IMPACTOS AMBIENTAIS DECORRENTES DE VAZAMENTO DE GÁS NATURAL DE BAIXA E MÉDIA PRESSÕES, NA ÁREA URBANA CENTRAL DO MUNICÍPIO DE SÃO PAULO

Com a busca por fontes de energia alternativas, o gás natural vem adquirindo posicionamento de destaque por seu relativo baixo custo de aquisição ao consumidor final e por apresentar reduzidos impactos na implantação de dutovias, comparados com outras fontes de energia (hidroelétrica e fissão). O presente trabalho foi direcionado para a verificação de possíveis impactos oriundos de vazamentos em tubulações de gás em sua fase operacional. A área de estudo localiza-se no Município de São Paulo; sua escolha deve-se por apresentar tubulações centenárias que demandam constantes intervenções ou manutenções e pela fácil captação de amostras para análise. Foram amostrados 40 pontos e nestes analisados aspectos dos meios antrópico, biótico e físico-químico. O método adotado fundamentou-se na caracterização dos dutos de gás e sua manutenção, no diagnóstico ambiental, considerados os fatores ambientais solo, ar, flora, fauna, condições de vida da população e paisagem urbana, e posterior identificação de impactos, nas situações de alteração dos impactos ambientais. Os resultados demonstraram que qualquer vazamento de gás gera uma alteração em pelo menos um fator ambiental, denotando um impacto. Novas linhas de estudo são propostas como melhor análise químico-física do material exposto ao contaminante e reações químicas do odorante com o solo que teve contato.

Metodologia para a Quantificação da Exalação do Gás Radônio em Rochas Ornamentais

Este trabalho descreve um método para quantificar o gás radônio exalado em rochas ornamentais implementado no DPM/IGCE/UNESP de Rio Claro. O gás radônio é radioativo, sendo considerado cancerígeno, o que reforça a necessidade da realização de estudos focando a sua presença no meio ambiente. Alguns métodos para quantificar o radônio exalado de rochas são complicados, precisando de várias etapas em laboratório para que sejam obtidos os dados, o que conduz à perda do gás na medida em que aumenta o tempo para a aquisição dos resultados. A técnica empregada é de fácil uso para se obter os resultados, adquiridos na forma de ciclos de medidas. O principal desafio consistiu no acondicionamento das amostras para a análise em recipiente que mantivesse certa pressão de vácuo interna por período relativamente longo, equivalente aos 25 dias necessários para que o 222Rn atinja seu equilíbrio radioativo, e que permitisse sua conexão ao aparelho medidor do gás sem interferência do ar do meio externo. Os procedimentos permitiram a realização do monitoramento e a quantificação do radônio para várias amostras de rochas ornamentais, contribuindo para o avanço das pesquisas sobre o comportamento e difusão desse gás em materiais pétreos.

Estudo numérico de modelos de arrasto e do coeficiente de restituição no escoamento gás-sólido em leito fluidizado

Pós-graduação em Engenharia Mecânica - FEG

Aparelho evaporador de extrato orgânico de amostras sobre fluxo de gás, em especial, para análise cromatográfica

Constituído por uma bacia (1) para banho-maria circular, preferencialmente em aço inox sem soldas, provida de resistência tubular (2) blindada (1000W) permitindo temperaturas de 30 a 100<198>C, ligada a um termostato.

Efeitos da parede de levedura em dieta úmida na microbiota fecal, na produção de gás e na morfologia intestinal de gatos adultos

The aim of this study is to evaluate the effects of yeast extract (EPL) in the moist diet on the fecal microbiotal, gas production and intestinal morphology of adult cats. Twenty adult cats from both sexes were randomly assigned to four treatments: 1) moist commercial diet (control); 2) control + 0,2% yeast extract dry matter; 3) control + 0,4%; and 4) control + 0,6%. Fecal microbiology and intestinal morphology were performed by radiographic, ultrasound, colonoscopy and intestinal biopsy exams for histology. There were no significant differences (P>0,05) for lactic acid bacteria counts and clostridium-reductor, gas area in the bowel (radiographic), wall thickness of the colon (ultrasound) and colonocytes count/globet cells (histology). Through colonoscopy, changes in characteristics of the intestinal mucosa in animals receiving treatment 4 were noticed. It is concluded that the addition of up to 0.6% EPL had no effect on the parameters evaluated, but further studies are needed to understand the action mechanisms and additive effects for domestic cats.

