Aminas biogênicas e polifenóis no leite e queijo de ovelhas da raça Bergamácia suplementadas com óleo ou farelo de linhaça (Linum usitassimum L.)

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Subsídios geomorfológicos para a avaliação da sensibilidade ambiental ao óleo: o caso do baixo curso do rio Tietê (SP)

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Estudos sobre a utilização de pentóxido de nióbio nanoestruturado na produção de biodiesel

In heterogeneous catalysis, numerous elements such as titanium and iron have been studied as nanoscale catalysts, but little is known about the use of niobium in nanocatalysis. The nanostructured particles have intrinsic and different physicochemical characteristics with great potential for use in industrial scale. Brazil having the largest known worldwide niobium reserve has the great challenge of creating pioneering technologies with the metal. Biodiesel is an alternative fuel and renewable substitute for regular diesel. Being biodegradable, non-toxic and have CO2 emissions lower than regular diesel, it contributes to the environment and to the independence from oil. The aim of this work was initially synthesize nanoscale particles of niobium pentoxide (Nanospheres, nanorods, nanofibers, nanocubes) from the sol-gel technique. The characterization of different nanoscale structures obtained was performed using different analytical techniques such as x-ray diffraction (XRD) and Scanning Electron Microscopy (SEM). The synthesized nanometer niobium oxide will be used as a heterogeneous catalyst in biodiesel synthesis from commercial soybean oil, checking in detail what the effect of morphology is presented (Nanospheres, nanorods, nanofibers, nanocubes) in the yield of biodiesel synthesis, comparing these results with those already described in literature for the amorphous niobium oxide and other oxide catalysts. The biodiesel obtained was characterized by gas chromatography system equipped with a FID detector

Avaliação das características geomorfológicas na sensibilidade ambiental a derrames de óleo: estudo de caso no baixo curso do rio Piracicaba

The environmental sensitivity charts to oil constitute an important tools for contingency planning and assessment of damage caused by oil spills. The main objective of this article is to evaluate the sensitivity of river dynamics to oil spills. Through the identification and mapping of fluvial geomorphological features will be assessed the importance of these resources in terms of sensitivity to oil spills. Through satellite images, was obtained the geomorphological mapping and geomorphological parameters were analysed, in order to characterize the environmental sensitivity to oil spills and derivatives. Therefore, the implementation of an environmental sensitivity mapping from geomorphological parameters contributes to the mapping of the environmental sensitivity to oil, which will assist in the containment and cleanup procedures in case of accidents in fluvial and terrestrial environments, that are slightly studied in Brazil

Co-digestão anaeróbia de dejetos de suínos, níveis de inclusão de óleo de descarte e microrganismos lipolíticos redução do impacto ambiental

The objective of this work for evaluating the potential of biogas and methane productions and still and reductions in levels of total solids (TS), volatile solids (VS) and neutral detergent fiber (NDF) of the co-digestion anaerobic digestion in digesters fed with swine manure plus disposal of oil and lyophilized microorganisms. For assay development substrates were prepared containing 4% TS, consisting of swine manure, disposal oil (the proportions 8, 10 and 12% oil content in relation to the substrate TS), lyophilized microorganisms (Biol-2000 ® - concentrations of 10 g/m3 and 15 g/m3 ), water for dilution of this waste and inoculum for batch digesters supply. There was no significant difference with respect to reductions in TS, VS and NDF constituents, providing very significant reductions in average 54.14; 62.79 and 49.16% respectively. Regarding the potential of biogas production, the highest yields occurred in digesters supplied with 10% oil and 15 g/m3 of Biol®, being 0.43 and 0.54 L of biogas per kg of TS and VS added, respectively, similar results were found when assessed the potential for methane production, with higher values (0.22 and 0.27 L of methane per kg of TS added and VS, respectively) obitidos the same treatment. The inclusion of 15 g/m3 in Biol® substrate composition containing swine manure and 10% of oil improves the yields of biogas and methane.

