Síntese e caracterização do complexo de lantânio (III) e indometacina no estado sólido

In this study, the drug indomethacin, a non-steroidal anti-inflammatory indoleacetic acid derivative and the complex of indomethacin and lanthanum (III) in solid form were synthesized and characterized by Thermogravimetry (TGA), Differential Thermal Analysis (DTA), Differential Scanning Calorimetry (DSC) and powder X-ray diffractometry (XRD), infrared vibrational spectroscopy by diffuse reflectance (FTIR) and complexometric titration with EDTA. With the TG curves it was possible to determine the stoichiometry of the complex as La(Ind)3·3.5H2O where Ind is the drug indomethacin. The result of thermal analyzes provided information on the thermal stability, enthalpy of dehydration and thermal behavior of the compounds. The infrared spectrum and with the aid of theoretical calculations suggests that the indomethacin is coordinated by the carboxylate group in the bidentate mode

Estudo termoanalítico de complexos do fármaco Ibuprofeno com lantanídeos (III) leves no estado sólido com exceção do promécio

This Final Paper had as it main goal to make a thermoanalytical study of lighter trivalent lanthanides (Lanthanum, Cerium, Praseodymium, Neodymium, Samarium and Europium) with the Ibuprofen ligand (nonsteroidal anti-inflammatory) that have a general formula LnL3.nH2O, on solid state, where Ln are the Lanthanides, L is the Ibuprofen ligand and n = number of water molecules of hydration that went from 1,0 to all the compounds. In order to characterize this compounds, it has been used the thermoanalytical techniques TG-DTA (thermogravimetry - Diferential Thermal Analysis) and DSC (Diferential Scanning Calorimetry), Fourier transformed infrared spectroscopy (FTIR) and complexometric titration with EDTA. Through the TG-DTA technique, it has been possible to set the thermal stability of the compounds, the number of thermal decomposition steps and temperatures that ocurred that also provided stoichiometry to the synthesized compounds. The DSC technique has shown the enthalpy of dehydration of the samarium and europium compounds, it was not possible to see it in the other compounds due to a endothermic peak on the DSC curve not being formed. In the case of neodymium, a thermal event ocurred, in which it could be a oxidative decarboxylation right after the dehydration. The infrared was utilised to study the carboxilate groups streches, and so, suggest a ligand metals compound coordination, that to this present paper has been a bidentade bridged coordenation. At last, the complexometric tritation was used to very the ammount of metal present in each compound, and so, verify if the proposed stoichiometry was according to the theory

Análise da curva de resfriamento e refino de grão da liga de alumínio AA 356

The macrostructure of an alloy solidification in the raw state is of utmost importance due to its influence on mechanical properties. A structure showing columnar grains is generally undesirable in most applications of cast products and grain refining aims to suppress the formation of these grains and get a fine-grained equiaxed structure that improves the supply of liquid metal and the mechanical properties, as yield strength and tensile strength limit, as well as the tendency of formation of hot cracks. The type and size of grains formed are determined by chemical composition, cooling rate and the use of inoculum for grain refining. Titanium and boron are the major refiners in the aluminum industry and can be added to the molten metal in the form of alloys such as Al-Ti, Al-Ti-B or Al-B. In this paper we will discuss the information obtained from cooling curves and first derivative of the cooling curve to obtain the thermal parameters that influence the process of grain refining alloy AA 356.0

A práxis docente fundamentada no programa ler e escrever potencializada pela proposta de educação freiriana: uma confluência em discussão

