Bacterial cellulose membrane as flexible substrate for organic light emitting devices

Bacterial cellulose (BC) membranes produced by gram-negative, acetic acid bacteria (Gluconacetobacter xylinus), were used as flexible substrates for the fabrication of Organic Light Emitting Diodes (OLED). In order to achieve the necessary conductive properties indium tin oxide (ITO) thin films were deposited onto the membrane at room temperature using radio frequency (r.f) magnetron sputtering with an r.f. power of 30 W, at pressure of 8 mPa in Ar atmosphere without any subsequent thermal treatment. Visible light transmittance of about 40% was observed. Resistivity, mobility and carrier concentration of deposited ITO films were 4.90 x 10(-4) Ohm cm, 8.08 cm(2)/V-s and -1.5 x 10(21) cm(-3), respectively, comparable with commercial ITO substrates. In order to demonstrate the feasibility of devices based on BC membranes three OLEDs with different substrates were produced: a reference one with commercial ITO on glass, a second one with a SiO(2) thin film interlayer between the BC membrane and the ITO layer and a third one just with ITO deposited directly on the BC membrane. The observed OLED luminance ratio was: 1; 0.5; 0.25 respectively, with 2400 cd/m(2) as the value for the reference OLED. These preliminary results show clearly that the functionalized biopolymer, biodegradable, biocompatible bacterial cellulose membranes can be successfully used as substrate in flexible organic optoelectronic devices. (C) 2008 Elsevier B.V. All rights reserved.

Modelling study of the impact of deep convection on the utls air composition - Part I: Analysis of ozone precursors

The aim of this work is to study the local impact on the upper troposphere/lower stratosphere air composition of an extreme deep convective system. For this purpose, we performed a simulation of a convective cluster composed of many individual deep convective cells that occurred near Bauru (Brazil). The simulation is performed using the 3-D mesoscale model RAMS coupled on-line with a chemistry model. The comparisons with meteorological measurements show that the model produces meteorological fields generally consistent with the observations. The present paper (part I) is devoted to the analysis of the ozone precursors (CO, NO x and non-methane volatile organic compounds) and HO x in the UTLS. The simulation results show that the distribution of CO with altitude is closely related to the upward convective motions and consecutive outflow at the top of the convective cells leading to a bulge of CO between 7 km altitude and the tropopause (around 17km altitude). The model results for CO are consistent with satellite-borne measurements at 700 hPa. The simulation also indicates enhanced amounts of NO x up to 2 ppbv in the 7-17 km altitude layer mainly produced by the lightning associated with the intense convective activity. For insoluble non-methane volatile organic compounds, the convective activity tends to significantly increase their amount in the 7-17km layer by dynamical effects. During daytime in the presence of lightning NO x, this bulge is largely reduced in the upper part of the layer for reactive species (e.g. isoprene, ethene) because of their reactions with OH that is increased on average during daytime. Lightning NO x also impacts on the oxydizing capacity of the upper troposphere by reducing on average HO x, HO 2, H 2O 2 and organic hydroperoxides. During the simulation time, the impact of convection on the air composition of the lower stratosphere is negligible for all ozone precursors although several of the simulated convective cells nearly reach the tropopause. There is no significant transport from the upper troposphere to the lower stratosphere, the isentropic barrier not being crossed by convection. The impact of the increase of ozone precursors and HO x in the upper troposphere on the ozone budget in the LS is discussed in part II of this series of papers.

Degradation analysis of the SnO2 and ZnO-based varistors using electrostatic force microscopy

The degradation phenomena of ZnO and SnO2-based varistors were investigated for two different degradation methods: DC voltage at increased temperature and degradation with 8/20 μs pulsed currents (lightning type). Electrostatic force microscopy (EFM) was used to analyze the surface charge accumulated at grain-boundary regions before and after degradation. Before the degradation process, 85% of the barriers are active in the SnO2 system, while the ZnO system presents only 30% effective barriers. Both systems showed changes in the electrical behavior when degraded with pulses. In the case of the ZnO system, the behavior after pulse degradation was essentially ohmic due to the destruction of barriers (about 99% of the interfaces are conductive). After the degradation with 8/20 μs pulsed currents, the SnO2 system still presents nonohmic behavior with a significant decrease in the quantity of effective barriers (from 85% to 5%). However, when the degradation is accomplished with continuous current, the SnO2 system exhibits minimum variation, while the ZnO system degrades from 30% to 5%. This result indicates the existence of metastable defects of low concentration and/or low diffusion in the SnO2 system. High energy is necessary to degrade the barriers due to defect annihilation in the SnO2 system. © 2013 The American Ceramic Society.

Desenvolvimento de hardware e software para tratamento e visualização de dados de descargas atmosféricas aplicados à segurança da navegação hidroviária

Pós-graduação em Engenharia Elétrica - FEIS

Sistema de aterramento com cabo contrapeso representado por linhas de transmissão implementado em Matlab com circuitos em cascatas de PÍ

Pós-graduação em Engenharia Elétrica - FEIS

Estudo do aterramento dos pés de torres de linha de transmissão frente às descargas atmosféricas

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Avaliação da suscetibilidade eletromagnética dos cabos metálicos dos sistemas de supervisão, proteção, comunicação e controle de subestações de alta tensão

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Diagnóstico do sitema de prevenção e combate a incêndios florestais na Fazenda Monte Alegre em Agudos

Pós-graduação em Agronomia (Energia na Agricultura) - FCA

Estudo do desempenho de sistemas de aterramento frente às descargas atmosféricas em instalações de baixa e média tensão

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Implementação computacional para avaliar os níveis de sobretensões atmosféricas induzidas em linhas de distribuição

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Avaliação, modificação e validação de metodologia para estudo de estabilidade de hidroquinona em creme

Pós-graduação em Ciências Farmacêuticas - FCFAR

Estudo e desenvolvimento do índice potencial de impacto de descargas atmosféricas em linhas de transmissão

Pós-graduação em Engenharia Mecânica - FEG

Analysis of the electrical characteristics and surge protection of EHV transmission lines supported by tall towers

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Pós-processamento de formas de ondas oriundas de descargas atmosféricas no Centro de Estudos de Descargas Atmosféricas e Alta Tensão (CENDAT) – IEE/USP

Atmospheric Discharges are responsible for several lost in the electrical system therefore it´s done studies to find ways to reduce the problem caused by discharges. This branch of engineering is necessary the gathering, stock and analysis of large quantity of data to validate or refuse the many studies produced about it The CENDAT proposed a project to collect data on induced voltages in distribution lines and current waveform of the lightning, but a difficulty that arose was the accumulation of data due to lack of manpower available to catalog all the data collected. Thinking in this difficulty, the engineer Acacio Silva Neto CENDAT´s researcher with trainees began to develop a program to solve this problem. This work keeps the development of this program in order to solve the problem of accumulation of data

Uso do ATP para simulações de descargas atmosféricas em para-raios de 15 kV dos serviços auxiliares de subestações de energia elétrica

This paper addresses the topics required for the selection of surge arresters used, the output of autotransformers, which protect the system Auxiliary Services (SE) of an electrical substation. Surge arresters used are part of the Protection System Lightning (SPDA). Transmission lines mostly run through regions with orographic well diversified and have constant weather changes, which lead to many undesirable interactions with electromagnetic phenomena, such as giving rise to blackout on 10 November 2009, which left nine states without power, which led to unplanned shutdowns in the system that left millions of people without electricity. This work of completion is to determine whether the method used in the selection of surge arresters meet the protection needs faced by a substation auxiliary services, through the use of software use ATPDraw