Desenvolvimento do açaizeiro de terra firme, cultivar pará, sob atenuação da radiação solar em fase de viveiro

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Determining the oscillation parameters by solar neutrinos and KamLAND

The neutrino oscillation experiment KamLAND has provided us with the first evidence for e disappearance, coming from nuclear reactors. We have combined their data with all solar neutrino data, assuming two flavor neutrino mixing, and obtained allowed parameter regions which are compatible with the so-called large mixing angle MSW solution to the solar neutrino problem. The allowed regions in the plane of mixing angle and mass squared difference are now split into two islands at 99% C.L. We have speculated how these two islands can be distinguished in the near future. We have shown that a 50% reduction of the error on SNO neutral-current measurement can be important in establishing in each of these islands the true values of these parameters lie, We also have simulated KamLAND positron energy spectrum after I year of data taking, assuming the current best fitted values of the oscillation parameters, combined it the with current solar neutrino data and showed how these two split islands can be modified. (C) 2003 Published by Elsevier B.V. B.V.

Global analysis of the post-SNO solar neutrino data for standard and nonstandard oscillation mechanisms

What can we learn from solar neutrino observations? Is there any solution to the solar neutrino anomaly which is favored by the present experimental panorama? After SNO results, is it possible to affirm that neutrinos have mass? In order to answer such questions we analyze the current available data from the solar neutrino experiments, including the recent SNO result, in view of many acceptable solutions to the solar neutrino problem based on different conversion mechanisms, for the first time using the same statistical procedure. This allows us to do a direct comparison of the goodness of the fit among different solutions, from which we can discuss and conclude on the current status of each proposed dynamical mechanism. These solutions are based on different assumptions: (a) neutrino mass and mixing, (b) a nonvanishing neutrino magnetic moment, (c) the existence of nonstandard flavor-changing and nonuniversal neutrino interactions, and (d) a tiny violation of the equivalence principle. We investigate the quality of the fit provided by each one of these solutions not only to the total rate measured by all the solar neutrino experiments but also to the recoil electron energy spectrum measured at different zenith angles by the Super-Kamiokande Collaboration. We conclude that several nonstandard neutrino flavor conversion mechanisms provide a very good fit to the experimental data which is comparable with (or even slightly better than) the most famous solution to the solar neutrino anomaly based on the neutrino oscillation induced by mass.

Impedance Spectroscopy Analysis of the Effect of TiO2 Blocking Layers on the Efficiency of Dye Sensitized Solar Cells

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Doping saturation in dye-sensitized solar cells based on ZnO:Ga nanostructured photoanodes

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Electron Transport in Dye-Sensitized Solar Cells Based on ZnO Nanotubes: Evidence for Highly Efficient Charge Collection and Exceptionally Rapid Dynamics

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Surface Passivation of Nanoporous TiO2 via Atomic Layer Deposition of ZrO2 for Solid-State Dye-Sensitized Solar Cell Applications

We report here the utilization of atomid layer deposition to passivate surface map states in mosoporous TiO2 nanoparticles for solid state dye sensitized solar cells based on 9,9'-spirobifluorene (spiro-OMeTAD). By depositing ZrO2 films with angstrom-level precision, coating the mesoporous TiO2 produces over a two-fold enhancement in short-circuit current density, as compared to a control device. Impedance spectroscopy measurements provide evidence that the ZrO2 coating reduces recombination lossed at the TiO2/spiro-OMeTAD interface and passivates localized surface states. Low-frequency negative capacitances, frequently observed in nanocomposite solar cells, have been associated with the surface-state mediated charge transfer from TiO2 to the spiro-OMeTAD.

Synthesis and characterization of mesoporous TiO2 nanostructured films prepared by a modified sol-gel method for application in dye solar cells

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Degradation of sulfamethoxazole in water by solar photo-Fenton. Chemical and toxicological evaluation

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Photo-Fenton degradation of the herbicide tebuthiuron under solar irradiation: Iron complexation and initial intermediates

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Diclofenac Abatement using Modified Solar Photo-Fenton Process with Ammonium Iron(III) Citrate

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Potencial de aplicação do processo foto-fenton/solar como pré-tratamento de efluente da indústria de laticínios

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Synthesis and characterization of ZnO and ZnO : Ga films and their application in dye-sensitized solar cells

Highly crystalline ZnO and Ga-modified zinc oxide (ZnO:Ga) nanoparticles containing 1, 3 and 5 atom% of Ga3+ were prepared by precipitation method at low temperature. The films were characterized by XRD, BET, XPS and SEM. No evidence of zinc gallate formation (ZnGa2O4), even in the samples containing 5 atom% of gallium, was detected by XRD. XPS data revealed that Ga is present into the ZnO matrix as Ga3+, according to the characteristic binding energies. The particle size decreased as the gallium level was increased as observed by SEM, which might be related to a faster hydrolysis reaction rate. The smaller particle size provided films with higher porosity and surface area, enabling a higher dye loading. When these films were applied to dye-sensitized solar cells (DSSCs) as photoelectrodes, the device based on ZnO: Ga 5 atom% presented an overall conversion efficiency of 6% (at 10 mW cm(-2)), a three-fold increase compared to the ZnO-based DSSCs under the same conditions. To our knowledge, this is one of the highest efficiencies reported so far for ZnO-based DSSCs. Transient absorption (TAS) study of the photoinduced dynamics of dye-sensitized ZnO:Ga films showed that the higher the gallium content, the higher the amount of dye cation formed, while no significant change on the recombination dynamics was observed. The study indicates that Ga-modification of nanocrystalline ZnO leads to an improvement of photocurrent and overall efficiency in the corresponding device.

Estudo da aplicação do processo foto-Fenton solar na degradação de efluentes de indústria de tintas

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Estimativa da irradiação solar global com partição mensal e sazonal para a região de Cascavel - PR

No presente trabalho, mostram-se equações de estimativa da irradiação solar global (R G), por meio do modelo de Angstrom, com partições sazonal e mensal para a região de Cascavel - PR. Os dados experimentais foram cedidos pelo IAPAR, coletados na sua estação meteorológica localizada na COODETEC/Cascavel - PR, no período de 1983 a 1998. Dos 16 anos de dados, 12 anos foram utilizados para cálculo dos coeficientes (a e b) e quatro anos para a validação das equações. Os coeficientes de determinação encontrados foram superiores a 80% para as duas partições. O mínimo da R G é superestimado e o máximo é subestimado quando comparados com o mínimo e o máximo para dados reais, sendo esses encontrados no solstício de inverno e equinócio de primavera, respectivamente. A variação sazonal e mensal do coeficiente a foi menor (0,16 a 0,19 e 0,14 a 0,21) e do coeficiente b maior (0,34 a 0,43 e 0,32 a 0,44). As maiores variações dos erros médios diários ocorreram no equinócio de primavera (-19,45% a 27,28%) e as menores no equinócio de outono (-11,32% a 10,61%). O ajuste mais eficaz das equações foi encontrado para a partição mensal.