O grupo araxá na região sul-sudoeste do estado de goiás

In the S - SW region of Goiás State, Brazil, the Araxá Group is constituted of a metasedimentary sequence containing schistose and gneissic (garnet-biotite-quartz schists, feldspatic garnet-biotite-quartz schists, garnet-biotite-quartz paragneisses, with muscovite and locally amphibole, epidote, kyanite and staurolite. This sequence presents intercalations of metaul-tramafc rocks (serpentinite, actinolite schist, talc schist, chlorite schist), metamafc ones (amphibolite, amphibole schist containing or not garnet, garnet amphibolite) and associated granitic bodies. Chemically, the Araxá Group metasediments present peraluminous composition, showing enrichment in LILE, when compared with HFSE and REE, and displaying negative anomalies of Nb, Ta, Sr, P and Ti. Their chemical composition is that of greywake and the chemical characteristics of the sediments are generated in magmatic arcs. Isotopic data for Sm/Nd - model ages (TDM) between 1,04 - 1,51 and 1,76 - 2,26 Ga - and U/Pb (predominance of zircon with ages < 900 Ma) suggest that these metasediments have Neoproterozoic rocks as the source rocks. Chemical and isotopic characteristics of the studied metasediments suggest that their source are rocks originated in magmatic arcs and that they were deposited in a fore arc basin developed in the margins of Neoproterozoic island arcs.

Commercially pure titanium implants with surfaces modified by laser beam with and without chemical deposition of apatite. Biomechanical and topographical analysis in rabbits

Objectives: The purpose of this study was to evaluate the surfaces of commercially pure titanium (cp Ti) implants modified by laser beam (LS), without and with hydroxyapatite deposition by the biomimetic method (HAB), without (HAB) and with thermal treatment (HABT), and compare them with implants with surfaces modified by acid treatment (AS) and with machined surfaces (MS), employing topographical and biomechanics analysis. Methods: Forty-five rabbits received 75 implants. After 30, 60, and 90 days, the implants were removed by reverse torque and the surfaces were topographically analyzed. Results: At 30 days, statistically significant difference (P < 0.05) was observed among all the surfaces and the MS, between HAB/HABT and AS and between HAB and LS. At 60 days, the reverse torque of LS, HAB, HABT, and AS differed significantly from MS. At 90 days, difference was observed between HAB and MS. The microtopographic analysis revealed statistical difference between the roughness of LS, HAB, and HABT when compared with AS and MS. Conclusions: It was concluded that the implants LS, HAB, and HABT presented physicochemical and topographical properties superior to those of AS and MS and favored the osseointegration process in the shorter periods. In addition, HAB showed the best results when compared with other surfaces. © 2012 John Wiley & Sons A/S.

Further investigation of the initial fission-track length and geometry factor in apatite fission-track thermochronology

The external detector method (EDM) is a widely used technique in fission track thermochronology (FTT) in which two different minerals are concomitantly employed: spontaneous tracks are observed in apatite and induced ones in the muscovite external detector. They show intrinsic differences in detection and etching properties that should be taken into account. In this work, new geometry factor values, g, in apatite, were obtained by directly measuring the ρed/ρis ratios and independently determined [GQR]ed/is values through the measurement of projected lengths. Five mounts, two of which were large area prismatic sections and three samples composed of random-orientation pieces have been used to determine the g-values. A side effect of applying EDM is that the value of the initial confined induced fission track, L0, is not measured in routine analyses. The L 0-value is an important parameter to quantify with good confidence the degree of annealing of the spontaneous fission tracks in unknown-age samples, and is essential for accurate thermal history modeling. The impact of using arbitrary L0-values on the inference of sample thermal history is investigated and discussed. The measurement of the L0-value for each sample to be dated using an extra irradiated apatite mount is proposed. This extra mount can be also used for determining the g value as an extension of the ρed/ρis ratio method. Eight apatite samples from crystalline basement, with grains at random orientation, were used to determine the g-values. The results found are statistically in agreement with the values found for apatite samples (from Durango, Mexico) measured in prismatic section and also measured at random orientation. There was no observable variation in efficiency regarding crystal orientation, showing that it is relatively safe using non-prismatic grains, especially in samples with paucity of grains, as it is the case of most basin samples. Implications for the ζ-calibration and for the calibration of the direct (spectrometer-based) fission-track dating are also discussed.

