Efeitos fotocrômico e termocrômico em ormosils dopados com azobenzenos

The sol-gel process and the wide variety of alkoxides commercially available have facilitated the processing of various Organic-Inorganic Hybrid Materials. In general, the hybrids are excellents matrix to incorporate organic or inorganic dopants that presents photochromic, thermochromic, and halochromic effects and in some cases photorefractive effects. The GPTS-TEOS hybrid matrix when deposited in the form of film is very resistant, adherent, has excellent transparency in visible region and allows to be doped with various azo-dye and metal salts of unusual oxidation states. One of the main characteristics of the azo-dyes when immersed in some hybrid matrix , is the capacity to isomerizes through group Azo (-N = N-) would can be commutated between the Cis (Z) and Trans (E) configurations by means of light or heat. Our goal was through the sol-gel process to prepare hybrid films of GPTS-TEOS doped with azo-dyes Methyl Red and Disperse Red 1, and characterize them optically. The characterizations are performed using techniques of UV / Vis spectroscopy, to identify changes in the absorption band of azo-dyes in the presence of optical pumping, (photochromic effects), in function of temperature (thermochromic effect). These properties are of wide scientific and technological interest because they will contribute to the confection Smart Windows (windows sensible to light), temperature sensors monitored optically and also in the recording of amplitude and phase diffraction gratings

Estudo da malha urbana e proposta de implantação de um parque tecnológico na cidade de Jacareí

The city of Jacareí above average presents a economic growth of the State of São Paulo, fact that comes if reflecting in the quality of life of the citizens, due to lack of infrastructure to hold the growth rhythm. Today the commercial center of the city, presents diverse urban conflicts with its narrow streets and sidewalk making it difficult to the locomotion and the access the areas and building of public interest gifts in this region. Aiming at the arrival of four multinationals that already make gratings investments in the city and the promise of growth and dinamização of the still bigger economy for the next years, this work studies the urban mesh of the city for a possible implantation of a Technological Park that serves of inductive element of the development of the region north of the city of Jacareí. Place, in which, they are being constructed the multinationals and where, according to Managing Plan of the city, the city hall intends to urbanizar in the next years, with the objective to minimize the areas of urban conflict in the commercial center and of form to absorb the growth of the city. From the study of old experiences, of works carried through on the subject, interviews with city planners of the e region after visits to the place, we will go to argue the possibility of implantation of the Technological Park in Jacareí and optimum place for its installation

Optical filters and resonant cavities based on di-ureasil organic–inorganic hybrids

Sol–gel derived poly(oxyethylene)/siloxane organic–inorganic di-ureasil hybrids containing different amounts (20–60% mol) of methacrylic acid (McOH) modified zirconium oxo-clusters (Zr-OMc) were processed as thin films and transparent and shape controlled monoliths. Laser direct writing was used to create channel waveguides, Bragg gratings, Fabry–Perot cavities and optical filters. The resulting Fabry–Perot optical cavity displays a free spectral range of 16.55 GHz and a fringe intensity contrast of 5.35 dB. Optical rejection values between 6.7 and 10.4 dB were obtained by varying the amount of the Zr-OMc oxo-clusters.