207 resultados para Complexos orgânicos


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Organic- inorganic hybrid (HOI) are materials prepared with the combination of inorganic and organic components. The properties of a hybrid material are unique, not being the sum of each individual component added. This occurs because there is a synergism that depends of the chemical nature of organic and inorganic components, of the size and morphology of their domains. The sodium carboxymethylcellulose (CMC) it's an anionic polymer obtained of the cellulose, very soluble in water in which forms both solutions themselves and gels. The sodium polyphosphate (NaPO3)n, known commercially as Graham Salt is the only polyphosphate soluble in water, and it's the polyphosphate with the longest chain. At the present work it was prepared and characterized new phosphate organic- inorganic hybrids films of carboxymethylcellulose / sodium phosphate and luminescent films of CMC/NaPO3 doped with europium chloride (EuCl3). The films where prepared in several proportions. At first, it was set the amount of water to be used and the amount of carboxymethylcellulose, changing the concentrations of sodium polyphosphate and europium chloride. After pre-establishing concentrations, for each film, the components were submitted to constant agitation and subsequent drying. The inorganic-organic hybrid films were characterized by, TG, DR-X, DMA, FT-IR, UV-Vis-NIR, RMN 31P e 13C and at last, a study of luminescence was made. The hybrid films obtained are transparent and macroscopically homogeneous, however, the MET measures showed the formation of micro-islands of polyphosphate along the material, this fact indicates a bigger fragmentation of the films and this is verified by DMA analysis which shows a smaller resistance of the film with the increase of the concentration of phosphate. Both spectrum FT-IR and RMN analysis of the films, don't show the formation of new bands of their precursors, CMC e NaPO3,....

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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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Pós-graduação em Engenharia Elétrica - FEIS

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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

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Pós-graduação em Engenharia Civil e Ambiental - FEB

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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

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Fundamentados na interação estética entre conteúdo e forma, visa-se delinear uma relação de equivalência frente aos fenômenos da percepção e da expressão. A partir da análise da interação percepção-expressão inserida na natureza humana, seres orgânicos complexos dotados de consciência, objetiva-se estender a questão tanto aos seres orgânicos mais simples, como até mesmo aos inorgânicos, a fim de generalizar tal interação à realidade em si como é experienciada.

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This is a theoretical paper that seeks to work, through interrelations, concepts relating to contemporary aesthetics in parallel to phenomenon of perception. It begins with the aesthetic interaction between content and form in order to trace the development of perceptionexpression interaction, inserted into the mutual action of its physical and psychical aspects "through behind" a thinking mind. In order to generalize such interaction to reality itself as a natural and evolutionary cycle, we start from the analysis of perception of more complex organic beings, endowed with consciousness, to extend the question to the simplest organic beings, as even to inorganics. It is based upon principles of equilibrium and unity in diversity to highlight a historical fact that it seems undeniable: that man evolves and this evolution, their perception clears, while that is particularized your experience and aesthetic judgment. Having in the art, the activity can boost an evolution more profound while pleasurable.

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

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Pós-graduação em Relações Internacionais (UNESP - UNICAMP - PUC-SP) - FFC