84 resultados para very fine particles


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Pós-graduação em Geologia Regional - IGCE

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Pós-graduação em Ciência e Tecnologia de Materiais - FC

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Pós-graduação em Geologia Regional - IGCE

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Pós-graduação em Engenharia Mecânica - FEG

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This study investigated the following aspects regarding a soakaway, i.e. an infiltration well: i) entrance filter device; ii) permeability of the geotextile; and iii) emptying time. The 3.6 m³ infiltration well drains a roof area of 241.8 m². The entrance device is made up of layers of sand, gravel and geotextile set on a metal structure. The concrete rings that form the lateral walls were covered with geotextile, and bricks were laid between the soil and concrete rings. The infiltration well remained in operation during the entire testing period, and specific events were simulated to measure the emptying time. Permeability and fine particle tests were carried out after eight months of operation. Samples of geotextile taken from the bottom, the walls and the entrance device presented average permeability reductions of approximately 50.7%, 7.7% and 21.2%, respectively. The sand in the entrance device retained around 34.8% of fine particles and the gravel retained 0.13% in the same period. The infiltration rate was approximately 34.7 mm/h. The R2 coefficient for measured and calculated times was 0.97.

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This work focuses on the study of BaMgAl10O17:Eu2+ (BAM:Eu) nanophosphors prepared by a microwave-assisted combustion procedure and more especially on the polymer/BAM:Eu nanocomposite film suitable for optical devices such as solid-state-lighting. Powder presented a specific nanomorphology, highly friable and thus easily ground into fine particles. They were then homogeneously dispersed into a polymer solution (poly(N-vinylpyrrolidone) or PVP) to elaborate a polymer phosphor nanocomposite. The structural, morphological and optical features of the nanocomposite film have been studied and compared to those of a pristine PVP film and BAM:Eu powder. All the characterizations (XRD, SEM, SAXS, etc.) proved that the blue phosphor nanoparticles are well incorporated into the polymer nanocomposite film which exhibited the characteristic blue emission of Eu2+ under UV light excitation. Furthermore, the photostability of the polymer/phosphor nanocomposite film has been studied after exposure to accelerated artificial photoageing at wavelengths above 300 nm.

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

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This work deals with a red phosphor. Y3BO6:Eu3+, and its corresponding poly(N-vinylpyrrolidone) (PVP)/Y3BO6:Eu3+ luminescent composite film suitable for applications in the next generation of Hg-free lamps based on near ultraviolet (UV) light emitting diodes (LEDs). Well crystallized samples of Y3BO6 powders with the Eu3+ content up to 20 mol% were prepared by the Pechini method. After structural, morphological and optical characterization, the best doping rate of Eu3+ in the matrix was determined to be 15 mol%. This optimal powder, which is highly friable, was easily ground into fine particles and homogeneously dispersed into a PVP polymer solution to give rise to a polymer phosphor composite. Structural and optical features of the composite film have been studied and compared to those of a pristine PVP film and Y3BO6:Eu3+ powder. All the characterization (XRD, SAXS, luminescence...) proved that the red phosphor particles are well incorporated into the polymer composite film which exhibited the characteristic red emission of Eu3+ under UV light excitation. Furthermore, photostability of the polymer/phosphor composite film under UV-LED irradiation was evaluated from exposure to accelerated artificial photoageing at wavelengths above 300 nm.