Avaliação espaço-temporal da distribuição de fósforo na água e nos sedimentos de fundo das sub-bacias dos rios Cuiabá e São Lourenço e em algumas baias do Pantanal Matogrossense

Pós-graduação em Química - IQ

Contaminação das águas subterrâneas por resíduos de postos de combustíveis: uma abordagem no município de Rio Claro

The contamination of underground waters is a subject of great importance, since a lot of people use this kind of source for public supply. This paperwork manages with how gas stations can contaminate these waters and what are some remediation techniques, used nowadays to solve this problem. The contamination caused by the gas stations can have its origin in the underground storage tanks when they suffer corrosion and show leaking problems. It’s a topic of great relevance, because the hydrocarbons derivated from petroleum present in the fuels can stay for a long time in the environment. Besides that, an analyses of the risk of contamination by gas stations in the city of Rio Claro was made based on three parameters: density of the gas stations, depth of the underground water and hydraulic conductivity. To achieve such goal, maps were elaborated considering those parameters individually and considering the three of them together. Analyzing those maps, it was concluded see that the spots that represent the biggest risks of contamination in Rio Claro are located southeast and center-west.

Análise histoquímica do epitélio de escamas de Prochilodus lineatus exposto a águas contaminadas

O Lago Azul (Rio Claro – SP), oriundo da canalização do Córrego Servidão, vem sofrendo com problemas de inundação, infiltração, erosão e contaminação das águas por esgoto. Alguns dos compostos mais despejados nas águas de rios, e responsáveis por tais problemas de contaminação são os detergentes biodegradáveis, que têm sido alvo de críticas, não apenas devido aos problemas de biodegradação, mas também devido ao fato de provocarem o fenômeno conhecido como eutrofização. A preocupação com a possível contaminação das espécies do Lago Azul levou a prefeitura de Rio Claro, junto da SABESP, a iniciar estudos das águas e sedimentos do Lago Azul. Visando essa preocupação o projeto pretende analisar os efeitos da água do Lago Azul e de uma diluição de detergentes em indivíduos de Prochilodus lineatus (Curimbatá), comparados a um controle exposto a água pura clorada do poço artesiano situado no Campus da UNESP de Rio Claro. O projeto procurou caracterizar o epitélio que recobre as escamas da espécie tratada, haja vista que se trata de uma estrutura inexplorada na literatura. A partir desses dados, análises foram realizadas através da detecção de possíveis alterações morfológicas na histologia e histoquímica das células epiteliais de escamas para avaliar os efeitos dos possíveis agentes contaminantes. Para as análises histológicas o material foi processado em resina para as técnicas de Alcian e PAS para detecção de polissacarídeos ácidos e básicos, Azul de Bromofenol para detecção de proteínas, Picrossirus Red para detecção de fibras colágenas I e III e Hematoxilina-Eosina para analisar alterações morfológicas. Os dados coletados foram analisados com auxílio de um microscópio Leica DM 2000, dotado de câmera para captura de imagens

Caracterização hidroquímica dos sistemas aquíferos Serra Geral e Guarani da sub-bacia do Rio Pardo e municípios adjacentes, no sudoeste do estado de São Paulo

The main purpose of this work is to evaluate the chemical composition of the groundwaters from Guarani Aquifer System and Serra Geral Aquifer System in the Rio Pardo basin, located at the southwestern of São Paulo state. To the hydrochemical characterization, physicalchemical analyses from 32 sampled wells were used. These results were plotted in Piper diagrams allowing the classification of groundwater as calcium or calcium-magnesium bicarbonate type and sodium bicarbonate type for both aquifer systems. Distribution of hydrochemical facies over the study area was obtained using Stiff diagrams. The groundwater can be classified, representing in this sequence its hydrochemical evolution. The recognized mechanisms responsible for groundwater evolution are dissolution of minerals magnesium, such as olivine, present in the basalt, dissolution of feldspars and removal of the carbonate cement of the sandstones mineral framework. Ionic exchange may represent an important processes in the groundwater evolution, responsible for the increase in the sodium concentration and decrease of calcium

Análise ambiental simplificada no entorno de águas superficiais na bacia do rio Corumbataí (SP)

The basin of the Corumbataí river is of vital importance to over 600 thousand people, who depend on its waters for consumption. The Simplified Analisys of Environmental Impacts in the Areas Surrounding the Surface Waters of the Drainage Basin of the Corumbataí River (SP) is aimed at defining the areas which are most susceptible to degradation or already damaged and propose engineering solutions according to the environmental problems identified. Using a questionnaire to indicate possible impacts in the surroundings, I related human actions to these damage and quantified them. Having studied the basin extensively and selected 42 areas - generically identified as points and grouped as sub-basins and according to the soil usage -, I was able to identify the main environmental impacts in the basin as: sugar cane monoculture, lack of riparian forest, damaged areas due to mining, the bad state of rural roads and bridges, rubbish disposal alongside roads or directly into the river, accelerated and unplanned expansion of residential and industrial areas into the rural areas and river sources, and Rio Claro's untreated city wastewater

