345 resultados para Contração de polimerização
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This study assessed the surface microhardness of compound resins cured by different light sources. Methods Three micro hybrid (Vit-l-escence, Amelogen Plus, Opallis) and one nanoparticle (Filtek Z350, 3M ESPETM Dental Products, St. Paul, USA) compound resins were selected. The resins were polymerized by a halogen light unit (Ultralux, Dabi Atlante, Ribeirão Preto, Brasil) with two tips, one semi-guided made of glass and another of painted acrylic and a LED-based source (UltraLume 2, Ultradent®, South Jordan, USA). Specimens constructed from a circular aluminum matrix were photopolymerized for 40 second after they received the compound resin and stored dry for 24 hours. After this period, a Vickers surface microhardness assay was performed, measuring the top (hardness 1) and base (hardness 2) surfaces four times each. Variance analyses were complemented by Newman-Keuls method, with significance set at 5%. Results The Opallis (FGM, Santa Catarina, Brasil) resin subjected to UltraLume 2 (Ultradent®, South Jordan, USA) obtained the lowest mean hardness values for the top surface. The Vit-l-escence (Ultradent®, South Jordan, USA) compound cured by Led UltraLume 2 (Ultradent®, South Jordan, USA) and by Ultralux PCP (Dabi Atlante, Ribeirão Preto, Brasil) halogen light obtained the highest mean hardness, followed by the Filtek Z350 (3M ESPETM Dental Products, St. Paul, USA) resin subjected to UltraLume 2 (Ultradent® South Jordan, USA). The Opallis (FGM, Santa Catarina, Brasil) resin cured by LED UltraLume 2 (Ultradent®, South Jordan, USA) also obtained the lowest mean hardness for the base surface and the Vit-L-Escence (Ultradent®, South Jordan, USA) resin obtained the highest value, followed by Amelogen Plus, when cured by Ultralux (Dabi Atlante, Ribeirão Preto, Brasil) using the semi-guided tip. Conclusion The polymerization and, consequently, the microhardness achieved by the LED unit was equivalent to those achieved by conventional halogen units for three of the four composites tested.
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Introduction: It is known that self-etching adhesive systems can act as semi-permeable membranes. Objective: Evaluate the effects of additional layer of hydrophobic resin on the microtensile bond strength of self-etching one-bottle adhesives. Material and method: Sixty bovine incisors were used in this study. The facial enamel surfaces of the crowns were abraded with silicon carbide paper to expose flat, mid-coronal dentin surfaces. The following adhesives were used: Clearfil Tri S Bond (CTSB), AdheSE One (ADH) and One Coat 7.0 (OC). Each material was tested with and without applying an additional layer of hydrophobic material from the same manufacturer. Z-350 composite resin was inserted in three 1 mm increments. All adhesive restorative procedure was performed under simulated pulpal pressure and the microtensile test was performed immediately after curing the composite resin. Data were submitted to ANOVA and Tukey test (p < 0.05). Result: For all adhesives tested, the worst results were observed in groups which the additional layer of hydrophobic resin was not applied. Conclusion: The application of additional layer of hydrophobic material can improve the adhesion of self-etching all-in-one adhesive systems.
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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
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Pós-graduação em Desenvolvimento Humano e Tecnologias - IBRC
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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
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On heat cured acrylic resins by microwaves energy the action of electromagnetic waves on methylmethacrylate promote the polymerization process. However, part of this energy is absorbed by the gypsum present in the flask and the function of this gypsum is to maintain the characteristics of specimen, nevertheless is unknown in the literature as the amount of water present in this gypsum affects the characteristics of acrylic resin. The proposal of this study was verified if dried gypsum influenced in some properties of the acrylic resins thermally activated by microwaves: presence of porosity, microhardness, roughness, flexural strength and dimensional change. Two different types of acrylic resin for complete denture were utilized: Lucitone 550 e Vipi-Wave and groups were formed: Lucitone 550, polymerization by microwave energy without gypsum treatment; Lucitone 550, polymerization by microwave energy with pretreatment gypsum; Vipi-Wave by microwave energy without gypsum treatment; Vipi Wave, polymerization by microwave energy with pretreatment gypsum; Lucitone 550 control group polymerization in hot water bath. For both situations were performed analysis of microhardness and porosity three different metallic shaped specimens were formed with followed dimensions: 2,0x2,0x2,0cm (8cm3); 2,0x2,0x1,0 (4cm3) e 2,0x2,0x0,5 (2cm3). Standardized wax specimens was used to prepare groups (n=9) and included in glass fiber flasks. The gypsum dry was made by microwave oven cycle (10min and 600W) and then the flasks were maintained in dry oven during two hours. Polymerizations of specimens were made and then polished. Wax patterns #7 obtained from the metal were embedded in plastic flask and following the processes of pressing and polymerization of the resin according to established groups. To evaluate the flexural strength, specimens 65mm x 10mm x 3.0mm from metallic patterns in bar format were made. ...
