107 resultados para Sintering additives


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The objective of this study was to evaluate the effects of feeding cattle with isoprotein and isoenergetic diets, with and without the addition of polyclonal antibody preparation (PAP), yeasts (YST) or monensin sodium (MON) on performance, carcass characteristics and gain cost in feedlot. Ninety-five 20-month old bullocks (323.3±21.8 kg) were distributed in 25 pens. The completely randomized experimental design had a 2 × 2 + 1 factorial arrangement and the treatments were replicated 5 times. There was no effect of MON for DMI throughout the feedlot period; however, MON reduced the dry matter intake (DMI) in g/kg of BW in the first 28 days when compared with the other treatments. The gain cost decreased with MON addition in relation to the other treatments. Inclusion of YST decreased average daily gain (ADG), final body weight, hot carcass weight, carcass weight, gain to feed ratio and DMI in g/kg body weight, worsening feed conversion and increasing the gain cost in the feeding periods. Inclusion of PAP increased ADG and decreased the gain cost, besides improving feed conversion. For MON and PAP, a difference was found for kidney-pelvic fat and kidney-pelvic fat per 100 kg of hot carcass weight. For MON and YST, there was a difference in ADG, feed conversion, gain cost and carcass yield and kidney-pelvic fat per 100 kg of hot carcass. Treatment YST worsened performance in relation to the non-supplemented treatments. Feeding PAP to animals did not influence performance and carcass characteristics of bullocks in feedlot negatively. Thus, PAP shows potential to substitute MON in cattle feeding using isoprotein and isoenergetic diets.

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Separation of microbial cells by flotation recovery is usually carried out in industrial reactors or wastewater treatment systems, which contain a complex mixture of microbial nutrients and excretion products. In the present study, the separation of yeast cells by flotation recovery was carried out using a simple flotation recovery systems containing washed yeast cells resuspended in water in order to elucidate the effects of additives (defined amounts of organic and inorganic acids, ethanol, surfactants and sodium chloride) on the cellular interactions at interfaces (cell/aqueous phase and cell/air bubble). When sodium chloride, organic acids (notably propionic, succinic and acetic acids) and organic surfactants (sodium dodecyl sulphate (SDS), cetyltrimethylammonium bromide (CTAB) and Nonidet P40) were added to the flotation recovery system, significant increases in the cell recovery of yeast hydrophobic cells (Saccharomyces cerevisiae, strain FLT-01) were observed. The association of ethanol to acetic acid solution (a minor by-product of alcoholic fermentation) in the flotation recovery system, containing washed cells of strain FLT-01 resuspended in water, leading to an increased flotation recovery at pH 5.5. Thus, the association among products of the cellular metabolism (e.g., ethanol and acetic acid) can improve yeast cell recovery by flotation recovery. (c) 2006 Elsevier B.V. All rights reserved.

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The sintering behavior of SnO2-CuO system has been investigated for two preparation methods and as a function of antimony concentration. A chemical preparation (Pechini's method) resulted in powders with smaller particle sizes than for a conventional oxide mixture. This led to smaller grain sizes in Pechini's method ceramics. The microstructures were heterogeneous in both systems, showing grain coarsening. The densification was aided by liquid phase formation, due to copper, in both systems, but the temperature of maximum shrinkage rate was larger for the Pechini's method ceramic because copper had to diffuse to the grain surface. Independently of the preparation method, antimony did not aid densification, and increasing its concentration led to a higher densification temperature and lower shrinkage rate. (C) 2003 Kluwer Academic Publishers.

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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Foram avaliadas, durante o processo de sinterização, as propriedades mecânicas de peças cerâmicas a base de argila com adição de rocha sedimentar. Foram preparados corpos de prova com 0, 20, 40, 60 e 80% em peso de rocha adicionada ao material argiloso. As peças foram sinterizadas nas temperaturas de 500, 800, 900, 1000, 1100 e 1200 °C e, posteriormente, submetidas à análise de difração de raios X e a ensaios tecnológicos Os resultados de difração de raios X mostram que a rocha sedimentar apresenta argilominerais micáceos enquanto o material argiloso possui a caulinita como fase principal. Técnicas de análises térmicas e difração de raios X das diferentes misturas mostram reações que indicam transformação (inversão do quartzo), decomposição (perda de hidróxidos) e formação de fase (mulita) durante o aquecimento das amostras. Os ensaios tecnológicos mostram que a adição da rocha sedimentar melhora algumas propriedades do material sinterizado, auxiliada pela presença de fundentes. Entretanto, a presença de quartzo na rocha dificulta a formação da fase mulita. A formação de novas fases e as transformações ocorridas no aquecimento e resfriamento das amostras ajuda explicar as propriedades tecnológicas dos materiais cerâmicos.

