. Liquid effluents generated for similar volumes of residues, disposed in ditches with ages different from closing, it should result in physical and chemical alterations you correlated at the time of residence materials. With base in this hypothesis, measures of electric resistivity were accomplished through the of Eletrical Resistivity geophysical method, on residues ditches closed annually between 12/2001 and 12/2007, localized in control landfill of the Cordeirópolis city (SP). The leachate is a liquid effluent generated by the decomposition of organic matter and characterized by high content in total dissolved solids, whose interaction with geological environment results in alterations in terms of electrical resistivity susceptible to detection for the geophysical instrumental. The results suggest a resistivity reduction for leachate percolation produced for ditches recently and increase progressive of the resistivity for older ditches. The statistical comparative analysis with reference values for the area suggests ages of the finish production and percolation leachate for soil and rock below the ditches.

Estudo geofísico de vazamento de combustíveis em posto de abastecimento

The geoelectrical methods have been widely used in research involving the evaluation and monitoring of areas with environmental risk. This paper presents the results of applying the Electrical Resistivity method by electrical profiling technique to investigate the fuel presence in soil and groundwater proceeding in station gas, located in an urban area Caçapava do Sul (RS), on soil in situ, from modification of Caçapava granite. The results suggest an association between low resistivity anomalies zone with potentially degraded from underground tanks worthless on the form of free phase, now represented as residual phase. The results of the model inversion are consistent with the standards expected for hydrocarbons present in the saturated zone. The electrical resistivity method proved to be an important tool for assessment and environmental monitoring in conjunction with direct methods of investigation.

Aplicação da eletrorresistividade na caracterização do meio hidrogeológico na cidade de JI-paraná (RO)

The Ji-Paraná city (RO) it doesn't possess public system of collection and treatment of sewers, being the waters residuárias produced by the local population thrown at sewages. Traditionally, many inhabitants use wells amazon extracted underground water or tubular shallow in the urban zone. The study accomplished in the Nova Brasília neighborhood for Silva (2009) revealed that the local aquifer is strongly contaminated for nitrate, originated of the decomposition of the organic matter deposited at the sewages local maidservants. With the objective of detecting areas with high concentrations originating from organic compositions of septic sewages, geophysical risings were accomplished, later related with analyses physical-chemistries in samples of groundwaters obtained in several wells installed in the Nova Brasília neighborhood, besides of soil samples descriptions in zone not saturated obtained in wells. The results obtained by the geophysical rehearsals they reveal that the polluting feather not migrates through the zone saturated, arriving with relative easiness to the aquifer, reaching in some points, superior depth to 34 m reached by the geoelectrical profiling.

Monitoramento temporal da pluma de contaminação no aterro de resíduos urbanos de Rio Claro (SP) por meio do método geofísico da eletrorresistividade

Several factors have contributed to the increase the world production of urban solid waste, resulting in difficulties to the correct management and the final environmentally appropriate disposal, in addition to causing serious socio-economic, environmental, and public health troubles. The soil and groundwater contamination by leachate in waste disposal sites is almost always present, leveraging the emergence and/or adaptation of methodologies for environmental assessment of these areas. The geophysical methods, especially the electrical resistivity method, are fast, reliable and low-cost alternative for this purpose. This paper reports the methodology adopted for the temporal monitoring of the plume of contamination of controlled landfill in the municipality of Rio Claro (SP). Electrical resistivity data were obtained in 1999 and 2008, by the resistivity method, using the techniques of vertical electrical sounding and electrical profile. In both years, similar tests were carried out in the same locations within the disposal area. The results indicated that the plume of contamination has resistivity values less than or equal to 50 ohm.m and moves guided by 2 flows: the main, to the southeast, and the secondary, to the west. Relatively to the first series of tests in 1999, the plume of contamination was higher and deeper in 2008, contrary to what was expected for a landfill deactivated for at least 10 years.

Geoelectrical prospection of disseminated sulfide mineral occurrences in Camaquã Sedimentary Basin, Rio Grande do Sul State, Brazil

The mineral exploration is a complex activity that should involve a combination of direct and indirect techniques of geological investigation. The growing demand for base metals in the national and international market provides the revaluation of mineral occurrences that can become deposits and mines. This paper presents the results of the electrical resistivity and induced polarization geophysical methods in azimuthal arrangement, applied in a mineral occurrence of disseminated copper sulfides, previously studied through trenches and core drilling, located in the Camaquã Sedimentary Basin, Rio Grande do Sul State, Brazil. The inversion models indicate the coincidence of high chargeability and low resistivity values. The integration of geophysical data permitted the elaboration of 3D attributes visualization models for the mineralization enclosed in volcanic tuffs. The integrated geophysical and geological analysis indicates the potential of a new mineralized area. © 2012 Sociedade Brasileira de Geofísica.

Caracterização geofísica em aterro de resíduos sólidos para avaliação de condicionantes de instabilidade geotécnica

The disposal of solid waste can create environmental problems, in addition to the potential risk of instability even in planned geotechnical works, such as provisions in stacks or high ends of the landfill, because they represent mere adjustments in civil engineering works. The Leme city, SP, generates about 35 t/day of municipal waste, that are deposited in a landfill located in the Barro Preto neighborhood. This work conducted a geophysical survey, based on geotechnical instability evidence in area, for analysis of the conditioners that cause on the sides leachate resurgence landfill and its relationship to mass movements and ravines installation in cover soil, with consequent waste exposure. The results indicate horizons of low resistivity connected with resurgence points generated by the organic matter decomposition contained in the waste. Such horizons result in leachate concentration in some places, which, in turn, may lead to loss of cohesion of the materials constituting the residues mass. The results are areas with mass flow by rotational movements, which, together with the surface flow of rainwater, evolves into ravines and exposed residues, preferably at the resurgence point. The leachate flow on the surface affects areas beyond the limits at landfill with direct impact on local agriculture and risk to pedestrians using the highway bordered by the landfill beyond the soil and the local aquifer.

Deposition of Al2O3 by resistive evaporation and thermal oxidation of Al to be applied as a transparent FET insulating layer

Alumina thin films have been obtained by resistive evaporation of Al layer, followed by thermal oxidation by means of annealing in appropriate atmosphere (air or O2-rich), with variation of annealing time and temperature. Optical and structural properties of the investigated films reveal that the temperature of 550 °C is responsible for reasonable oxidation, which is accelerated up to 8 times for O2-rich atmosphere. Results of surface electrical resistivity and Raman spectroscopy are in good agreement with these findings. Surprisingly, X-ray and Raman data suggest also the crystallization of Si nuclei at glass substrate-alumina interface, which would come from the soda-lime glass used as substrate. © 2013 Elsevier Ltd and Techna Group S.r.l.

Estudo de propriedades anelásticas de MgB2

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Investigação de propriedades de filmes finos de Al2O3 para aplicação em dispositivos eletrônicos

Pós-graduação em Ciência e Tecnologia de Materiais - FC

Aplicação do eletrocapilaridade na manipulação de microgotas

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)