165 resultados para Compósitos poliméricos. Marcadores magnéticos. Avaliação não destrutiva


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Pós-graduação em Biociências e Biotecnologia Aplicadas à Farmácia - FCFAR

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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

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Pós-graduação em Engenharia Mecânica - FEB

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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

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Este trabalho de pesquisa consistiu na obtenção de compósitos nanoestruturados utilizando matrizes poliméricas termorrígidas e nanotubos de carbono (CNT) e posterior caracterização de suas propriedades mecânicas, térmicas, elétricas, reológicas e demais características físico-químicas para aplicações aeroespaciais. As atividades experimentais para a realização deste trabalho foram, em sua maioria, conduzidas na Alemanha. Durante o desenvolvimento deste trabalho de pesquisa, foi possível entender melhor como deve ser realizada a purificação, funcionalização e dispersão de CNT em compósitos poliméricos. Desta forma, CNT foram caracterizados e utilizados como reforços para a obtenção de compósitos nanoestruturados em matrizes termorrígidas (resina fenólica). Estes compósitos foram processados, por meio de cura em autoclave e avaliados com relação aos seus desempenhos mecânicos, físico-químicos e morfológicos. Duas metodologias foram utilizadas para permitir a dispersão dos CNT: dispersão em solução aquosa e por calandragem (TRC). Os resultados obtidos mostram que a metodologia mais adequada para dispersar os CNT em resina fenólica é a partir do processo por calandragem e que teores superiores a 0,5% em massa de CNT não resultam em melhorias significativas quanto aos desempenhos viscoelástico, térmico, elétrico e mecânico destes compósitos. Ainda, a partir dos ensaios reológicos e elétricos, foi observado que teores abaixo de 0,2% em massa de CNT já são suficientes para promover a percolação dos CNT na resina fenólica, gerando mudanças significativas no comportamento físico-químico do compósito nanoestruturado. A partir deste trabalho de pesquisa...

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The concern with the environment preservation has done with that researchers as well as industries invest in the search for materials that come from renewable sources. Natural fibers, because they are ecologically correct and have low cost, have been studied as a possible substitute, even if partial, of synthetic fibers in the development of polymeric composites. In this context, the hybrid composites (natural/synthetic) increase considerably the range of application of natural composites. The auto industry, in its constant quest for good mechanical properties materials which are developed with sustainability, has in composites with hybrid reinforcement a very viable alternative. In the present work, the nature Crown pineapple fibers and nature Crown pineapple fibers treated with alkaline solution were studied in order to evaluate the influence of chemical treatment in its properties. For this techniques were used x-ray diffractometry, Thermogravimetry and Infrared Spectroscopy (FTIR). Composites have been developed using polypropylene, reinforced with pineapple fibers and pineapple fibers hybrids/glass fibres, both with levels of 5 and 10%. These composites were analyzed by Thermogravimetry techniques and tested by traction. The realization of this work indicated that although the chemical treatment did not affect the thermal stability of the fibers, caused an increase in crystallinity index fibers and decreased its hydrophilic. The tests performed on composite indicated that the composites process was suitable because it provided good dispersion of the polymer matrix. The addition of natural fibers from the pineapple's Crown, in a proportion of 10%, provided the greatest increase in modulus of elasticity (27%) when compared to the pure polymer

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Technology is growing interest in the use of composites, due to the requirement of lighter materials and more resistant, factors essential to meet the project specifications and reduce the operational cost. In the production of high performance structural composites, considering the aerospace criteria, the domestic industry has shown interest in the process of resin transfer molding (RTM) for reproducibility and low cost. This process is suitable for producing components of polymeric composites with relatively simple geometries, consistent thicknesses, high quality finish with no size limitations. The objective of this work was machined carbon steel to make a matched-die tooling for RTM and produce two composite plates of epoxy resin and carbon fiber fabric with and without induced discontinuities, which were compared towards their impregnation with ultrasound, their properties via tensile tests and thermal analysis. In ultrasonic inspection, it was found good impregnation of the preform of both composites. In the thermal analysis it was possible to check the degradation temperature of the composites, the glass transition temperature and it was found that the composites showed no effective cure cycles, but presented good performance in the tensile test when compared with aluminum alloy 7050 T7451 . The results showed that the injection strategy was appropriate since the laminate exhibited a good quality for the proposed application

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Nowadays technological trend is based on finding materials that could support low weight with satisfactory mechanical properties and for this reason composite material became a very attractive topic in research projects all over the world. Due to its heterogenic properties, this type of material shows scatter in mechanical test results, especially in cyclic loading. Therefore it is important to predict its fatigue strength behaviour by statistic analysis, once fatigue causes approximately 90% of the failure in structural components. The present work aimed to investigate the fatigue behaviour of the Twill/Cycom 890 composite, which is carbon fiber reinforced with polymeric resin as matrix and manufactured via RTM process (Resin Transfer Molding). All samples were tested in different tensile level in triplicate in order to associate these values. The statistical analysis was conducted with Two-Parameter Weibull Distribution and then evaluated the fatigue life results for the composite. Weibull graphics were used to determine the scale and shape parameters. The S-N curve for the Twill/Cycom composite was drawn and indicated the number of cycles to occur the first damages in this material. The probability of failure was associated with material reliability, as shown in graphics for the different tensile levels and fatigue life. In addition, the laminate was evaluated by ultrasonic inspection showing a regular impregnation. The fractographic analysis conducted by SEM showed failure mechanisms for polymeric composites associated to cyclic loadings ... (Complete abstract click electronic access below)

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)