Evolution of the South Atlantic passive continental margin in southern Brazil derived from zircon and apatite (U-Th-Sm)/He and fission-track data

The area between São Paulo and Porto Alegre in southeastern Brazil plays a key area to understand and quantify the evolution of the South Atlantic passive continental margin (SAPCM) in Brazil. In this contribution, we present new thermochronological data attained by fission-track and (U-Th-Sm)/He analysis on apatites and zircons from metamorphic, sedimentary and intrusive rocks. The zircon fission-track ages range between 108.4 (15.0) and 539.9 (68.4). Ma, the zircon (U-Th-Sm)/He ages between 72.9 (5.8) and 525.1(2.4). Ma, whereas the apatite fission-track ages range between 40.0 (5.3) and 134.7 (8.0). Ma, and the apatite (U-Th-Sm)/He ages between 32.1 (1.5) and 93.0 (2.5). Ma. The spatial distribution of these ages shows three distinct blocks with a different evolution cut by old fracture zones. While the central block exhibits an old stable block, the Northern and especially the Southern block underwent complex post-rift exhumation. The sample of the Northern block shows two distinct cooling phases in the Upper Cretaceous and the Paleogene to Neogene. After sedimentation of the Permian sandstones the samples of the Central block were never heated up over 100. °C with a following moderate to fast cooling phase in Cretaceous to Eocene time and a fast cooling between Oligocene to Miocene. The five thermal models obtained in the Southern block indicate a complex evolution with three cooling phases. The exhumation events of the three blocks correspond with the Paraná-Etendekka event, the alkaline intrusions due to the Trinidad hotspot, and the evolution of the continental rift basins in SE Brazil and are, therefore, most likely to be the major force for the post-rift evolution of the passive continental margin in SE Brazil, which therefore corresponds to the three main phases of the Andean orogeny. © 2013 Elsevier B.V.

Nanostructured materials based on mesoporous silica and mesoporous silica/apatite as osteogenic growth peptide carriers

The aim of this work was the preparation of inorganic mesoporous materials from silica, calcium phosphate and a nonionic surfactant and to evaluate the incorporation and release of different concentrations of osteogenic growth peptide (OGP) for application in bone regeneration. The adsorption and release of the labeled peptide with 5,6-carboxyfluorescein (OGP-CF) from the mesoporous matrix was monitored by fluorescence spectroscopy. The specific surface area was 880 and 484 m2 g- 1 for pure silica (SiO) and silica/apatite (SiCaP), respectively; the area influenced the percentage of incorporation of the peptide. The release of OGP-CF from the materials in simulated body fluid (SBF) was dependent on the composition of the particles, the amount of incorporated peptide and the degradation of the material. The release of 50% of the peptide content occurred at around 4 and 30 h for SiCaP and SiO, respectively. In conclusion, the materials based on SiO and SiCaP showed in vitro bioactivity and degradation; thus, these materials should be considered as alternative biomaterials for bone regeneration. © 2013 Elsevier B.V.

Caracterização metamórfica das rochas do grupo Araxá na região de São Sebastião do Paraíso, Sudoeste de Minas Gerais

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Migração de 226Ra e 228Ra nas águas superficiais e subterrâneas no complexo alcalino do Barreiro de Araxá (MG)

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Ortognaisses peraluminosos associados ao Grupo Araxá na região de Mairipotaba-Prof. Jamil Safady, Goiás

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Estudo de rochas alcalinas intrusivas na região de Três Fontes - MG

Geological researches conducted in the past few years detected, through deep drill hole data, the presence of alkaline rocks in the region of Três Fontes-MG, where the Barbacena Group rocks, the Morro do Ferro Greenstone Belt rocks and Araxá/Canastra groups‟ rocks are exposed. This paper aimed the petrographic and chemical characterization of these alkaline rock types, which have not yet been described in the literature. Based on petrographic descriptions and geochemical and Scanning Electron Microscopy analysis, it was possible to characterize the rock in question as lamprophyre, rich in carbonates, phlogopite, pyroxene, olivine, titaniferous opaque minerals and apatite concentrations that reach 7%. This occurrence corresponds to an alkaline intrusion, which caused brecciation of host rocks, possibly indicating that the material is explosive, however, in the study area there was no evidence of volcanic activity on the surface