This study presents results a research held in the framework of, literacy projects and the process of formation of critical consciousness (instances considered, research, literacy essential to the process) and was based on the theory and design education and literacy of Paulo Freire, as well as theories that deal with the acquisition of the writing system and the process of social literacy. The objective is to see how the process of literacy and literacy for children of elementary school second, through teaching practices arising from the current state program, Read and Write and analyze the processes of formation of conscience in this age group, from the educational concepts of Paulo Freire. Was aimed also consider and describe the possible confluence between the pedagogical praxis based on state curriculum and educational proposals frerianas. For the survey, we used the field study of exploratorydescriptive and the methodology developed in three stages, namely: literature review, field research in locus, and data analysis. The instruments used were literature review and annotated by syntheses, systematic observation recorded in field notebook; open a questionnaire, and protocol of semi-structured interview. The survey was conducted in a state school in the city of Bauru, in a classroom of second year of elementary school, I cycle and the research subjects were a literacy teacher and 18 students in that room. This study developed a historical overview of literacy methods, and present the concepts of literacy and literacy in which it is based. The survey results indicate that, on the literacy practices, proposals and guidelines of the Reading and Writing Program meet the expectations which they propose to achieve, on the literacy practices in the classroom are used various kinds of texts, however, not explored are the social aspects of production, ...((Complete abstract click electronic access below)

Marcas da formação escolar, acadêmica e docente: uma análise dos memoriais de formação de alunos(as) do PROESF

This work describes and contextualizes the PROESF - Special Program for Teacher Training Exercise in the early grades of elementary school and children education in municipal schools of metropolitan region of Campinas. The PROESF was organized by University of Campinas (UNICAMP) and remained from 2002 to 2005 graduated about 1600 teachers. The objetives of this course was provide pedagogy formation to teachers in activity in elementary schools and children schools from municipalities of this region. The course also intended to improve the quality of the education and teachers formation. At the final part of course, the teachers had to elaborating a memorial of formation. These materials can be accessed on the website of UNICAMP. The contribution of these memorial of formations can help to think about the teachers formation. This study was a qualitative research from these materials for 2008, and the objective is to identify the marks the formation perceived by these teachers and contributions for them formation. It is understood by marks the formation school memories significant for this group of teachers, stressing the points of what the academic formation contributes for the teacher in day-to-day in the school and what life in the classroom as a teacher marked the teaching practice. After reading the memorials I saw the marks, socialize my memorial, in which one perceives the same brands, presenting a reflection from the living

Educação no campo e educação rural: distinção necessária para compreensão da realidade geográfica

The work’s objective is to point out the difference between rural / urban and country side / city, drawing on the historical process of formation of the terms and analyzing the current dichotomous and continuous, to clarify the concepts of education in rural and rural education, in an attempt to differentiate these types of education in accordance with the schools. Also works with the different conceptions of children, adolescents and youth of the rural that are mostly students from schools in the 1st and 2nd grade. On empirical evidences, we try to adapt the concepts studied in the School Municipal Agricultural Engenheiro Rubens Foot Guimarães, Rio Claro, SP

A empatia, a sensibilização e a formação de professores do ensino público para uma inclusão efetiva de alunos com necessidades educacionais especiais

Special education and inclusion of students with Special Educational Needs (SEN) in regular classrooms of public schools has being widely discussed in academic and political areas. From Salamanca Declaration signed in 1994, which established that the education of people with special needs should be guaranteed by public system, being offered within regular classrooms said. Along the inclusion process, has been observed an increasingly difficult for teachers to work with these special students. This difficulty comes from an incomplete or inadequate formation, resulting in an education that is not always inclusive. The present work aims to investigate what are the motivational factors that lead teachers, working in public schools, to seek continuing courses of formation in specialized educational services, and what are the possible impediments that eschew them from seeking such courses. Data were collected through questionnaires given to elementary school teachers, from public schools in the city of Rio Claro- SP. With their answer, it could be identified what are the motivational factors of the quest for continuing formation, as well as facts that obstruct this specialization. It could be observed that there is a need for constant training of the education professionals, for them to be able to appropriate of the inclusion as a pedagogical approach, not just a law and far from reality

Diversão noturna das juventudes prudentinas: o caso da Mancha de Lazer do Jardim Bongiovani

