Modelagem e Simulação Computacional das propriedades estruturais, eletrônicas e constantes elásticas do ZnO

The electronic, structural properties and elastic constants of the wurtzite phase of zinc oxide, ZnO, was investigated using computer simulation at Density Functional Theory level, with B3LYP hybrid functional and Hartree-Fock methodology. The electronic properties as well the band energy was investigated through the analysis of the band structures and density of states (DOS), and the mechanical properties was studied through the calculus of the elastic constants C11, C33, C44, C12 e C13. The results are in good agreement with experimental data found in the literature and in accordance with results obtained by another theoretical methodology

Estudo sobre o potencial de alguns latossolos da região do Vale do Paraíba, estado de São Paulo, para uso em camadas estruturais de pavimentos de baixo volume de tráfego

The main purpose of this research is to raise, through lab rehearsals, the geometric properties of some oxisols from the region of Vale do Paraíba as well as comparing them to demands prescribed by Technical Specifications ESP08/05 of the Road Department of the State of Paraná, for sub-base or fine grained lateritic soil base (SAFL) and in the Technical Specification ET-DEP00/006 of the Road Department of the State of São Paulo (DER/SP) for subbase or crushed stone base. According to the results that were obtained it will be feasible to appraise the usage of these sorts of soils in structure layers of low-weight traffic pavements

O Leão do Norte vai voltar a rugir?: um estudo de caso sobre as mudanças na Administração do Comercial Futebol Clube da cidade de Ribeirão Preto - SP

From the informations collected on the Commercial Football Club, the city of Ribeirao Preto, there was a case study in order to identify and describe the management model adopted by the club, to overcome the financial and administrative crisis. It was used as reference to analyze the concepts of social capital and historic capital, considered decisive for the choice of the management model adopted. In addition, we also used the proposals contained in sports management studies to identify the business model chosen by the Commercial Club Football Club. In the final considerations argued that the adopted model already includes some results, as the club qualified to participate the Series A-1 League football Paulista, one of the targets set by the new management of the club

Análise estatística da vida em fadiga de compósitos estruturais pela distribuição de Weibull

Nowadays technological trend is based on finding materials that could support low weight with satisfactory mechanical properties and for this reason composite material became a very attractive topic in research projects all over the world. Due to its heterogenic properties, this type of material shows scatter in mechanical test results, especially in cyclic loading. Therefore it is important to predict its fatigue strength behaviour by statistic analysis, once fatigue causes approximately 90% of the failure in structural components. The present work aimed to investigate the fatigue behaviour of the Twill/Cycom 890 composite, which is carbon fiber reinforced with polymeric resin as matrix and manufactured via RTM process (Resin Transfer Molding). All samples were tested in different tensile level in triplicate in order to associate these values. The statistical analysis was conducted with Two-Parameter Weibull Distribution and then evaluated the fatigue life results for the composite. Weibull graphics were used to determine the scale and shape parameters. The S-N curve for the Twill/Cycom composite was drawn and indicated the number of cycles to occur the first damages in this material. The probability of failure was associated with material reliability, as shown in graphics for the different tensile levels and fatigue life. In addition, the laminate was evaluated by ultrasonic inspection showing a regular impregnation. The fractographic analysis conducted by SEM showed failure mechanisms for polymeric composites associated to cyclic loadings ... (Complete abstract click electronic access below)

Estudos estruturais com a importina-α e Sequências de Localização Nuclear (NLS) de proteínas envolvidas no metabolismo de Neurospora crassa

Proteínas que apresentam atividades no núcleo e possuem sequência de localização nuclear (NLS) tem seu deslocamento dependente do heterodímero importina-α/β. A importina- (ImpA) é responsável pelo reconhecimento inicial do substrato a ser importado através da interação com os NLS. Os sinais são caracterizados por apresentar um ou mais grupos de aminoácidos básicos, denominados como sequências monopartidas e bipartidas. O fungo Neurospora crassa vem sendo utilizado há mais de 70 anos como organismo modelo em estudos de expressão gênica, desenvolvimento e diferenciação celular, ritmo circadiano, defesa do genoma, bem como outros aspectos da biologia de eucariotos. A presença de um grande número de genes no genoma de N. crassa ainda com funções desconhecidas aponta este organismo como um promissor modelo para o estudo de novos mecanismos genéticos e bioquímicos ainda não identificados. Considerando a importância do metabolismo do glicogênio para os organismos, o presente trabalho teve como objetivo o estudo estrutural de complexos de ImpA com peptídeos NLSs (NCM e NCB) de proteínas envolvidas no metabolismo de glicogênio do fungo N. crassa, utilizando técnicas de cristalografia de proteínas. Monocristais dos complexos ImpA-NCM e ImpA-NCB foram obtidos para a coleta dos dados de difração de raios-X, resultando em dois conjuntos de dados à 2,1Å e 2,45Å de resolução, respectivamente. Após elucidação da estrutura da ImpA, mapas de densidade eletrônica gerados revelaram uma densidade eletrônica no sítio principal de reconhecimento de NLS da ImpA de ambas estruturas, possibilitando modelagem dos peptídeos. Em uma comparação do mapa de densidade eletrônica obtido de ambos complexos com um mapa de uma estrutura nativa de ImpA (70-529) coletada à 2,0Å de resolução, a qual usualmente apresenta um peptídeo “contaminante” no sitio de ligação... (Resumo completo, clicar acesso eletrônico abaixo)

