Multimethod study of the degree of humification of humic substances extracted from different tropical soil profiles in Brazil's Amazonian region

This work consisted of determining the degree of humification of humic substances (HS) extracted from six different Amazonian soils collected from flooded and unflooded regions at different depths (0-10, 10-20, 20-40, and 60 cm). The humic substances were extracted according to procedures recommended by the International Humic Substances Society and characterized using elemental analysis, electron paramagnetic resonance (EPR), and fluorescence spectroscopy. The findings on semiquinone-type free radical concentrations in HS showed variations of 0.10-7.55x10(18) spins g(-1) of carbon (g C)(-1), indicating considerable differences between the humification levels of HS extracted from Amazonian soils. The results showed an average of 1.71 +/- 0.04 x 10(18) spins (g C)(-1), which is congruent with other data reported in the literature on Tropical soils. It was found that, on average, HS extracted from flooded soil contained higher semiquinone-type free radical concentrations than HS extracted from unflooded soils, indicating the influence of humidity in the humification process of organic matter. The humification process varies according to the profile, and the 10-20- and 0-10-cm profiles generally showed more humified HS. The degree of humification of the HS studied here displayed a similar behavior when exposed to fluorescence (excitation at 465 nm) and EPR (R=0.85). However, the low correlation between the C/H, C/O, and C/N atomic ratios and the semiquinone-type free radical concentration/fluorescence intensities indicated that data obtained by these techniques with regard to the degree of humification of HS may lead to different conclusions. (c) 2004 Elsevier B.V. All rights reserved.

Parâmetros geotécnicos e previsão da capacidade de carga de estacas apiloadas em solo tropical arenoso obtidos com o Pressiômetro Ménard

This paper presents and discusses Ménard Pressuremeter test results used to predict bearing capacity of pounded piles installed in a tropical sandy soil. Fifteen pre-bored pressuremeter tests were carried out at the Experimental Research Site from Unesp - Bauru up to 15 m depth, one test per meter. Several laboratory and in situ tests were carried out in this research site as well as load tests on plates and on piles. Pressuremeter test results were firstly analyzed to determine geotechnical soil parameters based on empirical methods, emphasizing the estimative of the earth pressure coefficient at rest (K0). After that, bearing capacity prediction of pounded piles with 4 m, 7 m and 10 m were made and compared with test results from instrumented load tests. Pressuremeter test results allowed a very good estimative of bearing capacity for the pile with 4 m length and underestimated in 25,7% and 20,0% the bearing capacity for the pile with 7 and 10 m length, respectively. The back analysis of the test results suggests that the appropriate value for the bearing capacity factor for the tested soil-pile system on this soil is equal to 2.

Cross-hole and seismic CPT tests in a tropical soil site

A large portion of Brazil is covered with tropical soils but literature about dynamic parameters of these soils is very limited. SCPT and cross-hole tests were carried out at an experimental research site inland in the state of São Paulo, Brazil. Shear wave velocities (VS) determined based on both tests are presented and compared. A good agreement was observed between both test results and the differences can be associated with soil variability, which was very sensitive to CPT tests. It was also observed that Go/q c ratio determined based on SCPT appears to be an interesting technique to help identify tropical soils. Copyright ASCE 2006.

Evolution of the mechanical properties of a tropical soil stabilized with lime and ash of rice rind

The ash of rice rind is a pozzolanic material that reacts with the calcium hydroxide (Ca (OH)2) forming bonding composites, when finely worn out and in water presence. Considering this behavior, the objective of the present work was to evaluate the potential use of this residue in the enrichment of the content of pozzolanic materials of a tropical soil stabilized with a commercial hydrated lime. The laboratory testing program incorporated unconfined compression strength tests performed on the soil and on its mixtures with contents of 8% of lime enriched with 5 and 10% of ash of rice rind in relation to the soil dry mass. The results of the testing program supported that the use of the residue was effective in increasing the degree of reactivity of the soil that was also directly related with the increase in the ash content and the period of cure of the mixtures.

Aspects of Mechanical Behavior and Modeling of a Tropical Unsaturated Soil

The research studies the applicability of two elastoplastic models for the collapse prediction of the lateritic soil profile from Southeastern Brazil. These tropical soils have peculiar geotechnical behavior, due to their mineralogical composition and porous structure coming from intense process of formation. Two elastoplastic models were analyzed: the Barcelona Basic Model (BBM) and another one based on BBM, however developed for tropical soils. Oedometric tests with suction control were performed at three distinct depths of the soil profile. The BBM was not suitable for the upper layer of the soil profile, because BBM considers the compressible behavior of the soil in function of the reduction of the elastoplastic compressibility index with the increase of the matric suction. The model developed for tropical soils showed better suited to the compressible behavior of the soil profile, resulting in good prediction of the collapse potential, mainly by accepting increasing values of the elastoplastic compressibility index of the soil profile with the matric suction rise. © 2013 Springer Science+Business Media Dordrecht.