Mapeamento da condutividade hidráulica da cobertura do aquífero Guarani, situado na bacia hidrográfica dos rios Jacaré-Guaçú e Jacaré-Pepira, na porção centro-norte do estado de São Paulo

Given the importance of preserving the water quality of the Guarani Aquifer, the work done in the hydrographic basin of the rivers Jacaré-Guaçú e Jacaré-Pepira, located in the central-northern São Paulo state, was made to map the hydraulic conductivity from the use of some empirical methods associated with granulometric analysis and in situ testing, specifically with the Guelph permeameter. All results were submitted to a correlation analysis and subsequently mapped using the methodology of minimum curvature, based on numerical techniques Spline. These procedures provide for studies of aquifer vulnerability and assist in decision making in environmental projects and guidelines for urban planning

Caracterização da radioatividade das águas do aquífero Guarani

This research aimed to evaluate the quality of “Aquifer Guarani’s” waters in the context of the current legislation related to the radioactive aspects, besides correlating the values obtained with chemical data already available, seeking to make an integrated analysis of the data in order to establish possible tendencies with directions of underground flow. The determinations of the total radioactivity beta and alpha were accomplished through the employment of the available infrastructure at the LABIDRO – Laboratory of Isotope and Hydrochemistry of the Petrology and Metallogeny of UNESP’s Institute of Geosciences and Exact Sciences, largely implanted through resources supplied by FAPESP and CNPq. The systems were gauged for the determinations of interest with tracer of known activity. Preliminaries tests were accomplished with high radioactivity samples of water to check the applicability of the methods. It was ended that the waters analyzed possess low radioactivity, as much alpha as total beta, and, therefore, they are appropriate for the human consumption; that there is not lineal relationship between the obtained data and the chemical data already available; and that the direction of the underground flow of the Aquifer doesn't check any tendency to the generated data.

Análise de fácies sedimentares e de paleocorrentes das sequências inferiores do grupo Itararé, Centro-Leste do estado de São Paulo

The Itararé Group is the record of one of the most significant glaciation events of the Gondwana. Of neocarboniferous-eopermian age, this unit has facies associations interpreted as resulted from shallow marine settings with glacial and deglacial water influence. The role of glaciers on the tectonic-sedimentary processes of the Itararé Group is striking, as typical facies such as diamictites, tilites, shales and rhythmites with dropstones are generated, besides the existence of glacially striated and polished surfaces. This work had as main goal to contribute to the geological knowledge of the Itararé Group in the central eastern portion of São Paulo State, using as basis outcrops from Itu, Salto and Porto Feliz, and also pertinent bibliographic data and well profiles located in the surrounding areas. About the stratigraphic framework, genetic association and paleogeography of these deposits, this work concludes that the area studied comprises the basal section of the Itararé Group. The stacking of the facies recognized during the field work begins with the striated and polished surfaces of the basement, described in Salto, superposed by tilites and diamictites with glacial movement features. Over these are the turbidites from Itu, associated with the glacier retreat. The outcrops of Porto Feliz are at the top of this succession, with deposits generated by flows with lateral and vertical variations, sometimes with prevalence of tractive conditions, and sometimes with sediments transported largely by suspension. Paleocurrent measurements show main flow directions towards NW, the same as glacial striae, suggesting the influence of reworking of sediments by the meltwater during deglacial periods

Caracterização dos usuários do setor urbano privado sujeitos a cobrança pelo uso dos recursos hídricos do Estado de São Paulo nas bacias PCJ e avaliação da demanda de água deste setor como ferramenta de gestão

The present study is about data characterization and evaluation related to private urban users (legal entity) of the Watersheds of the rivers Piracicaba, Capivari, and Jundiai (PCJ), with the PCJ Collection System, sustained by the Department of Water and Power (DAEE), in order to: provide quantitative numbers about this sector, identifying the cities and economic activities corresponding to the largest water consumers, and determine the sector's share in the total charged contribution. The charge for water use is the most recent and the last instrument which has been implemented for the management of water resources, provided by the institution of the State and National Policy of Water Resources in 1991 and 1997, respectively, regarded as an important step towards the preservation and restoration of water resources. According to the data collected in the PCJ Collection System, the urban sector is the private sector that has the highest number of users in these watersheds (52,95% of users), but with less representation in the financial recovery (only 7%), due to its low water demand in their uses compared to the uses of other sectors. The collected data will also serve as both a parameter for comparing the amount of water used by different economic activities and municipalities in the PCJ watersheds and other locations, and as a tool for water resources management