Potencial de produção de gás metano e dióxido de carbono in vitro dos ingredientes utilizados em dietas para ovinos

This study aimed to evaluate the potential of CH4 and CO2 in vitro production of soybean hulls, sunflower meal, corn, citrus pulp and corn silage. Four rumen-cannulated sheep were fed diets containing the evaluated ingredients at 40:60 forage:concentrate ratio. The gases produced by samples incubation were measured by injection into a gas chromatograph equipped with flame ionization detector. The experimental design was completely randomized with repeated measures, with three replicates for each evaluated food at four different periods. Under the experimental conditions, we verified different potential gas production among the ingredients. The citrus pulp meal was the ingredient with the greatest potential for CO2production. Corn silage and soybean hulls showed the greatest potential while citrus pulp and sunflower meal showed the least potential for CH4 production, when expressed in mL/g of degraded dry matter; therefore, they can be considered, among the evaluated ingredients, those with the lowest environmental impact.

Fotocatalisadores a base de dióxido de titânio modificados com nióbio para redução de gás carbônico a metanol

Pós-graduação em Química - IQ

O grafeno versus gás de elétrons 2d: filtro fano relativístico de spins por meio de pontas de afm e stm

Pós-graduação em Ciência dos Materiais - FEIS

Micro-fungos de interesse para o setor de petróleo, gás e biocombustíveis

Oil is a hydrocarbon mixture of various sizes, including saturated and aromatic compounds. Natural gas is a mixture of gaseous hydrocarbons and its main component is methane. In our society, the great demand for these fuels requires fast extraction, transportation and refining, increasing the number of accidents that compromise the environment. Oil is a finite resource and it is necessary to reduce the problems related to the question concerning environmental pollution which has encouraged the search for alternative fuel sources in our country. So today we have two major biofuels: ethanol and biodiesel. Concurrently, many studies have been done directed toward the isolation of microorganisms capable of degrading petrochemical industrial wastes, most of them using as a source of isolation soil and water collected in a contaminated environment. Isolation from alternative substrates has emerged as a new strategy that has provided satisfactory results. In this work, we present the leaf-cutter ants of the Attini tribe as a source for the isolation of micro-fungi with the potential for hydrocarbon degradation. These insects have a social way of life and a highly specialized system of intra and interspecific communication, which is based on the recognition of individuals through volatile chemical compounds, the majority hydrocarbons, stored in their exoskeleton. The micro-environment exoskeleton of Attini ants (genus Atta) used in this work proved to be a rich source of microbial biodiversity, as other studies have found. The flotation isolation technique applied here allowed the achievement of 214 micro-fungi, 118 representatives of the dematiaceous fungi group and 96 hyaline filamentous fungi. They were submitted to toluene degradation tests and at least one strain of each genus presented good results, namely Teratosphaeria, Exophiala, Cladosporium, Penicillium, Aspergillus... (Complete abstract click electronic access below)

Estudo da variação da porcentagem e da estimativa de geração de gás metano para o aterro sanitário do município de Rio Claro - SP

Increased demand for energy and the search for alternative energy sources are remarkable and current facts. The management of domestic solid waste is also part of the issue in view of the possibility of power generation in existing landfills, which could provide financial autonomy to the system of waste management and improve the environmental balance of landfills in Brazil, currently only used for final solids disposal. Landfill gas is a viable alternative energy source has been tested in landfills in the World and in Brazil. Thus, the research aimed to evaluate the percentage of methane (CH4) present in three sinks of gases from a landfill in the municipality of Rio Claro – SP (Brazil), and to estimate the potential methane generation over its life through the application of a mathematical model. As a result it was found that in general the percentage of methane present in the gases is significant, between 50 and 62%. It was also noted that waste with disposal time between 8 and 12 months already are in the methanogenic stage. Finally, there was a tendency to increase the generation of methane in the transition periods of rain and drought

Foraminíferos em um transecto de manguezal da Ilha do Cardoso (SP): distribuição em função da frequência de inundação e modelos para reconstruções paleoambientais no setor de petróleo & gás