Avaliação da resistência ao cisalhamento de um solo tropical não saturado

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

The cone loading test to estimate deformability moduli of a tropical soil

The Cone Loading Test (CLT) consists of the execution of a load test on the piezocone probe in conjunction with the CPT test. The CLT yields the modulus ECLT, a parameter that can be used in the estimative of foundation settlement. It is also presented here the interpretation and the process to determine ECLT values from the stress-displacement curves obtained from cone loading tests. Several CLT tests were conducted at the experimental research site of São Paulo State University, Bauru-SP-Brazil. The geotechnical profile at the studied site is a brown to bright red slightly clayey fine sand, a tropical soil common to this region which is lateritic, unsaturated and collapsible. The results of CLT tests satisfactorily represent the behavior of the investigated soil. The penetrometric modulus ECLT for each depth was calculated considering the elastic behavior in the initial linear segment of the soil stress-strain curve. The ECLT moduli obtained for the various tests were compared to moduli obtained from PMT and DMT test results performed at same studied site. The shear modulus degradation curves obtained from the CLT tests are also presented. The comparison to PMT and DMT results indicates the CLT test is a viable complementary test to the CPT in the quest for better understanding stress-strain behavior of soils. Further, the CLT test provides a graphic visualization of the degradation of the shear modulus with increasing levels of strain. As a hybrid geotechnical test, CPT+CLT can be valuable in the investigation of non-conventional collapsible soils, whose literature lack reference parameters for the prediction of settlement in the design of foundations.

Shear strength of a natural and compacted tropical soil

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Padrão de distribuição de K+, Ca++, Mg++ e P no solo de um pomar de citros em função da fertirrigação

Em solos tropicais, a distribuição dos nutrientes no solo em função da fertirrigação realizada por meio de irrigação localizada (gotejamento e/ou microaspersão), na cultura de citros, é pouco conhecida. Este trabalho teve por objetivo avaliar os padrões de distribuição de potássio, cálcio, magnésio e fósforo em solo tropical, em função da fertirrigação, aplicada por dois sistemas de irrigação localizada (microaspersão e gotejamento), sendo que o sistema por gotejamento era composto por uma e duas linhas laterais por linha de plantas, e o de microaspersão por apenas uma linha, e com três dotações hídricas (100%, 75% e 50%) da evapotranspiração da cultura (ETc), em um pomar de laranjeira. As fontes de fertilizantes utilizadas na fertirrigação foram o nitrato de amônio (fonte de N), o cloreto de potássio (fonte de K+) e o ácido fosfórico (fonte de P). Observouse que, sob o emissor, nos tratamentos com gotejamento, houve depleção nos teores de Ca++ e Mg++ desde a superfície do solo até 60 cm de profundidade em relação aos teores anteriores às fertirrigações, enquanto os teores de P aumentaram, principalmente na camada de 0 cm a 20 cm. Na microaspersão, esses efeitos não foram observados, ocorrendo distribuição mais homogênea desses nutrientes tanto na direção transversal à linha de plantas quanto em profundidade. As lâminas de irrigação aplicadas por irrigação localizada não interferem na distribuição de K+ aplicado por fertirrigação e do Ca++ e Mg++ no solo em profundidade, porém menores lâminas de irrigação promovem maior concentração de P na camada mais superficial do solo, e lâminas maiores carregam o P para camadas mais profundas.

Resposta de mudas de goiabeira a aplicação de fósforo

Phosphorus is a nutrient that most limits plant growth because of its importance in nutrition and low concentration in tropical soils. The present study aimed to evaluate the response of guava to application of phosphorus. For this, the experiment was conducted in a greenhouse at UNESP, Jaboticabal Campus, with guava plants (cv. Paluma) from herbaceous plants cultivated in plastic bags (2.8 dm(-3)), filled with Alfissol (P = 2 mg dm(-3)), between November 2007 and April 2008. The treatments consisted of five doses of phosphorus (0, 100, 200, 300 and 400 mg dm(-3)) in the form of triple superphosphate (44% P(2)O(5)), arranged in a randomized block design with four replications. After 100 days of transplantation evaluated the phosphorus content in soil, dry weight of shoot and root phosphorus and zinc in the shoot. The highest production of dry weight guava was a dose of 257 g dm(-3) of phosphorus and was associated with P content in soil and leaf 110 mg dm(-3) and 2,3 g kg(-1).