Avaliação da influência da esterilização por radiação gama nas propriedades mecânicas, estruturais e na biocompatibilidade de matrizes híbridas orgânico-inorgânicas

Atualmente, as pesquisas acadêmicas e industriais não estão voltadas apenas para a descoberta de novos fármacos, mas também para novas maneiras de administração de medicamentos pretendendo obter melhores ações farmacológicas alem de reduzir efeitos colaterais. Partindo deste pressuposto, estudos demonstram que inúmeras moléculas podem ser incorporadas a polímeros híbridos orgânico-inorgânico preparados pelo processo sol-gel, assim pretende-se estudar a possibilidade de sua aplicação no desenvolvimento de um dispositivo de liberação controlada de fármacos na forma de implantes subcutâneos. As matrizes hibridas para serem implantadas devem, necessariamente, ser estéreis. Para isto este trabalho analisa a interação entre o processo de esterilização e uma provável alteração estrutural nestes polímeros. A esterilização por calor úmido em autoclave e a esterilização por radiação gama foram escolhidas para analisar a correlação entre alteração estrutural do hibrido e o processo de eliminação de microorganismos. Outro aspecto que levamos em consideração foi a melhora das características mecânicas das matrizes poliméricas confeccionadas com poli óxido etileno de peso molecular 1900 (POE 1900) e poli óxido propileno de peso molecular 400 (POP 400). Para serem implantadas estas matrizes devem estar uniformes, e não podem trincar ou quebrar antes ou após a implantação. Considerando estes fatores foi adicionado as amostras um agente plastificante, o álcool polivinílico (PVA), na tentativa de melhorar estas características

Propriedades estruturais de géis de sílica preparados com adições de dodecil sulfato de sódio

This work aims to study the structural characteristics of silica gels obtained from the acid hydrolysis of tetraethoxysilane (TEOS) in water solutions with different concentrations of sodium dodecyl sulfate (SDS). The structural characteristics were studied in stages ranging from the wet gel to the dry stages of the gels (aerogels and xerogels). Aerogels were obtained by ambient pressure drying (APD) after silylation process using trimethylchlorosilane (TMCS) as silylating agent. Xerogels were obtained by conventional evaporating the liquid phase from non silylated gels. The samples were characterized by nitrogen adsorption and small angle X-ray scattering (SAXS). The structure of the wet gels and of the aerogels prepared with the surfactant exhibited characteristics of mass-fractal structures with fractal dimension D in the range 2.1-2.2 for the wet gels and 2.3-2.4 for the aerogels. The characteristic size  of the fractal domain reduces while the size a0 of the primary silica particle composing the fractal structure increases with the drying of the gels, in a process in which share of the porosity is eliminated. Aerogels exhibited typical values for the specific surface of 900 m2g-1 and of 3.5 cm3.g-1 for the total pore volume. These values are correspondingly comparable to those of the aerogels prepared by supercritical drying, since the silylation process replaces hydrophilic –OH groups by hydrophobic –Si-R3 ones, inhibiting the porosity elimination on drying. The silica particle size also increases lightly with the silylation because the attachment of the –Si-R3 groups on the silica surface. The pore size distribution curves of the aerogels are similar for all samples exhibiting a maximum in around 40 nm, independent the concentration of surfactant. This suggests that the characteristic size of 40 nm is due to the association of surfactant micelles... (Complete abstract click electronic access below)

Reformas estruturais no Brasil na década de 1990 e seu impacto sobre o emprego

O país passou por um período de grandes transformações no último quarto do século XX, os quais afetaram em grande medida a esfera social, política e econômica da sociedade. Dado o enfraquecimento do Estado de Bem Estar Social, e a ascensão do pensamento neoliberal nos anos 1970, houve a revisão do papel do Estado em todo o globo. As reformas neoliberais durante a década de 1990 tiveram um impacto significativo sobre os níveis do produto, e refletiram na redução do emprego até o fim da década, além do surgimento de novas formas de precarização do trabalho. Este trabalho tem como principal objetivo elucidar o impacto destas reformas estruturais sobre o emprego e seus desdobramentos na sociedade