Simulação numérica de fluxo de águas subterrâneas na bacia do Rio Grande (BA)

The Urucuia Aquifer System represents a strategic water source in western Bahia. Its baseflow is responsible for the flow rate of the main tributaries of São Francisco river left bank in the dry season, including the Rio Grande, its main tributary in Bahia state. This river has a hydrological regime heavily affected by groundwater and is located in a region with conflicts about water resources. The aquifers geology is constituted by neocretacious sandstones of Urucuia Group subdivided in Posse Formation and Serra das Araras Formation. The embasement is formed by neoproterozoic rocks of Bambuí Group. This work focuses on an important tool application, the mathematical model, whose function is represent approximately and suitably the reality so that can assist in different scenarios simulations and make predictions. Many studies developed in this basin provided the conceptual model basis including a full free aquifer, lithological and hydraulical homogeneity in entire basin, null flux at plateau borders and aquifer base. The finite element method is the numerical method used and FEFLOW the computational algorithm. The simulated area was discretized in a single layer with 27.357,6 km² (314.432 elements and 320.452 nodes) totaling a 4.249,89 km³ volume. Were utilized 21 observation wells from CERB to calibrate the model. The terrain topography was obtained by SRTM data and the impermeable base was generated by interpolation of descriptive profiles from wells and electric vertical drilling from previous studies. Works in this area obtained mean recharge rates varying approximately from 20% to 25% of average precipitation, thus the values of model recharge zones varying in this range. Were distributed 4 hydraulic conductivity zones: (K1) west zone with K=6x10-5 m/s; (K2) center-east zone with K=3x10-4 m/s; (K3) far east zone with K=5x10-4 m/s; e (K4) east-north zone with K=1x10-5 m/s. Thereby was incorporated to the final conceptual model...

Avaliação da toxicidade sobre Ceriodaphnia dubia das águas dos rios Atibaia, Jaguari e efluente tratado de refinaria de petróleo

Ensuring availability of quality water for human consumption causes becomes an increasing number of studies for the analysis of effluent before and after treatment, so that its release into receiving bodies do not cause significant changes in the river water and on the biological communities related to them. The biomarkers of toxicity have long been used to verify the potential toxic effluent and its correlation with the treatment efficiency of them. In this context, the cladoceran Ceriodaphnia dubia stands out because it is a benthic aquatic organism highly sensitive to environmental changes. In this study, to evaluate the interference of the release of treated wastewater of oil refinery in Rio Atibaia, we sought to determine the toxicity on population dynamics of Ceriodaphnia dubia microcrustacean in water samples upstream and downstream from the launch site, compared with samples from Rio Jaguarí at the point of capture by the company itself and treated effluent. We have studied the number of offspring produced in 10 replicates, each starting with a test individual of up to 24 hours for each sample and correlated the results with physical-chemical and microbiological tests performed by a laboratory technician. For most tests, the results indicate that the treated effluent gives sub-lethal toxicity to the microcrustacean, as delay the onset of the reproductive cycle of the same

Avaliação da vulnerabilidade a contaminação das águas subterrâneas do aquífero Rio Claro na mineração Mandu, distrito de Ajapi - Rio Claro-SP

Groundwater in the Rio Claro district is predominantly extracted from low productivity wells on the Itararé Aquifer, from depths greater than 150 m. These factors in conjunction with increasing demand for water supply have stimulated many industries to exploit the Rio Claro Aquifer, constituted by Cenozoic sediments of the Rio Claro Formation, where hydraulic properties are poorly known. For this reason, it is necessary to study the possible vulnerable to contamination punctual locations of the aquifer, in order to enable proper management of these groundwater reserves and to allow continuity of supply. Thus, this study aims to assess the vulnerability to groundwater on contamination Rio Claro Aquifer, punctually in Mandu mining site area, located in the District of Ajapi, Rio Claro - SP, the company which operates and sells industrial sand. The risk of groundwater contamination depends on the relationship between the hydrogeological characteristics of the aquifer layer (vulnerability to contamination) and the pollutant load. To evaluate the susceptibility to contamination it was applied the method GOD (FOSTER and HIRATA, 1987; FOSTER et. al., 2002) and, in addition, field and laboratory tests were performed to chacacterize the granulometry of the strata, hydraulic conductivity and some physical indices to make the evaluation more assertive and detailed. Punctual contamination vulnerability found in the aquifer Rio Claro, was moderate, which means that the aquifer is vulnerable to some contaminants, but when continuously discharged or leached. Thus, Mandu mining has a great role on preventing the emission of contaminants in the process of extraction and processing of sand... (Complete abstract click electronic access below)