Extração e caracterização qualitativa do óleo da polpa e amendoas de frutos de macaúba [Acrocomia aculeata (Jacq) Lodd. ex Mart] coletada na região de Botucatu - SP

The international energy situation indicates to the depletion of oil reserves in the short term. Brazil, considering its potential, has sought through public policy, encourage the study of alternative forms of energy. Many of these forms are based on sub-products and agricultural products, especially the ethanol industry for fuel purposes. Another alternative of vegetable origin, most recently discussed, would be the production of fuel oil called biodiesel. The study aimed to extract and measure the pulp oil production of macaúba palm [Acrocomia aculeata (Jacq) Lodd. ex Mart], collected in Botucatu (SP). In addition, the qualitative analysis of the pulp and almond oil are determined. The results showed low productivity in oils, compared to the reported for macauba natural populations of Minas Gerais. The qualitative analysis of the macauba pulp shows to be rich in long chain fatty acids, while the almond have significant amounts of lauric acid.

Análise parâmetros elétricos consumo, fator de carga e demanda de empresas de refino de óleo vegetal

Empresas muitas vezes tem seu consumo de energia elétrica descontrolados por possuírem motores elétricos muitas vezes super-dimensionados, trabalhando em vazio ou em horário de pico. Sendo este tipo de atividade responsável por grande parte do gasto energético da empresa. Existem dois fatores que avaliam o modo de utilização desta energia, denominados fator de potência (fp) e fator de carga (fc), que indicam a eficiência e racionalidade da forma de utilização da energia elétrica, respectivamente. A necessidade de uma avaliação global da utilização da energia, levando em consideração os dois fatores citados, é realizada por especialistas da área energética para a determinação da situação real da empresa. Podendo ser uma tarefa árdua muitas vezes demorada. Para isto é necessária uma análise estatística descritiva dos dados. Este trabalho tem como objetivo realizar esta analise de dados de uma empresa de refino de óleo vegetal.

Qualidade do óleo bruto de grãos de crambe (Crambe abyssinica Hochst) sob diferentes métodos de secagem

The Culture of crambe became promising since its grains presents high oil content. The methods of drying may influence the quality of crude oil extracted from the beans, depending on the way it is managed. This study goal was to evaluate the influence of different drying methods on the quality of the crude oil extracted from crambe grain. The experimental design was completely randomized with five treatments (drying with heated air, natural air, yard, shade, and at the field), and with four tests for each. In order to check the quality of the grains, we performed an analysis of fat acidity, and to evaluate the crude oil quality, we conducted analysis of iodine value, acid value, water content, density at 20ºC, and a kinematic viscosity at 40°. After obtaining the data, the results were submitted to analysis of variance. When significant means were detected, they were compared by t-test (p ≤ 0.05). The method of drying with heated air provided a lower rate of fatty acid in grains. The drying methods evaluated did not compromise the quality of the oil extracted from the crambe grain.

Comparação do custo de produção do crambe (Cambe abyssinica Hochst) com outras culturas oleaginosas em sistema de plantio direto

Biodiesel is a reality in Brazil, due to the National Program of Biodiesel Production and Use (PNPB), which became mandatory in 2008 in adding 2% biodiesel in all diesel sold in a blend known as B2. The agribusiness sector responded to the federal program, facing many difficulties in biodiesel production, which highlights the supply of raw material. Problems related to biodiesel production were mainly the shortage of vegetable oil, because of demand from domestic and foreign markets, and rising prices of raw materials available for production, making this biofuel production economically feasible, even in Brazil, where agricultural production costs are among the most competitive in the world. The crambe is a specie that has aroused the interest of Brazilian producers due to oil content, hardiness, and mechanized cultivation, mainly for being a winter crop, it becomes one more option for farmers in this period. In addition, you can compose systems of crop rotation as well as being used as ground cover in winter. The aim of this study was to evaluate the potential for productive and cost of production of crambe, conducted in no-tillage system, to compare these parameters with other oil crops such as sunflower, canola and soybean. The trial was conducted in the agricultural year 2008 at the Experimental Farm Lageado belonging to the Faculty of Agronomic Sciences - UNESP, located in Botucatu - SP. The estimated yield was 1.507,05 kg ha-1, resulting in a production of 561,94 liters of oil per hectare. The cost of installation and conduct of crambe per hectare was R$ 875,87, resulting in a cost of R$ 1,56 per liter of oil, the lowest cost among the oilseed crops analyzed.