Análise dos efeitos das deformações estruturais sobre a transferência transversal de carga em um veículo do tipo fórmula SAE submetido a uma aceleração lateral constante

This paper studies the frame deformations on a formula SAE vehicle in steady-state cornering and its influence on the lateral load transfers and, consequently, on the tires normal loads due to the applied lateral load. For a vehicle with a perfect rigid frame, the vehicle mass, the position of the center of gravity and the suspensions are the only factors responsible for the load distribution between the tires. When the frame deformations are no longer negligible, the frame deformations affect the loaddistribution between the tires. The frame flexibility turns it able to behave as an additional set of springs to the suspension system, thus changing the behavior of the set. This paper describes howit happens and suggests ways to minimize this phenomenon

Caracterização físico-mecânica de elementos estruturais roliços perfilados de Amaru

The study of physical and mechanical properties of wood is essential for its structural use and it is of great importance to the construction industry. Thus, this study aimed to determine the physical and mechanical properties of the wood Amaru - a hybrid of Eucalyptus, developed by Plantar Projects and Forest Products Ltda. In order to determine the properties of Amaru, round samples were used, which were provided to the Laboratory of Wood and Wooden Structures of the School of Engineering of São Carlos, University of São Paulo - LaMEM / EESC / USP. For the characterization of the physical properties, the apparent specific gravity and moisture content of the samples were determined. To the mechanical characterization, the following properties were evaluated: strength and stiffness in compression, strength and stiffness in bending, shear and tension. The procedures of the tests performed in this study were done according to the recommendations of the Brazilian Wood Standard ABNT NBR 7190:1997. The specimen used were confectioned in actual dimensions, according to as those used in the construction system proposed by Plantar. The results obtained from the tests performed showed that the mechanical properties approached the values proposed by the Wood Standard NBR 7190. The visual grading was important to provide a primary idea about the failure modes to be obtained from the tests performed. The bending test showed the modulus of elasticity (MOE) and Modulus of Rupture (MOR), which resulted in 15822 MPa and 101,7 MPa, respectively. The compression test resulted in values Ec0,m and fc0, 15698 MPa and 50,7 MPa. The tensile strength (ft0) of this hybrid was calculated and its value obtained was 60,8 MPa. The shear strength (fv0) was 8,2 MPa. The results obtained from the tests are the basis for engineers and architects to design structures using wood species Amaru

Vicentina Aranha de sanatório a parque: histórias e mudanças

This assignment intents to analyze the recover and the research of the cultural legacy identity of Vicentina Aranha Sanatorium to the inhabitants of the city of São José dos Campos-SP. That initiative becomes present through the importancy of the sanatorium to the public health of Vale do Paraíba in the decades between 30 and 70, of the 20th century. Nowadays this place refuges a park, presenting a reexamination of its space, with the possibility of the leisure practice, entertaining and tourism. The Vicentina Aranha Sanatorium Park presents itself conserving a landscape that is able of being inserted in a continuum past-present resignifying ways of appropriation and use. The word patrimony has many meanings and it‟s commonly associated to the set of goods that someone, the society or an entity owns. Transporting in a determinate territory, the patrimony starts to be a set of goods that are in its limits of administrative competency. (BARRETO, 2000). More than this, the cultural-historical patrimony guard a relation of belonging between it and the entity that has it. The Vicentina Aranha Sanatorium was inaugurated in 1924, with the project of the architect, Ramos de Azevedo, constituting an architectural ensemble placed under governmental trust as a historical and cultural patrimony of the state in 2001. It has a grove with centenary vegetal species like: MOGNO, PEROBA ROSA, JEQUITIBÁ and JACARANDA, constituting also a natural patrimony important for the city. There are projects like “Leitura no Bosque” and it‟s visited by the local population. Today the city seeks a new identity for that place transforming it in the center of industrial and technologic study

Estudo das políticas de obtenção dos assentamentos de reforma agrária no Brasil entre 1985 e 2009

Understanding the territorial transformations is important to the geographic knowledge, especially when it is related to structural questions as agrarian one. In this way, the land acquisition to agrarian reform enables us to understand some of these transformations, represented by territorialization of landless workers in rural settlements, that are concrete results of the struggle for land that boost the policies of agrarian reform in our country. The renewal of the agrarian structure is fundamental to the concept of land reform and also provides that advances social, political, cultural, economic, etc. Classified as a country with rates of the highest land concentration in the world, Brazilian government attempts to base his actions to take in the expropriation of land the main character of the land reform. However, new policies have been gradually used to obtaining the rural settlements, in a process that Fernandes (2010) called the reconceptualization of land reform. Starting in 1985, Brazil has 63% of the beneficiaries of land reform policies settled on expropriated land, the rest is a result of incorporation policies such as land regularization, of land reform and land purchase. Such policies generate changes in agrarian structure, that is the goal of land reform, but don´t concentrate to the land ownership. This attitude of the state in coping with the agrarian question is his response to the pressures of capitalist agriculture represented by landowners and agribusiness, coping catching an intense and uneven territorial dispute with peasant agriculture, in an attempt to impose its model of development for the field. The aimed of this present study is to understand better the land reform acquisition and its implications in the Brazilian territory, in order to understand it in their multiplicity.