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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Objetivou-se estudar a ação do tempo após a queima do canavial e o uso de aditivos sobre as características fermentativas, as perdas e a composição química de silagens de cana-de-açúcar. A cultivar utilizada foi a IAC 86-2480 colhida em cinco tempos (1, 4, 7, 10 e 14 dias) pós-queima. Os aditivos utilizados foram controle, sem aditivos, Lactobacillus buchneri, cal virgem micropulverizada e Lactobacillus buchneri + cal virgem micropulverizada. Antes da ensilagem em cada tempo, foram determinadas as populações de leveduras presentes na cana-de-açúcar. Decorridos 56 dias após a ensilagem, os silos experimentais foram abertos. O delineamento experimental utilizado foi o inteiramente casualizado em esquema fatorial, considerando os fatores aditivos e tempo pós-queima. Houve recontaminação da cana-de-açúcar pelas leveduras, elevando a população de 5,04 para 6,48 log ufc/g de forragem. Os teores de matéria seca (MS) após a abertura do silo reduziram em média 7,6 unidades percentuais em comparação aos observados na ensilagem. As silagens controle e com Lactobacillus buchneri tiveram menores recuperações da matéria seca (613 e 631 g/kg, respectivamente), em comparação às observadas nas silagens com cal e com a combinação Lactobacillus buchneri + cal (807 g/kg e 832 g/kg, respectivamente), fato que pode ser justificado pelo controle de levedura pela cal. Após a queima, as maiores variações foram na produção de gás e na recuperação de matéria seca: a produção de gás foi maior nos primeiros dias e diminuiu com o tempo após a queima, consequentemente, a recuperação de MS foi menor nos primeiros dias e aumentou com o tempo após a queima. O tempo após a queima altera o valor nutritivo da cana-de-açúcar fresca e das suas silagens, assim como a magnitude das perdas no processo de ensilagem.

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Lead zirconate powder, with Zr/Ti ratio of 50/50 was prepared by polymeric precursor method and doped with 3, 5 and 7 mol% of Sr+2 Or Ba+2, as well as by 0.2 to 5 mol% of Nb+5. The powder was calcined at 750 degrees C by 4 hours and milled during 1.5 h in isopropilic alcohol. Powders were characterized by surface area measurements (BET method), by infrared spectroscopy and by X-ray diffraction to characterize the crystal structure. Isostatically pressed samples were sintered in a dilatometer furnace by using a constant heating rate of 10 degrees C/min from ambient to 1200 degrees C. Synthetic air and air with water vapor were used as atmospheres. Both Sr+2 and Ba+2 substitute Pb+2 and favor the formation of rhombohedral phase. Otherwise, Nb+5 substitute preferentially Zr+4 favoring tetragonal phase. The concentration of dopants and the atmosphere influence the densification and the microstructure of the PZT, which alters the dielectric and piezoelectric properties of the ceramics.

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Nanocrystalline ZrO2-12 mol % CeO2 powders were synthesized using a polymeric precursor method based on the Pechini process. X-ray diffraction (XRD) patterns showed that the method was effective to synthesize tetragonal zirconia single-phase. The mean crystallite size attained ranges from 6 to 15 nm. The BET surface areas were relatively high reaching 97 m(2)/g. Studies by nitrogen adsorption/desorption on powders, dilatometry of the compacts, and transmission electron microscopy (TEM) of the powders, were also developed to verify the particles agglomeration state. Both citric acid : ethylene glycol ratio and calcination temperature affected the powder morphology, which influenced the sinterability and microstructure of the sintered material, as showed by scanning electron microscopy (SEM). (C) 2001 Kluwer Academic Publishers.

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SnO2 ceramics doped with ZnO and WO3 were prepared by mixed oxide method. The effect of ZnO and WO3 additives could be explained by the substitution of Sn4+ by Zn2+ and W6+. The addition of WO3 inhibits the grain growth due to the segregation of SnZnWO8 and ZnWO6 at the grain boundaries without strong influence on the densification process. The electrical characterization (log E x log J) shows that the ternary system SnO2-ZnO-WO3 exhibits a very high resistivity of around 10(14) Omega M. Independently of the WO3 concentration, the electrical conductivity of the Sn02-ZnO-WO3 system is always lower than that of the undoped tin dioxide. (C) 2005 Elsevier Ltd and Techna Group S.r.l. All rights reserved.

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PLZT ceramics belong to one of the very important groups of functional materials that make a basis for the production of a large range of electronic devices. The microstructure and properties of ceramics depend on the powder preparation and thermal processing conditions. Various techniques have been used to obtain chemically homogeneous and fine starting powders. PLZT powders have been prepared by two different production routes: by a modified Pechini method, using a polymeric precursor method (PMM) and by a partial oxalate method. A two-step sintering process, including a hot pressing, was carried out at 1100 and 1200degreesC Distinct phases obtained during the sintering process have been investigated by SEM and EDS techniques and dielectric properties such as permittivity and dielectric loss were measured in a frequency range from 1 to 20 kHz.. A significant difference in microstructure and dielectric properties, depending on powder origin and sintering procedure, has been noticed.