Efeito da adição dos azocorantes DR73 e DB79 nas propriedades do poli(metacrilato de metila)

Currently new polymeric materials have been developed to replace other of traditionally materials classes. The use of dyes allows to expand and to diversify the applications in the polymeric materials development. In this work the behavior and ability of azo dyes Disperse Blue 79 (DB79) and Disperse Red 73 (DR73) on poly(methyl methacrylate) (PMMA) were studied. Two types of mixtures were used in the production of masterbatches: 1) rheometer 2) solution. Processing by extrusion-blow molding of PMMA was carried out in order to evaluate the applications of polymeric films. Thermal analysis were performed by thermogravimetry to evaluate polymer and azo dyes thermal stability. Colorimetric analysis were obtained through monitoring the spectral variations associated with sys/trans/anti azo dyes isomerization process Colorimetric data were treated and evaluated in accordance to the color system RGB and CIEL*ab, by monitoring the color change as function of time. Mechanical properties, characterized by tensile tests, were evaluated and correlated with the presence and content of azo dyes in the samples. Analyses by scanning electronic microscopy (SEM) were performed on the surfaces of samples to check the azo dye dispersion after the mixing process. It was concluded that the production of PMMA/azo dyes is possible and feasible, and the mixtures produced had synergy of properties for use in various applications

Uma implementação da análise de componentes independentes em plataforma de hardware reconfigurável

Blind Source Separation (BSS) refers to the problem of estimate original signals from observed linear mixtures with no knowledge about the sources or the mixing process. Independent Component Analysis (ICA) is a technique mainly applied to BSS problem and from the algorithms that implement this technique, FastICA is a high performance iterative algorithm of low computacional cost that uses nongaussianity measures based on high order statistics to estimate the original sources. The great number of applications where ICA has been found useful reects the need of the implementation of this technique in hardware and the natural paralelism of FastICA favors the implementation of this algorithm on digital hardware. This work proposes the implementation of FastICA on a reconfigurable hardware platform for the viability of it's use in blind source separation problems, more specifically in a hardware prototype embedded in a Field Programmable Gate Array (FPGA) board for the monitoring of beds in hospital environments. The implementations will be carried out by Simulink models and it's synthesizing will be done through the DSP Builder software from Altera Corporation.

Um estudo da abundância de lítio, rotação, atividade cromosférica e magnetismo das estrelas análogas e gêmeas solares

The study physical process that control the stellar evolution is strength influenced by several stellar parameters, like as rotational velocity, convective envelope mass deepening, and magnetic field intensity. In this study we analyzed the interconnection of some stellar parameters, as Lithium abundance A(Li), chromospheric activity and magnetic field intensity as well as the variation of these parameters as a function of age, rotational velocity, and the convective envelope mass deepening for a selected sample of solar analogs and twins stars. In particular, we analyzed the convective envelope mass deepening and the dispersion of lithium abundance for these stars. We also studied the evolution of rotation in subgiants stars, because its belong to the following evolutionary stage of solar analogs, and twins stars. For this analyze, we compute evolutionary models with the TGEC code to derive the evolutionary stage, as well as the convective envelope mass deepening, and derive more precisely the stellar mass, and age for this 118 stars. Our Investigation shows a considerable dispersion of lithium abundance for the solar analogs stars. We also realize that this dispersion is not by the convective zone deep, in this way we observed which the scattering of A(Li) can not be explained by classical theories of mixing in the convective zone. In conclusion we have that are necessary extra-mixing process to explain this decrease of Lithium abundance in solar analogs and twins stars. We analyzed the subgiant stars because this are the subsequent evolutionary stage after the solar analogs and twins stars. For this analysis, we compute the rotational period for 30 subgiants stars observed by Co- RoT satellite. For this task we apply two different methods: Lomb-Scargle algorithm, and the Plavchan Periodogram. We apply the TGEC code we compute models with internal distribution of angular momentum to confront the predict results with the models, and the observational results. With this analyze, we showed which solid body rotation models are incompatible with the physical interpretation of observational results. As a result of our study we still concluded that the magnetic field, convective envelope mass deepening, and internal redistribution of angular momentum are essential to explain the evolution of low-mass stars, and its observational characteristics. Based on population synthesis simulation, we concluded that the solar neighborhood presents a considerable quantity of solar twins when compared with the discovered set nowadays. Altogether we foresee the existence around 400 solar analogs in the solar neighborhood (distance of 100 pc). We also study the angular momentum of solar analogs and twins, in this study we concluded that added angular momentum from a Jupiter type planet, putted in the Jupiter position, is not enough to explain the angular momentum predicted by Kraft law (Kraft 1970)

Efeito da adição dos azocorantes DR73 e DB79 nas propriedades do poli(metacrilato de metila)

Currently new polymeric materials have been developed to replace other of traditionally materials classes. The use of dyes allows to expand and to diversify the applications in the polymeric materials development. In this work the behavior and ability of azo dyes Disperse Blue 79 (DB79) and Disperse Red 73 (DR73) on poly(methyl methacrylate) (PMMA) were studied. Two types of mixtures were used in the production of masterbatches: 1) rheometer 2) solution. Processing by extrusion-blow molding of PMMA was carried out in order to evaluate the applications of polymeric films. Thermal analysis were performed by thermogravimetry to evaluate polymer and azo dyes thermal stability. Colorimetric analysis were obtained through monitoring the spectral variations associated with sys/trans/anti azo dyes isomerization process Colorimetric data were treated and evaluated in accordance to the color system RGB and CIEL*ab, by monitoring the color change as function of time. Mechanical properties, characterized by tensile tests, were evaluated and correlated with the presence and content of azo dyes in the samples. Analyses by scanning electronic microscopy (SEM) were performed on the surfaces of samples to check the azo dye dispersion after the mixing process. It was concluded that the production of PMMA/azo dyes is possible and feasible, and the mixtures produced had synergy of properties for use in various applications