Processo de fabricação de tarugos pelo método HotTop de ligas de alumínio da série 6XXX e as não conformidades desse processamento

The goal of this work is to report some problems that occur in the in the production of aluminum billets (series 6XXX) produced by the hot top process in the Alcoa aluminum Inc. The aluminum fabrication process is described from its first stage, since the mining until the reduction, smelting and treatment of the metal. One of the plant’s final product, are billets for clients that produce profiles by extrusion. The product’s final quality highly depends on the whole production process. Therefore it’s necessary to use good practices in the treatment of the metal, follow up its fabrication and control its thermal treatment, in order to meet the required standards to satisfy the clients. The billet’s production method and its variables will be detailed through temperature and casting speed, cone of water flow, cooling rate, duration of thermal treatment, degassing and metal “in line “filtering, in other words when it’s still found in its liquid state. The non-conformities of the process were studied by metallographic analysis, both macrostutural and microstructural that will be described and discussed in this work

Síntese e caracterização de ferritas de manganês e zinco visando aplicação como agente de contraste em diagnóstico médico

This work aims to synthesize the manganese and zinc ferrite, by the polymeric precursor method, in order to obtain materials with appropriate characteristics for the application in medical diagnosis techniques. The manganese and zinc ferrite powders with the composition of Mn(1-x)ZnxFe2O4, where x=0,23, were prepared and calcined in air at different times and temperatures. The X-ray diffraction (XRD) data show that the sample calcined at 400°C crystallize as ferrite (monophase), but in an inverted spinel structure (high content of iron occupying manganese tetrahedral site and manganese occupying the iron octahedral site). The samples calcined at temperatures between 600°C and 900°C shows the secondary phase of hematite and the sample calcined at 1100oC shows to be monophase in ferrite with normal spinel structure. The monophase powders of ferrite showed a reduction in the surface area and an increasing in the pore size for higher calcination temperatures. The magnetic analysis show that the sample calcined at 400°C presents satisfactory magnetization at room temperature, however, it behaves as diamagnetic material at low temperatures (10K). The powder containing hematite, without the partial substitution of iron ions by manganese, showed to have low transition temperature, and consequently low magnetization at room temperature. The hematite, when partially substituted, provides materials with irregular magnetization at the saturation region. The powder calcined at 1100°C shows high magnetization either at room temperature or low temperature (10K)

Comportamento fractal de superfícies de fadiga em ligas aeronaúticas

Fracture surfaces express sequences of events of energy release with crack propagation in metal alloys, the evolution of topographic features can indicate the lines of load action, failures during the use or processing. The quantitative fractography is an important tool in the study of fracture surfaces, because it allows their interpretation and characterization. In order to evaluate the effectiveness of the characterization of fracture surfaces grounded on concepts such as selfsimilarity and self-affinity, it used the 15-5PH steel that was characterized by metallographic and tensile tests. The metallography allows the microstructural characterization of this steel and proved the presence of the martensite phase in the slats form and a fine-grained, both in the radial and in the axial direction of the dowel. The tensile test (ASTM E8) of this material allowed the determination of the mechanical properties, so based on the obtained results it was possible to affirm that the 15-5PH steel has high mechanical properties and a good stretch. Besides, the specimens also underwent testing of crack propagation, standardized by ASTM E647-00, thus it was obtained the fracture surfaces for characterization under monofractal and multifractal approaches. In front of all the exposed it was possible to conclude that in all measurements the correlation between the crack tip position and the fractal dimension was established in accordance with changes in the thickness and in the fracture micromechanisms presents. Furthermore, the multifractal approach was more sensitive to these variations allowing a more detailed characterization of the morphology

Cimentação de coroas com fosfato de zinco sobre munhões de liga de titânio, irradiados ou não por laser

By means of tensile strength, NiCr total crowns were removed from machine-made conical abutments composed by an Ti-6Al-4V alloy. In a total of 20 abutments, 10 were used with it surface presenting high smoothness and 10 abutments had its surfaces modifi ed by laser both cemented with zinc phosphate. The mechanical test was performed at a MTS 810 universal machine adjusted to a speed of 0.5 mm/m. The statistical analysis was done by Levene’s test, which showed homogeneity of variances among groups (F =2.21; p < 0.1). “Student t test” showed that signifi cant differences were found between groups. The modifi cation of the abutment surface through laser caused an increase in pull-out resistance of crowns cemented with zinc phosphate from 430.66 N to 1.514,87 N.

