183 resultados para Catálise homogênea
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This work presents a proposal to create a Polo Ceramic Craft in the town of Indiana - SP, through the potter’s organization in a cooperative that will coordinate activities to add value to ceramic pieces. To achieve this, two things are essential: improving the ceramic body and improve the properties of the ceramic material. For the first action it’s necessary to create a Central Mass Production of Ceramics, to provide raw materials and homogeneous composition that results in differentiated ceramic after burning process (sintering). To this end, we propose the incorporation of additives (which act as fluxes) to the clay material. These additives can be mineral such as feldspar and nefelinas or leavings, such as glass powder obtained from disposable containers. For the second action is necessary to acquire an oven, electric or gas, it reaches higher temperatures (around 1200 ° C). The presence of the additive and burning at higher temperatures will enable better production of sintered ceramic material with less porosity and water absorption and higher mechanical strength, and pieces vitrified and glazed, allowing them to assign a higher value. For the production of these materials (thinner walls) requires a smaller volume of clayey raw materials. Besides benefiting the ceramic pieces, the proposed changes reduce the environmental impact caused by burning wood, since it will be replaced by natural gas (or electricity), and even will reduce the disposal of glass containers in the environment by recycling and incorporating this material in the clay. From a social standpoint, the cooperative is crucial to the viability of the proposed project, to coordinate activities and commercial production, which will result in better wages and profits for companies and consequently for the city and its population
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Airplane Motor Cradles have a complex geometry, since they require different conbinations between different tubes and TIG welded in several angles. In T-25 aircraft and Universal T-27 Tucano (EMBRAER / FAB), besides having to bear the engine balance, these components maintain fixed the nose landing gear in another extremity. They are considered critical to flight safety, and for this reason, the aviation standards are extremely rigid in their production, imposing a zero index” of defects on the final weld metal quality. These structures may be containing an historical of welding repairs, whose effects on their structural integrity are not computed. In this work we analyzed the standardised AISI 4130 steel and the raw steel of tubes to the Airplane Motor Cradles. First of all, microscopy and microanalysis of the base steel, then we analyzed the effects of the TIG weld. Tensile testing was conducted to measure the difference between the mechanical properties of standardised steel and without this treatment
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The increasing application of structural composites in the aerospace industry is mainly due to its low specific weight coupled with its excellent mechanical properties when in service. As a result of climatic variations that pass the aircraft is of paramount importance to study the influence of weathering on this type of material when subjected to such changes. The purpose of this work is to evaluate the mechanical behavior of specimens of kevlar fiber /epoxy matrix composites, by dynamic mechanical thermal analysis (DMA) and interlaminar shear strength tests (ILSS), after passing through three environmental conditioning: saline fog, hygrothermal and ultraviolet radiation. From the results, we concluded that the laminate was molded supplied homogeneously, not presenting problems such as porosity, delaminations or cracks inside. After a period of 625 hours of exposure to hygrothermal conditioning, we observed a 1,2% maximum of absorption of moisture. Samples subjected to the conditioning by UV irradiation (600 hours) and salt spray showed a reduction of about 24,30% and 32,30%, respectively, on the shear strength (ILSS). In DMA analysis is not observed significant changes on the glass transition temperature. However, when considering the storage modulus of the samples conditioned by UV radiation (1200 hours), salt spray and hygrothermal conditioning there is an increase of 5,34% , 7,19% and 5,57% respectively
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A survey we conducted, and bring expressed in this text is a preliminary study on the shape of asteroids and allowed us to understand a little more the dynamics around these bodies, in order that the images we have of asteroids are the most irregular possible. In this work, the asteroid is modeled by the method of the polyhedron, which provides a very good accuracy of the irregular shape of the body. Through study of models for non-spherical gravitational potential bodies, implementation of computational algorithms and numerical simulations a preliminary analysis was performed in relation to the shape of asteroids 4179 Toutatis, 6489 Golevka, 2063 Bacchus, 1620 Geographos and 1998 ML14, as well as regions of stability instability, we compute the coefficients of the gravitational potential. The work not only enables expansion for the case of asteroids, but also for other non-spherical bodies, contributing to the development of targeted studies the origin and evolution of the solar system, and perhaps the origin of the earth, and new technologies for modeling and mapping of non-spherical bodies. The main results were obtained by analyzing the graphics format and planning of asteroids, which confirmed how these bodies are irregular and show how distribution of non-homogeneous mass. Observe the behavior of the curves of zero velocity and equipotential curves as well as their respective surfaces. Also, compute some values of the gravitational potential and the spherical harmonic coefficients of each object. Furthermore, we find possible equilibrium points of asteroids except 4179 Toutatis, and analyze its stability
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Titanium has proven its suitability as an implant material in surgery over many years. Excellent biocompatibility and corrosion resistance are outstanding features. Implant surfaces always causes concern and interest in scientific communities, due to its close relationship with the time required for osseointegration. Surface modification can be performed by several methods, being laser irradiation one of them. Titanium implants with two different surfaces were inserted in rabbits: Group I (G-I: machined surface, control group), and group II (G-II: laser irradiated, test group) being processed 30 and 60 days after surgery for histological analysis. Surface characterization was performed with SEM-EDS, contact angle measurement, and mean roughness (Ra) parameters. Surface analysis in the GII group showed a nanomorphology affected by melt and quick solidification zones following laser irradiation (SEM), as well as total wettability and Ra mean values significantly higher than in the G-I group. The laser treatment resulted in a homogenized, porous surface, with increased surface area and volume. Histological analysis of bone-implant contact linear extension (BIC) showed better results in G-II at 30 days (39.26 ± 18.23 and 68.41 ± 13.68 for G-I and G-II groups, respectively). Titanium implants modified by laser irradiation showed important features that may accelerate early osseointegration.
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Pós-graduação em Odontologia Restauradora - ICT
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Pós-graduação em Biopatologia Bucal - ICT
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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
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Pós-graduação em Química - IQ
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Pós-graduação em Química - IQ
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O fenômeno da prostituição não se configura como uma classe homogênea de comportamentos e/ou identidades sexuais e de gênero. Este estudo de caso, qualitativo-descritivo, teve por objetivo geral investigar as concepções sobre a prostituição sob o ponto de vista de quem realiza os programas. Os relatos de um profissional do sexo foram obtidos por meio de entrevista e foram agrupados nas seguintes categorias temáticas: (1) Construção identitária e relações familiares, (2) Caracterização sobre a atividade da prostituição e (3) Aspectos sociais: reflexos do estigma e do preconceito. A análise evidencia uma relação conflituosa e ambivalente entre machismo, homofobia e construção da masculinidade na atividade da prostituição viril que se revela, na sociedade machista, circunscrita a um território recoberto pela vergonha, preconceito e homofobia.
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Pós-graduação em Medicina Veterinária - FCAV
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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
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The present study was developed in two streams from the two different drainage basins located in the mid-southern region of Paraná state. In each stream were evaluated some physical and chemical parameters in open (without streamside vegetation) and shaded (with streamside vegetation) segments. Monthly samplings were carried out from January to December 2007. The following limnological parameters were measured: water temperature, specific conductance, oxygen saturation, pH, turbidity and current velocity. In the same stream were not observed differences among segments from the drainage basins, and nominal values and seasonal pattern have been very similar between open and shaded ambient. A Principal Component Analysis (PCA) showed small divergence between streams and segments, with separation of groups with base sampling dates. The results suggest that the region is homogeneous according to physical and chemical water conditions, therefore, stronger influenced for time factor, and diverging seasonal periods associated a climatic region condition.