This work aims to approach the Youth Studies to the Geography. It adressesYouth Sociability through the nightlife entertainment context, considering the spatiality and temporality of this phenomenon and its territorialization in urban space. For this, we made a case study of a Leisure Spot - a centrality formed by the cohesion of evening entertainment establishments, which serves as a reference of entertainment to their attenders and also to the residents of the city - located in the Jardim Bongiovani one of the university district of Presidente Prudente - SP. The study sought to reconstruct the historical process of formation and structuring of that spot, and know its current dynamics, based on Participant Observation. Thus, we sought to identify the social actors that were there and their spatial practices, its paths and streams, the reference group identity, and spatial references and territorializations in the Leisure Spot, and also the ways of the youth to gain visibility in this scenario of urban spectacle

Investigação sobre deformação neotectônica no lineamento Guapiara, região de Guapiara e Jacupiranga

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Formação-Arte-Escrita: contribuições estéticas para a noção de experiência

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Supervisores de ensino da Rede Estadual de São Paulo: entre práticas e representações

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Experiências Comparadas na Educação do Campo entre Brasil e Cuba e as Possibilidades de Formação Omnilateral na América Latina

This text aims to present the challenges and opportunities of omnilateral formation in Latin America as elaborated in Villela (2009-2010). This work has the horizon systematize the educational practices of the “Third World “, i.e. originating from the educational experience of Latin America, Africa and Asia. In the struggle for emancipation, these countries have built and are building unique educational practices. In this sense, we start questioning the historical and theoretical topic, omnilateral formation, and deployment, we discuss the Latin American school and omnilateral formation. We question specifically issues relating to intellectual and educational organization working in the “field schools” in Cuba (1960-1975). The issue of “intellectual and organizational culture”, in a Gramscian perspective (Gramsci, 2000), was addressed in several papers throughout our academic career (Villela, 2003, 2008, 2009-2010). In order to further these issues, we address the challenges of formation for children and rural youth in Latin America. By analyzing the educational practices in the education field, emerges the theme of contemporary global justice.

O espaço dos homens plenos: experiência comparada na educação do campo entre brasil e cuba e as possibilidades de formação omnilateral

This text aims to present the challenges and opportunities of omnilateral formation as elaborated in Villela (2009-2010). This work has the horizon systematize the educational practices originating from the educational experience of Brasil and Cuba. In the struggle for emancipation, these countries have built and are building unique educational practices. In this sense, we start questioning the historical and theoretical topic, omnilateral formation, and deployment, we discuss school and omnilateral formation. We question specifically issues relating to intellectual and educational organization working in the field schools in Cuba (1960-1975). The issue of intellectual and organizational culture, in a Gramscian perspective (Gramsci, 2000), was addressed in several papers throughout our academic career (Villela, 2003, 2008, 2009). In order to further these issues, we address the challenges of formation for children and rural youth in Latin America. By analyzing the educational practices in the education field, emerges the theme of contemporary global justice.

Práticas Educativas Comparadas em Educação do Campo e os Desafios da Formação Omnilateral na América Latina

This text aims to present the challenges and opportunities of omnilateral formation in Latin America as elaborated in Villela (2009-2010). This work has the horizon systematize the educational practices of the "Third World ", i.e. originating from the educational experience of Latin America, Africa and Asia. In the struggle for emancipation, these countries have built and are building unique educational practices. In this sense, we start questioning the historical and theoretical topic, omnilateral formation, and deployment, we discuss the Latin American school and omnilateral formation. We question specifically issues relating to “intellectuals and the organization of culture” in "schools in the countryside" in Cuba (1960- 1975). The issue of "intellectuals and the organization of culture", in a gramscian perspective (GRAMSCI, 2000), was addressed in several works throughout our academic career (VILLELA, 2003; 2008; 2009-2010). In order to further these issues, we address the challenges of formation for children and youth of the field in Latin America. By analyzing the educational practices in the schools in the countryside, emerges the theme of contemporary global justice.

Capitalismo, trabalho e formação profissional: dilemas do trabalho cotidiano dos assistentes sociais em Ribeirão Preto - SP

Pós-graduação em Serviço Social - FCHS