O estudo do conteúdo de foraminíferos de 8 amostras de sedimentos superficiais coletados em manguezal do norte da Ilha do Cardoso, sul do Estado de São Paulo, no verão (período chuvoso) de 2001, ao longo de um transecto no sentido da Baía de Trapandé para o interior, revelou dois segmentos distintos: a) uma planície inferior lamosa, com menor tempo de exposição sub-aérea e maior diversidade específica, dominada por Ammotiumcassis, A.salsum, Arenoparrella mexicana e Trochamminainflata, com abundância expressiva de Caroniaexilis na parte mais baixa e de Miliammina fusca na parte mais alta; b) uma planície superior arenosa, com maior tempo de exposição sub-aérea e menor diversidade, dominada por M. fusca e com abundância expressiva de T. inflatana parte mais baixa. Os sedimentos investigados são colonizados por foraminíferos exclusivamente aglutinantes, representados por 21 espécies de 16 gêneros. Dados de abundância relativa, riqueza, diversidade e equitatividade das espécies ao longo do transecto são apresentados, bem como os valores de salinidade, pH, oxigênio dissolvido e temperatura, medidos a partir da água intersticial dos sedimentos no momento da coleta das amostras. São feitas comparações com um estudo anterior, similar, que focalizou amostras coletadas, nos mesmos pontos, no inverno (período seco) de 2002. Os resultados obtidos interessam às análises de sistemas estuarinos modernos e antigos, bem como a projetos envolvidos com o diagnóstico do estado de conservação de áreas litorâneas, sendo úteis ao Setor de Petróleo e Gás

Estudo da fluidodinâmica de uma mistura de sólidos em um leito fluidizado gás-sólido

Fluidization consists in a bed of solid particles acquire fluid behavior by using a fluid (in this case air) flowing through the solid particles. Because of this, it can be a good mix of these materials, as well as to show increased rates of heat and mass transport. The fluid flowing through the spaces between the particles gives an interstitial velocity, that if is too low does not cause movement of the particulates. The gradual increase in speed will generate small vibrations between the particles promotes its fluidization. Our study focus in the fluid state of solid bed , when the fluid velocity reaches a state where the drag forces are sufficient to support the weight of the solid particles making these solids behave like fluids . Knowledge of the minimum velocity required to fluidize that particles is of great importance since below this speed there is no fluidization, and far above it, the solids are carried out of the bed. The fluidized bed reactor is widely used in physics and engineering, particularly in gas-solid fluidization, with emphasis on thermochemical processes

Análise microestrutural de tubos API P110, para prospecção de petróleo e gás, soldados pelo processo HF/ERW

On the grounds of the great advances achieved over recent years, the process HF/ERW (High-Frequency/Electric Resistance Welding)welded pipe have played an active role in the oil and gas industry for deep water applications, at high and extremely low temperatures, under high pressure and in highly corrosive environments, gradually replacing manufactured pipes by other processes. However, studies have shown that defects in the welded joints are a the leading causes of pipelines failures, which has required the determination of toughness values in this region, in compliance with the strict recommendations of the codes and standards with manufacturers and construction companies, on the oil and gas sector. As part of the validation process required toughness values, this research project focuses on a microstructural analysis in HF / ERW tubes microalloyed, steel grade API 5CT P110, designed to explore oil and gas in deep waters, the subject of strategic relevance to the country because of the recent discoveries in the Santos mega fields: Tupi and Libra (pre-salt). In this scientific work will be presented and discussed the results of mechanical tensile and Charpy, a few CTOD tests curves (showing the trend of toughness values to be obtained), and the microstructures of the base material obtained by optical microscopy, with special emphasis on the formation of nonmetallic inclusions in the welded joint

Analise técnico-econômica de um gaseificador Downdraft e de filtros para limpeza de gás de síntese

The biomass gasification systems have been used for a long time and prove to be a good alternative to the generation of energy problems. This type of management requires a simple installation and maintenance which gives them a high availability. In Biomass project via Call CTEnerg 33/2006-1, funded by the Ministry of Science and Technology - MCT - Brazil, the Group Energy Systems Optimization – GOSE - at FEG - UNESP built and tested two prototypes of gasifiers. These is fed with 25 kg / h of dry wood (chips), and 50 Nm3 / h of air to produce gas at a flow rate of approximately 70 Nm3 / h of wood (syngas) at a temperature approximately 600 ° C. In this work of graduation, studies were conducted on the materials used in both the gasifier as well as cleaning the filter synthesis gases. The system of gas cleaning and conditioning is vital to ensure the life of the Internal Combustion Engine. In this case the studies of different filters for small gasification systems (properties, materials used, characteristics, types, etc.) are very relevant to its use in the prototype of the college campus. Were also performed a technical and economic analysis of a cogeneration system that consists in the combination of the downdraft gasifier studied in this work, an internal combustion engine, two heat exchangers and a SRA (absorption system refrigerator). Were calculated the costs of electricity generation, hot water and cold water. Finally, we analyzed the economic feasibility of the project