Atividade antioxidante e determinação de fenóis totais, carotenoides, betacarotenos, licopeno e zinco em variedades branca, amarela e rosada de Manihot Esculenta Crantz

There are cassava varieties that present compounds as carotenoids, beta-carotene, lycopene and minerals important for human and animal health. The present study evaluated the antioxidant activity of the white, yellow and pinkish varieties of Manihot esculenta, by mean of the DPPH test and by the ferrous ion-chelating activity. Furthermore, the total phenols, carotenoids, beta-carotene, lycopene and zinc contents were also determined. Utilizing the DPPH test it was possible to find that extracts of boiled samples presented higher antioxidant activity (89.53% - pinkish) in comparison to the fresh samples (1.97% - white). For the ferrous ion-chelating test, the highest activity was found for the boiled pinkish variety extract (63.43%) and the lowest was for fresh yellow extract (17.34%) the white sample did not present activity. The highest concentration of total phenols and zinc content was obtained for the boiled pinkish variety extract 136.12 mg EAG/g of extract and 0,811ppm, respectively, in the concentration of 1000 µg/mL. The pinkish variety presented also higher quantity of pigments, including carotenoid (29.40 µg/g), beta-carotene (9.14 µg/100g) and lycopene (68.92%). According to the results obtained in this study it was possible to conclude that the yellow and pinkish varieties of M. esculenta present quantity of phenolic compounds and minerals sufficient to attribute the antioxidant activity and may thus contribute to reduce oxidative damage and be used as nutraceuticals or directly ingested in the diet to maintain good health.

Efeitos da corrente elétrica contínua e do sulfato de zinco administrado pela iontoforese transdérmica sobre a cicatrização da pele de ratos diabéticos induzidos pela aloxana: análise morfológica e ultraestrutural

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Estudo do comportamento em fadiga das ligas AA6005, AA6063 e AA6351

Aluminum alloys have shown great potential for the automotive industry, especially aluminum alloys 6xxx series. This category has good mechanical strength and excellent corrosion resistance, important for the areas of construction and transport. The automotive industry has always shown great interest in the study of fatigue behavior, because structural components are subjected to cyclic and vibration loads, generating cracks and fracturing. The mechanical response depends on the material properties, applications, surface condition and microstructure. In this work was study the fatigue behavior of high cycle of machined bodies (not polished) and the effect of roughness on the fatigue life for three aluminum alloys of 6xxx series: AA6005, AA6351 and AA606, all in the T6 condition . S / N curves were made from fatigue tests in rotating bending (R = -1). The influence of roughness was studied by measuring the roughness of each specimen. Was compare the fatigue behavior of polished specimen and not polished specimens. The fractured surfaces of samples were observed by MEV, and it was observed that most of nucleation sites for fatigue crack is initiated below the surface

Formação e crescimento do óxido de zinco e óxido de zinco dopado com cobre

Pós-graduação em Química - IQ

Efeito de elementos susbstitucionais e intersticiais nas propriedades mecânicas e na biocompatibilidade de ligas do sistema Ti-15Zr-xMo

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Equipamento e processo de enriquecimento superficial seletivo de ligas metálicas

Equipamento e processo de enriquecimento superficial seletivo de ligas metálicas. É descrito um equipamento e processo de enriquecimento superficial seletivo de ligas metálicas com controle da velocidade e da intensidade do processo, de forma a permitir controlar a espessura da camada enriquecida e a diminuição do tempo necessário para ser obtida camada enriquecida com espessura desejada.

Propriedades físico-química e antibacteriana de medicações intracanal a base de hidróxido de cálcio e óxido de zinco micro e nanoparticulados

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Contribuição ao estudo do desgaste de bedames na usinagem de ligas de alumínio-silício

Pós-graduação em Engenharia Mecânica - FEIS

Seletividade do clomazone em sementes de algodão tratadas com dietholate e acetato de zinco

The objective of this study objective was to evaluate the selectivity of pre-emergence applications the herbicide clomazone cotton seeds treated with dietholate and zinc acetate. The 4 x 2 factorial arrangement was adopted (4 seed treatment methods and 2 clomazone dosages), distributed in a randomized block design with 4 repetitions. In treatments where dietholate and zinc acetate were applied, rates of 0.4 kg ha(-1) and 8 ml per kg of seeds were used respectively. The clomazone rates used refer to 0.8 and 1.0 kg ha(-1). The cotton cultivar used was the Fiber Max 966 LL. Independent of treatment, all seeds were treated with tiametoxam insecticide and fludioxonil + metalaxyl-M fungicide at rates of 2.24 and 0.08 + 0.03 g per kg of seed, respectively, to control pests early and limit losses caused by pathogens in germination and seedling emergence. Dietholate and zinc acetate treatment had greater initial effect on cotton plants at 21, 30 and 45 days after application. In phytointoxication symptoms were observed for treatment with dietholate and zinc acetate during the evaluation periods. Seeds treated with dietholate, dietholate and zinc acetate or zinc acetate alone provided a higher number of bolls and seed cotton production compared to the control.

Análise da espessura da película de cimentos de ionômero vítreo e fosfato de zinco, empregados na cimentação de coroas totais metálicas, preparadas in vivo

Pós-graduação em Odontologia Restauradora - ICT