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A general analysis of the behaviour of "Cebus" shows that when this primate moves position to feed or perform another activity, it presents different ways of locomotion. This information shows that the brachial biceps muscle of this animal is frequently used in their locomotion activities, but it should also be remembered that this muscle is also used for other development activities like hiding, searching for objects, searching out in the woods, and digging in the soil. Considering the above, it was decided to research the histoenzimologic characteristics of the brachial biceps muscle to observe whether it is better adpted to postural or phasic function. To that end, samples were taken from the superficial and deep regions, the inserts proximal (medial and lateral) and distal brachial biceps six capuchin monkeys male and adult, which were subjected to the reactions of m-ATPase, NADH-Tr. Based on the results of these reactions fibres were classified as in Fast Twitch Glycolitic (FG), Fast Twitch Oxidative Glycolitic (FOG) and Slow Twitc (SO). In general, the results, considering the muscle as a whole, show a trend of frequency FOG>FG>SO. The data on the frequency were studied on three superficial regions FOG=FG>SO; the deep regions of the inserts proximal FOG=FG=SO and inserting the distal FOG>FG=SO. In conclusion, the biceps brachii of the capuchin monkey is well adapted for both postural and phasic activities.
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There is little information regarding bond strengths of polyglass to metal alloys. This study evaluated the influence of bonding system on shear bond strength of a composite resin (Artglass/Heraeus Kulzer) to cast titanium (Ti). Twenty metallic structures (4mm in diameter, 5mm thick) of titanium grade I were cast shaped and abraded with 250mm aluminum oxide and separated into two groups. For each group was applied one bonding system (Siloc or Retention Flow) before opaque and dentin polymer superposition. This procedure was managed using teflon matrices. They were manipulated and polymerized according to the manufacturer's recommendations. The samples were stored in distilled water for 24 hours at 37º and thermocycled (5º and 55ºC/500 cycles). Shear bond strength tests were performed by using an Instron Universal testing machine at a crosshead speed of 5mm/min. Results were analyzed statistically with one-way ANOVA (a=0,5) and they indicated that the Retention Flow system was statistically better than Siloc (20.74 MPa and 11.65 MPa , respectively). It was possible to conclude that the bonding agent influenced the adhesion between polymer and cast titanium.
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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
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The goal of the present study was to investigate possible differences towards strenght recovery measured by different methods and running economy (RE), after one session of downhill running (DR), in order to induce muscle damage (MD). Our hypothesis is that the strenght recovery measured by jumps is more alike RE markers, due to the measures' specificity. Ten male subjects, ages 18 to 30, apparently healthy, without any experience with strenght training at least 6 months before the tests took place in this study. After going to the lab twice (to familiarize themselves with the protocols, and determine their maximum oxygen consumption/running speeds), they went to the lab five times in the following week, in order to collect all the variables before, immediately after, and 24, 48, 72 and 96 hours in. The variables obtained were: stride frequency (SF), stride lenght (SL), oxygen volume (VO2), carbon dioxide volume (VCO2), ventilation (VE), lactate blood concentration ([Lac]), isometric peak torque (IPT), subjective pain perception (SPP), effort perception (EP), medial-portion circumference (CIR), knee movement extent (EXT), torque development rate (TDR), counter movement jump and squat jump height (HCM and HS), strenght development rate of both jumps (SDCM and SDS), and maximum soil strenght reaction (SRCM and SRS). Changes over time in all variables were verified by one way variancy analysis. Differences between the strenght measures were verified by two way variancy analysis. When significant effects were verified, Tuckey's post-hoc were applied. The significancy level taken on this study was p < 0,05. Of all indirect muscle damage markers, IPT, SPP and TDR were the only ones in which ocurred significant changes. We couldn't find the moments where this happened for TDR with the post-hoc used. On RE markers, VO2, [Lac] and VE suffered significant effects over time. About the jumps variables, only SDCM and HCM presented significant...
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Pós-graduação em Biologia Geral e Aplicada - IBB
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Pós-graduação em Biologia Geral e Aplicada - IBB
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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
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A modificação de nanopartículas de óxido de ferro tem sido motivo de diversos estudos devido ao grande potencial em aplicações tecnológicas, em especial a área biomédica, pela aliança das propriedades magnéticas dos óxidos com a funcionalidade que a dextrana confere a esse material. O presente trabalho tem como objetivo sintetizar e caracterizar o sistema óxido de ferro/dextranas. O óxido de ferro foi obtido pela reação de co-precipitação de sais de ferro (II) e ferro (III) - na razão molar 1:2 - com hidróxido de sódio e a modificação das partículas magnéticas se deu por dois métodos: (I) a co-precipitação na presença de dextrana e carboximetil dextrana e (II) a co-precipitação seguida da modificação. Para modificação proposta pelo método (II) se fez necessário enxertar a dextrana em ácido acrílico, utilizando o íon Ce(IV) como iniciador da reação de polimerização. Nessa etapa se averiguou a concentração de iniciador ótima para a síntese e, através da técnica de espectroscopia de infravermelho, se pode confirmar a eficiência do enxerto. A concentração 0,3% de íon Ce(IV) apresentou melhor distribuição de tamanho, obtidos por análises de microscopia eletrônica de varredura e espalhamento de luz dinâmico, sendo escolhida para síntese junto a partícula magnética. A difratometria de raio X permitiu determinar a formação de estrutura cristalina da magnetita e maghemita, que são muito parecidas entre si, porém os espectros de infravermelho apontaram desdobramentos da ligação Fe - O característica da maghemita. A relação Fe2+/ Fe3+ obtida por espectrofotometria também resultou em oxidação. A estabilidade coloidal dos sistemas foi avaliada através de medidas de potencial zeta. A modificação da partícula magnética com carboximetil dextrana foi equivalente para os dois métodos empregados, entretanto a modificação com ...