Concentração de tensões em peças e componentes estruturais - uma abordagem através do método dos elementos finitos

Any failure process that may occur in a part probably is located where the stress exceeded the level of resistance. When a part or component has a sharp change in geometry, such as slots, holes, grooves, bumps or other irregularities, there is an increased concentration of stress at a specific location of the part. The objective of this study is to determine the maximum stresses in structural parts and components using the equations of elasticity theory in conjunction with the stress concentration factor experiment and compare them with results obtained by finite element method

Aspectos florísticos e estruturais da família Myrtacea na floresta Ombrófila Densa Submontana (Parque Estadual Serra do Mar - Núcleo Picinguaba, Ubatuba - SP)

Com base nas coletas realizadas em quatro parcelas de um hectare (Designadas pelas letras B, C, D e E localizadas no Núcleo Picinguaba, município de Ubatuba, São Paulo, foi levantada uma base de dados florísticos e fitossociológicos para a família Myrtaceae. Todas as parcelas situam-se em área de ocorrência de Floresta Ombrófila Densa e estão inseridas no Projeto Temático “Composição florística, estrutura e funcionamento da Floresta Ombrófila Densa dos Núcleos Picinguaba e Santa Virgínia do Parque Estadual da Serra do Mar” do Programa BIOTA-FAPESP. O estudo teve como objetivo investigar a influência de Myrtaceae na constituição estrutural e diversidade do componente arbóreo no trecho florestal amostrado. No total foram amostradas 66 espécies para a família, distribuídas em 9 gêneros, sendo que Eugenia foi o gênero de maior riqueza. A parcela B foi a que mais apresentou espécies de Myrtaceae. Dos 4750 indivíduos contemplados, Myrtaceae contribuiu com 861, sendo precedida apenas por Rubiaceae com 922 indivíduos; A parcela E concentrou o maior número deles (223); Da área basal total 106,17 m², Myrtaceae contribui com 16,16 m². Apareceu com frequência absoluta entre 85% e 90% nas quatro parcelas, totalizando 87,5% nos 4 ha. Apresentou diâmetro e altura média de 12,73 cm e 8,17m respectivamente. Foi a família mais importante em todas parcelas (VI), apresentando valor de importância de 15,24% quando calculado para a somatória das quatro parcelas. O índice de Shannon calculado para parcela B, C, D, E e total foi 4,12 nats/ind; 3,98 nats/ind; 4,00 nats/ind; 4,06 nats/ind; 4,23 nats/ind respectivamente. A equabilidade foi 0,82; 082; 0,79; 0,82; 0,76 respectivamente. Para as espécies de Myrtaceae, Marlierea obscura destacou-se em primeiro lugar quanto ao número de indivíduos (83), frequência absoluta (18,5%), dominância absoluta (0,46), sendo assim... (Resumo completo, clicar acesso eletrônico abaixo)

Influência do condicionamento ambiental sobre as propriedades viscoelásticas de compósitos aramida/epóxi

The increasing application of structural composites in the aerospace industry is mainly due to its low specific weight coupled with its excellent mechanical properties when in service. As a result of climatic variations that pass the aircraft is of paramount importance to study the influence of weathering on this type of material when subjected to such changes. The purpose of this work is to evaluate the mechanical behavior of specimens of kevlar fiber /epoxy matrix composites, by dynamic mechanical thermal analysis (DMA) and interlaminar shear strength tests (ILSS), after passing through three environmental conditioning: saline fog, hygrothermal and ultraviolet radiation. From the results, we concluded that the laminate was molded supplied homogeneously, not presenting problems such as porosity, delaminations or cracks inside. After a period of 625 hours of exposure to hygrothermal conditioning, we observed a 1,2% maximum of absorption of moisture. Samples subjected to the conditioning by UV irradiation (600 hours) and salt spray showed a reduction of about 24,30% and 32,30%, respectively, on the shear strength (ILSS). In DMA analysis is not observed significant changes on the glass transition temperature. However, when considering the storage modulus of the samples conditioned by UV radiation (1200 hours), salt spray and hygrothermal conditioning there is an increase of 5,34% , 7,19% and 5,57% respectively