Estrutura populacional e distribuição sazonal de Callinectes ornatus (Decapoda; Brachyura; Portunidae) no litoral norte do Estado de São Paulo, Brasil

Callinectes ornatus tem sua distribuição geográfica no Atlântico ocidental: da Carolina do Norte até a Florida, golfo do México, Antilhas, Colômbia, Venezuela, Guiana e Brasil (Amapá ao Rio Grande ao Sul), ocorrendo em fundos de areia, lama e águas menos salinas podendo alcançar 75 metros de profundidade (Melo, 1996). Essa espécie tem um papel importante na teia trófica marinha, pois possui o habito carnívoro oportunista alimentando se também de detritos, assim controlando a estrutura de várias comunidades bentônicas (Haefner, 1990; Mantelatto & Christofoletti, 2001; Mantelatto et al., 2002). O presente estudo aborda as populações de C. ornatus que vivem no infralitoral não-consolidado das regiões das Ilhas do Mar Virado e das Couves, localizadas no litoral norte do Estado de São Paulo, e teve por objetivo a caracterização dos períodos de recrutamento e reprodutivos da espécie baseado na presença de jovens/adultos e fêmeas ovígeras respectivamente. Os dados utilizados nesse estudo foram coletados do Verão de 1998 á Primavera de 1999 no infralitoral não consolidado das Ilhas do Mar Virado e das Couves totalizando dois anos. As amostragens foram realizadas mensalmente, com auxilio de um barco de pesca equipado com duas redes do tipo “double-rig”. O total coletado durante os dois anos foi de 1164 animais. Os menores indivíduos machos e fêmeas encontrados na Ilha do Mar Virado apresentam os seguintes tamanhos respectivamente 22,2 mm e 17,7 mm, já na Ilha das Couves foram de 20,2 mm e de 32,3 mm. Foi obtido um total de 12 classes de tamanho, com 5,0 mm de amplitude. As duas primeiras classes foram ocupadas apenas por indivíduos jovens já as cinco ultimas principalmente por indivíduos adultos e fêmeas ovígeras. Para os indivíduos machos adultos foi possível observar o deslocamento de modas da Primavera de 1998 à Primavera de 1999... (Resumo completo, clicar acesso eletrônico abaixo)

Dosimetria ambiental do gás 222Rn: um exemplo de estudo das águas da região de Presidente Prudente – SP e considerações sobre abordagem do tema através do Banco Internacional de Objetos Educacionais – BIOE

Over the years, the concern with the detection of the levels of radionuclides in the environment has increased, given that they are carcinogenic to the human respiratory system. Present in the air, waters, soil and building materials, among other substances, radionuclides are unknown by most of the population. In this paper, we present the radioactive gas 222Rn, predominant element among all others and one way of detecting it in an example study of the waters of the Presidente Prudente - SP, through the plastic detector called CR-39. Likewise, we realized the need to approach this issue more broadly in schools and even in higher education, since this field of modern physics and environmental physics usually appears only in master's and doctorate. Thus, we attempted to perform the didactic transposition schooluniversity, through the construction of an object Educational, OE, to be placed on the Bank for International Educational Objects - bioethanol and by developing this contribute to the knowledge and understanding of the importance of monitoring of radioactivity in a way accessible to the population as a whole

Organização e implementação de um banco de dados para a sensibilidade ambiental ao óleo e avaliaçao de ações adequadas de resposta a derramamentos - São Sebastião (SP)

The need to know and to preserve the coastal ecosystems is justified by the whole importance that those ecosystems have for our society. Then, it is big the concern in guaranteeing that those places stay free from contaminations. Among the several types of potentials pollutants that can affect the coastal systems, the petroleum-derived are the ones that cause the worst impacts, given the frequency of these accidents. Rapid actions are necessary in order to minimize the oil negative effects . This answer is faster when the most sensitive areas are known and when it presents characteristics of larger importance, as for instance, the presence of sea harvesting or the habitat of an endemic specie. Besides, it is necessary to know which cleanup methods are recommended and which are not recommended for the reached areas, so, the corrected emergency plans for each coastal environment can be applied. It is in this context that this project was developed, implementing a geographical database for the different coastal environment of São Sebastião municipality, SP, and also the data about the best cleanup techniques for each segment of the coast. This database was made available by the internet, enabling the access for several types of users.