The crystal field strength parameter and the maximum splitting of the 7F1 manifold of the Eu3+ ion in oxides

We examine, from both the experimental and theoretical point of view, the behavior of the maximum splitting ΔE, of the 7F1 manifold of the Eu3+ ion as a function of the so-called crystal field strength parameter, Nv, in a series of oxides. In connection with the original theory that describes the relation between ΔE and Nv, a more consistent procedure to describe this relation is presented for the cases of small total angular momentum J. Good agreement is found between theory and experiment. © 1995.

Effect of recasting procedure upon corrosion behavior and metallic ion release of Co-Cr-Mo dental alloy in physiological

Recasting process influence upon corrosion behavior of Co-Cr-Mo dental alloy in simulated physiological serum has been investigated using chemical and electrochemical techniques. Recast Co-Cr-Mo alloy by induction (IND) or by blowtorch (FLAME) has exhibited similar dendritic structures. Both IND and FLAME alloys have presented good corrosion resistance in physiological serum. Passivation process provides this corrosion resistance. Codissolution makes this process difficult. Passive films, formed on these alloys, have been analyzed as a dual layer consisting of an inner barrier and an outer porous layer. Passive film protective characteristics are higher in FLAME than in IND alloy. On this last alloy, the passive film is more porous due to a higher Codissolution. ©Carl Hanser Verlag, München.

Effect of the gadolinium ion on body fluid regulation

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Influence of storage period of pieces in stiffness of pinus elliottii Glulam Beams

This study aimed to investigate the influence of storage time (0, 48 hours) of Pinus elliottii pieces and the tests to obtaining modulus of elasticity (static bending and transversal vibration) in glued laminated timber beams, produced with resorcinol based adhesive and 0.8 MPa compaction pressure. After pieces were properly prepared, part of them was used in immediate three manufacturing glulam beams, tested after adhesive cure, and part stored for 48 hours under a roof with a temperature of 25°C and relative humidity of 60% for subsequent manufacturing and testing three other glulam beams. Results of analysis of variance (ANOVA) revealed that the storage period was significant influence in modulus of elasticity obtained in static bending test (8% reduction from 0 to 48 hours). This not occurred with modulus of elasticity obtained by transversal vibration test (no significant influence). ANOVA results showed equivalence of means in both test procedures. New researches ire needed to better understand the investigated phenomenon, using new wood species, other storage conditions and a great number of samples.