Application of chemometric methods in the evaluation of chemical and spectroscopic data on organic matter from Oxisols in sewage sludge applications

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Adubação fosfatada no meloeiro-amarelo: reflexos na produção e qualidade dos frutos

O melão (Cucumis melo L.) é uma das culturas de grande expressão econômica e social para a região Nordeste do Brasil. Apesar disso e dos baixos níveis de fósforo (P) dos solos tropicais, existem poucas pesquisas sobre adubação com P nesta cultura, embora seja frequentemente mencionado que este nutriente tem papel preponderante na produção e qualidade dos frutos. Neste contexto, objetivou-se com este trabalho avaliar o efeito de doses de P (0; 120; 240; 360 e 480 kg ha-1 de P2O5), na produção e qualidade do melão-amarelo híbrido Goldex F1, nas condições ambientais de Teresina - Piauí. O experimento foi conduzido em um delineamento de blocos ao acaso, com quatro repetições, tendo 40 plantas por parcela. Os frutos foram colhidos aos 75 após o plantio. Foram avaliados os dados médios da produção total, produção de frutos comerciais, massa e número de frutos por planta, comprimento e diâmetro de frutos, espessura da polpa de frutos, sólidos solúveis, acidez titulável e o índice de maturação. A produção total e comercial, assim como a massa e o número de frutos e acidez titulável aumentaram com as doses de P aplicadas até a dose de 278 kg ha-1 de P2O5. Doses acima de 278 kg ha-1 de P2O5 prejudicaram a produtividade de frutos classificados como comerciais. O comprimento, o diâmetro de frutos e a espessura de polpa aumentaram até a dose de 355 kg ha-1 de P2O5, com aumentos pouco expressivos entre 278 e 355 kg ha-1 de P2O5. O teor de sólidos solúveis totais não foi afetado pela adubação fosfatada. Para as condições de fertilidade do solo deste trabalho, recomenda-se uma dose ao redor de 275 kg ha-1 de P2O5.

Adsorção de selênio em latossolos

A retenção de Se pelos colóides do solo constitui importante processo para a manutenção da sanidade ambiental. A informação sobre a adsorção de Se em solos altamente intemperizados é restrita e existem poucos padrões quantitativos disponíveis para a definição de estratégias de remediação de áreas contaminadas. Quantidades crescentes de Se (5, 10, 25, 50, 100 e 250 mg L-1), na forma de Na2SeO3, foram adicionadas a amostras de dez Latossolos brasileiros [três Latossolos Vermelho-Amarelos (LVA-1, LVA-2 e LVA-3), dois Latossolos Vermelhos (LV-1 e LV-2), um Latossolo Vermelho eutroférrico (LVef), um Latossolo Vermelho acriférrico (LVwf), dois Latossolos Amarelos (LA-1 e LA-2) e um Latossolo Amarelo acriférrico (LAwf)]. Isotermas de adsorção foram construídas e foi verificado o ajuste dos resultados experimentais aos modelos de Langmuir e de Freundlich. A equação de Langmuir ajustou melhor os resultados de adsorção de Se do que a isoterma de Freundlich. Todas as isotermas apresentaram o formato tipo-L (exponencial), com exceção daquelas obtidas para o LVA-1 e para o LVA-2, que apresentaram comportamento tipo-C (linear). Valores de adsorção máxima (Ads máx), estimada pelo modelo de Langmuir, variaram de 135 (LVA-3) a 2.245 mg kg-1 (LA-1), enquanto os coeficientes de afinidade (K L) estiveram entre 0,002 (LVA-2) e 0,326 (LVA-3). A constante de afinidade estimada pelo modelo de Freundlich (Kf) variou de 13,7 (LVA-2) a 180,1 (LAwf). A adsorção máxima de Se foi mais elevada no LVef e nos Latossolos ácricos (LAwf e LVwf), enquanto os maiores valores de Kf foram encontrados no LV-2, LVef, LVA-3 e LVwf. Não houve correlação entre os atributos dos solos e as constantes de Langmuir. Valores de Kf correlacionaram-se com os teores de argila (r = 0,42*) e com a capacidade de troca de ânions (r = 0,64*).

Desenvolvimento de grãos e produção de fitomassa do girassol em função de adubações boratadas

Sunflower crop is a good option to no-tillage system; however, it is sensible to low B availability, what is common in tropical soils. The objective of this study was to evaluate the crop development, grain yield and grain size as affected by B fertilizer doses applied in the sowing and by leaf application. The experiment was conducted in controlled conditions, with four Borax doses (0; 1; 2 e 3 kg B ha(-1)) in the sowing interacting with four Boric Acid doses (0; 0,5; 1 e 2 kg B ha(-1)) by leaf application. The plants were managed until grain physiological maturity, when stems, leaves and capitula were sampled, besides the counting and weighing of two grain classes separated by size. The B fertilizer applied in the sowing lines increased total dry matter phytomass and grain yield. However, when interacting with high doses of B by leaf application, these values decreased. Grain size was increased with leaf fertilization, when B was not applied in the soil or with only 1 kg B ha(-1) in the sowing line. on the other hand, when B was applied from 2 to 3 kg ha(-1) in the crop sowing, high doses of leaf fertilizer affected grain filling.

Soybean root growth and yield in rotation with cover crops under chiseling and no-till

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)