Effect of different surfactants on the shape, growth and photoluminescence behavior of MnWO4 crystals synthesized by the microwave-hydrothermal method

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Influence of doping on the preferential growth of alpha-MoO3

MoO3 is a lamellar material with applications in different areas, as solid lubricants, catalysis, solar cells, etc. In the present work, MoO3 powders, synthesized by the polymeric precursor method, were doped with nickel or cobalt. The powder precursors were characterized by TG/DTA. After calcination between 500 and 700 degrees C, the samples were characterized by X-ray diffraction, infrared and Raman spectroscopy and scanning electron microscopy. beta-MoO3 was obtained after calcination at low temperatures. With the temperature increase, alpha-MoO3 is observed, with a preferential growth of the (0 2k 0) planes, when the material is doped and calcined at 700 degrees C. Doping with nickel increases five times the preferential growth. As a consequence, plate-like particles are observed. (c) 2007 Elsevier B.V. All rights reserved.

Modelling of fatigue crack growth following overloads

In variable-amplitude loading there are interaction effects between the loading history and the crack propagation rate. The most important of these effects is the retardation in the crack propagation, which may raise the life of the cracked structureconsiderably. The main objective of this research is to analyse and quantify the retardation of crack propagation in a thin plate of the high-resistance aluminium alloy 2024-T3, comparing the results obtained from the mathematical models proposed to account for the retardation effect. The specimens were tested under high-low loading sequences, for different crack sizes and overload ratios. A simplified model was developed, based on crack closure theory, that could represent the crack behaviour during retardation very well. © 1991.