Datação por U-Pb em rutilos de rochas de metamorfismo de alta pressão do grupo Araxá na região de São Sebastião do Paraíso - MG

Although several studies of Araxá Group in the region of Passos, just a few works deal with the age of metamorphism of this group. The current work aims to determine the cooling age of these rocks by in situ U-Pb dating in rutiles. Interestingly, the region of São Sebastião do Paraíso shows a condensed lithostratigraphic column from the Passos Nappe and exposes the higher metamorphic grade rocks described for this unit. The use of rutile as a geochronometer is based on its ability to incorporate U in its structure, facilitating the calculation of the age of the isotope ratio by U-Pb. Furthermore, the use of in situ dating technique with Laser Ablation has been a reliable and advantageous study because the analysis are punctual, and do not destroy the whole sample to be analyzed. The analyses of this work were made at the University of Gothenburg - Sweden and obtained 238U/206Pb ages between 608-566 ± 10 Ma and 235U/207Pb between 627-572 ± 10 Ma, showing that these ages are concordant with the literature in the area and are interpreted as the cooling age of metamorphism

Estudo do metamorfismo de rochas de alto grau do grupo Araxá na região de São Sebastião do Paraíso - MG

This study focuses on metasedimentary rocks from the Passos Nappe in São Sebastião do Paraíso, southern Minas Gerais, Brazil. These rocks belong to the Internal Domain (Araxa Group) of the Southern Brasilia Belt, a Neproterozoic orogenic belt associated to the formation of the Gondwana Supercontinent. Rocks from the studied area are characterized by an inverted metamorphic gradient. Previously calculated metamorphic conditions show an increasing from geenschist facies at the base (450°C, 6 kbar), to upper amphibolite facies (750°C, 11 Kbar) at the top of the sequence. However, most of these estimates are based on Fe-Mg exchange thermometers and peak temperatures may be underestimated due to Fe-Mg exchange from cooling after peak metamorphism. In this study, we present new PT results for these rocks, based on metamorphic mineral assemblage LA-ICP-MS analyses. In the studied area, rocks from the top of the sequence have a typical granulite facies mineral assemblage: Grt+Ky+Kfs+/-Pl+liq. These rocks lack muscovite and have only minor amounts of Ti-rich, dark brown biotite. In a simplified NaKFMASH system the stability field for this mineral assemblage is bounded by the reactions Sil = Ky on the low pressure side, Ms+Ab = Ky+Kfs+liq on the low temperature side and for high-Mg bulk compositions Bt + Grt = Opx + Ky + liq on the high-temperature side. Minimum temperatures (considering post-peak reequilibration) of ca. 750°C are obtained by Fe/(Fe+Mg) values of 0.7 in garnets from a Grt+Ky+Kfs bearing sample. LA-ICP-MS results obtained for three samples show that rutiles included in garnets have up to 1847 ppm of Zr, which would translate into temperatures up to 830°C for a pressure between 12 to 15 kbar. Also for retroeclogite sample, the results indicate the contents of Zr in the garnet 537 ppm at a temperature of 708 ° C. It is noteworthy that several occurrences of retroeclogites occur in the upper part of the sequence and pressures...

Ortognaisses peraluminosos associados ao grupo Araxá na região de Rochedo, Goiás

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Group analysis method for fission track thermochronology

A methodology to obtain ages and thermal histories of sets of apatite samples from localities with geologically compatible characteristics is described. A methodology exploring the fact that samples with similar geological characteristics should present the same thermal history is proposed. This approach can contribute for the obtainment of more conclusive results by analysing fewer samples than it is necessary when the samples are individually analysed. In order to determine the ages, we use the absolute neutron dosimetry through thin films of natural uranium along with lambda(f) = 8.46 x 10(-17) a(-1). As an example of application of the proposed methodology, we analyse samples collected in a Brazilian region, Sao Francisco Craton, which experienced low tectonic activity. (C) 2008 Elsevier Ltd. All rights reserved.

Surface characterization of Ti-7.5Mo alloy modified by biomimetic method

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Effect of Iron II on Hydroxyapatite Dissolution and Precipitation in vitro

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)