Efeito imediato do método de secagem na qualidade de sementes de crambe

Crambe (Crambe abyssinica Hochst) seeds have high oil contents and its growth in Brazil aims to produce bio diesel. The crambe seeds production and commercialization began a few years ago. Research in technology production is essential and it is also important to use high quality seeds regardless of the technological level employed in the crop production. One of the factors that affect seed quality there is the drying process. Seed drying performed properly can reduce seed moisture content for storage without decrease in its qualitative characteristics. The aim of this study was to evaluate the immediate effect of natural and artificial drying methods (using heated and unheated air) on crambe seeds quality. The seeds were produced at Fazenda Lageado, Faculdade de Ciências Agronômicas, UNESP, Botucatu/SP, on April 2009. Seeds were submitted to the following drying methods: a) seed drying in the shade with natural ventilation; b) artificial drying method using heated air; c) artificial drying method using unheated air; d) drying on ceramic patio; e) drying on the mother plant. The seeds were evaluated immediately after drying. The following tests were performed: seed moisture content; standard germination; first count of germination; seedling emergence; emergence speed index and electrical conductivity. The experimental design was randomized blocks and the data obtained was subjected to analysis of variance, worth means being compared by Tukey test at 5% probability. There was no significant difference among drying treatments in relation to: germination rate, first count of germination, electrical conductivity, seedling emergence and emergence speed index. The highest percentage of abnormal seedlings was obtained on treatment with heated air drying. The drying on the mother plant method showed the lower percentage of dead seeds. The drying methods studied did not cause an immediate effect on crambe seeds quality, which showed high percentage of dormant seeds post-harvest.

Remoção pela chuva de diferentes formulações de flutriafol aplicada em soja, com e sem a adição de óleo mineral na calda

The present study had as objectives to verify the effect of rainfastness of different flutriafol formulations, in laboratory conditions, applied on soybean plants with and without the oil adjuvant in the spray solution, as well as to verify the influence of the oil on the droplet spectrum. The experiment considered ten spray solutions related to five treatments containing flutriafol (four formulations of flutriafol and a flutriafol mixture with tebuconazole), all applied with and without mineral oil. Particles size analysis were based on the determination of the droplet spectrum, medium volumetric diameter and the amount of droplets below 100 μm. All the solutions were sprayed with Teejet XR 11001 (fine droplets). Droplet spectrum was determined in a direct way by diffraction of laser (Malvern Mastersizer S®, version 2.15). Confidence interval at 90% degree was used to compare the mean data. The results showed that the addition of mineral oil in the solutions provided tendencies of larger medium volumetric diameter, smaller amount of droplets below than 100 µm and better uniformity of the droplet spectrum. All of the solutions with the addition of mineral oil presented larger adhesion and/or absorption of the fungicide on the plants in comparison with the solutions without oil. The increase of the time between the application and the rain, caused reduction of the fungicide removal, independently of the rain intensity. The increase of the amount of rain didn't change the relative behavior among the solutions; however, this larger amount of rain caused larger fungicide removal along the time. It was observed significant removal of flutriafol by the rain up to 48 hours after the spray application.

Avaliação da capacidade de renovação do epitélio do mesêntero e seus efeitos no potencial reprodutivo de fêmeas adultas de Ceraeochrysa claveri (Neuroptera: Chrysopidae) alimentadas durante a fase larval com óleo de nim (azadirachta indica A. JUSS)

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)