Desenvolvimento de um sistema de SHM sem fio e com compensação automática de temperatura

Pós-graduação em Engenharia Elétrica - FEIS

Eletro-oxidação de metanol e etanol sobre PtAu/C em meio alcalino

The development of electrocatalysts for the oxidation of methanol and ethanol is very important, because these alcohols may be used in the anode fuel cells which convert chemical energy directly into electrical energy with high efficiency, cleanly and with low noise. Thus, this study reports to the synthesis of nanocatalysts of PtAu supported on carbon by microemulsion method. The physical characterization of these catalysts is performed through the techniques of X-ray diffraction and transmission electron microscopy. The catalytic activity of the prepared materials was studied using conventional electrochemical techniques and also the technique of spectro-electrochemical in situ FTIR, which allows identification of intermediates and products of the reactions. From the x-ray diffraction, it was observed that the thermal treatment applied to catalysts favored incorporation of Au into the crystal lattice of Pt,that is, increased the formation of PtAu alloy. Micrographs indicated particle size about 3 nm to materials not heat treated and 9 nm to materials subjected to thermal treatment (heating at 150 ° C for 1h and 30 min in argon atmosphere). Current density oxidation of methanol on PtAu / C were superior to pure platinum. Spectroscopic results indicated the presence of formate in solution in 50:50 and the composition showed bands for CO2, indicating complete oxidation, in lower potential. During ethanol oxidation on the catalyst PtAu, the main product formed was acetate, product of incomplete oxidation. The good performance for methanol oxidation can be attributed to large amounts of oxygen species adsorbed on the catalyst surface, or an electronic effect.

Análise de desempenho de redes de comunicação wireless em aplicações de Smart Grid

Pós-graduação em Engenharia Elétrica - FEIS

Processo de obtenção de ácido acrílico a partir do glicerol e uso de vanadosilicatos microporosos no referido processo

A tecnologia descrita na presente invenção se refere ao processo de obtenção de ácido acrílico a partir do glicerol, utilizando vanadosilicatos microporosos como catalisadores de maior seletividade, estabilidade frente à deposição de coque e alta conversão de glicerol em ácido acrílico. Ainda, menciona-se a utilização de catalisadores bifuncionais no referido processo, sendo estes capazes de desidratar o glicerol e oxidar a acroleína formada até ácido acrílico em um único leito catalítico.

Proposta de metodologia para o gerenciamento automático de sistemas fotovoltaicos de geração distribuída

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Aluminas macro-mesoporosas produzidas pelo método sol-gel para aplicação em catálise heterogênea

Pós-graduação em Química - IQ

Estudos sobre a utilização de pentóxido de nióbio nanoestruturado na produção de biodiesel

In heterogeneous catalysis, numerous elements such as titanium and iron have been studied as nanoscale catalysts, but little is known about the use of niobium in nanocatalysis. The nanostructured particles have intrinsic and different physicochemical characteristics with great potential for use in industrial scale. Brazil having the largest known worldwide niobium reserve has the great challenge of creating pioneering technologies with the metal. Biodiesel is an alternative fuel and renewable substitute for regular diesel. Being biodegradable, non-toxic and have CO2 emissions lower than regular diesel, it contributes to the environment and to the independence from oil. The aim of this work was initially synthesize nanoscale particles of niobium pentoxide (Nanospheres, nanorods, nanofibers, nanocubes) from the sol-gel technique. The characterization of different nanoscale structures obtained was performed using different analytical techniques such as x-ray diffraction (XRD) and Scanning Electron Microscopy (SEM). The synthesized nanometer niobium oxide will be used as a heterogeneous catalyst in biodiesel synthesis from commercial soybean oil, checking in detail what the effect of morphology is presented (Nanospheres, nanorods, nanofibers, nanocubes) in the yield of biodiesel synthesis, comparing these results with those already described in literature for the amorphous niobium oxide and other oxide catalysts. The biodiesel obtained was characterized by gas chromatography system equipped with a FID detector

Estudo de caso: do desenvolvimento a aplicação de um jogo computacional para o ensino da tabela periódica

The chemistry is a science little adored by students, because it is a modeling science. The study in chemistry needs a little of abstraction to be able to view something that can not being viewed, that is why chemistry uses many models and tools. The periodic table is a tool useful, but complicated to be understood, where many students end up just decorating for a test, and losing interest in class. The use of ludic games is a way to facilitate the teaching-learning process, because a game has rules to be followed, so the student will get involved to the content to be studied in addition to having to respect rules. Therefore, it is needed that teachers make their lectures more attractive for their students. This work has analyzed an alternative method for teaching the periodic table using basic computer resources, in order to propose a ludic game to a different class, seeking to get the students attention in order to facilitate the understanding of the content

Nanopartículas magnéticas como suporte para imobilização de lipases

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Influência de elementos terras raras nas propriedades catalíticas de óxidos derivados de hidrotalcitas para produção de biodiesel etílico

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Síntese e caracterização da MOF NH2-MIL-125(Ti) e sua aplicação como catalisador na reação de condensação de Knoevenagel

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Obtenção de nanofibras de carbono a partir do processo de eletrofiação

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Simulação de um sistema de reputação centralizado para VANETs

Pós-graduação em Ciência da Computação - IBILCE

Nanopartículas de Pd suportadas em compósitos óxido-carbono: influência das interações metal-suporte na oxidação de etanol em meio básico

Fuel cells powered directly with ethanol (Direct Ethanol Fuel Cell-DEFC) are very attractive for the possibility of using a renewable fuel in the generation of clean energy. However, it is still necessary to deepen the understanding of catalytic processes and their dependence on the catalytic properties. This work proposes to study the catalytic activity of ethanol oxidation in an alkaline medium of Pd nanoparticles supported in carbon oxide hybrids using various transition metal oxides (MoO3, TiO2, WO3 and ZrO2). The materials prepared were characterized by techniques such as X-ray diffraction, transmission electron microscopy (TEM) and X-ray dispersive spectroscopy (EDX) to verify the structure, the distribution of particles in the supports and the presence of Pd on particles oxide. Experiments of X-rays absorption spectroscopy were carried out using soft X-rays (SXS) to evaluate the changes in the electronic properties of the Pd particles caused by interactions with different oxides. Measurements of cyclic voltammetry and potential sweeps of adsorbed CO oxidation allowed evaluating general aspects of the catalysts' electrochemical behavior and determining the electrochemically active area thereof. The catalytic performances of ethanol oxidation in alkaline medium were evaluated by electrochemical techniques (potential scan and chronoamperometry), and showed an improvement in activity with the addition of oxides in material containing only carbon, which was most pronounced for the catalyst containing TiO2. This improvement was predominantly associated with the electronic effects caused by the interaction of Pd on the support, causing a vacancy in the 4d band of Pd which, in turn, produces variations in adsorption energies of the species...

A participação dos medidores eletrônicos na rede inteligente de energia elétrica

Depuis que l'électricité a été découverte et que le secteur électrique s'est considérablement développé dans le XVIIIe siècle, jamais l'homme n'a pu se détacher de cette énergie. Pendant longtemps le système d'énergie électrique a fonctionné sans grand changement, mais avec le développement rapide des technologies, de nouvelles améliorations apparaissent. Ce mémoire traite des nouveaux concepts de réseaux d'énergie électrique appelés Réseaux intelligents ou Smart Grid. À travers un panorama de leurs développements dans le monde, cette étude porte d'une part, sur l'avancée des projets dans quelques pays et d'autre part, du niveau de développement de ce réseau au Brésil et de son intérêt pour le pays. L'étude a comme point central un des composants de ce réseau intelligent, le compteur communicant, qui est l'élément essentiel des interconnexions entre consommateurs et producteurs. Ce rapport apporte un éclaircissement sur les compteurs conventionnels et les compteurs intelligents et sur leur mode de fonctionnement. Enfin il aborde la question des consommateurs : par quels moyens leur transmettre tous ces changements à venir, puisque jusqu'à présent, leur seule participation était de payer l'énergie consommée. Avec le nouveau réseau, ils deviendront de véritables acteurs puisqu'ils seront informés en temps réel de leur consommation d'énergie électrique. Pour terminer, le mémoire montrera comment ils pourront s'adapter à cette nouvelle façon de gérer leur consommation en ésperant les inciter à une utilisation plus raisonnable de l'énergie et à modifier leur comportement en gérant de manière active leur consommation en intégrant notamment les énergies renouvelables