Mecanismos de desgaste de poliuretano em ensaios de microabrasão

Wear mechanisms and thermal history of two non-conforming sliding surfaces was investigated in laboratory. A micro-abrasion testing setup was used but the traditional rotative sphere method was substituted by a cylindrical surface of revolution which included seven sharp angles varying between 15o to 180o. The micro-abrasion tests lead to the investigation on the polyurethane response at different contact pressures. For these turned counterfaces with and without heat treatment. Normal load and sliding speeds were changed. The sliding distance was fixed at 5 km in each test. The room and contact temperatures were measured during the tests. The polyurethane was characterized using tensile testing, hardness Shore A measurement, Thermogravimetric Analysis (TGA), Differential Scanning Calorimetry (DSC) and Thermomechanical Analyze (TMA). The Vickers micro-hardness of the steel was measured before and after the heat treatment and the metallographic characterization was also carried out. Worn surface of polyurethane was analysed using Scanning Electron Microscope (SEM) and EDS (Electron Diffraction Scanning) microanalyses. Single pass scratch testing in polyurethane using indenters with different contact angles was also carried out. The scar morphology of the wear, the wear mechanism and the thermal response were analyzed in order to correlate the conditions imposed by the pressure-velocity pair to the materials in contact. Eight different wear mechanisms were identified on the polyurethane surface. It was found correlation between the temperature variation and the wear scar morphology.

Evolução termocronológica do sistema de falhas Senador Pompeu-CE

The region of the Senador Pompeu Shear Zone (SPSZ), in the North Tectonic Domain of the Borborema Province (BP), has its recent history associated with to South Atlantic Ocean formation event at the Jurassic. A lot of geologics models have discussed about crustal axis elevation in local scale and large scale (Borborema Province), relative to importants regionals tectonics directions of it. The identification and the relationship among this surfaces, stepped in many topographyc levels by tectonics mecanisms, is dificult because of the erosion process on it. Over there, sedimentary deposits is complex and it has not biostratigraphyc record in continental deposits. The analysis metodology on apatita fission-track, in the region of the SPSZ, purpose the more knowledge about morphotectonics mecanisms of the area and the impruvement of its morphotectonics models. For this, it was moleled the age and thermal history of the 11 apatites samples collected on both sides of this shear zone, taking relationships among other results of the thermochronology studies in the BP. Based on the thermal studies in this search, the region of the BP developed on two distint cooling events, separated for one period of relative stabilited. The first episode occur between 130 and 90 M.y., has been began when the samples cross the 120°C isoterm for last time and fineshed at 70°C. The second moment of the cooling process was began about 30 M.y., when the temperature was 90°C, from this to the equlibrium with present surface temperature at 30°C. Some evidences indicated a relacionship between thermal episodes and uplift events of the regional relief. The fundaments of the interpretation was based mainly on comparatives studies among results of the thermochronology analysis and geologics studies about BP. Nóbrega et al.(2005), e.g., on studies about the Portalegre Shear Zone, got similar results on SPSZ, with some details relative to local tectonic activity. Morais Neto et al. (2000) interpreted two importants cooling events in the BP based on their regional studies, that can be associated to regional uplift events. When Assine (1992) studied the stratigraphyc sequences of the Araripe Basin, in the south of Ceará state, conclude that the abrupt return to continentals condictions from the last sedimentar sequency (albiano-cenomaniane) indicate a regional uplift of the NE region of the Brazil at the 100 M.y., in the Albiano Intermediate/Superior. This ages are compatible to termal model of the SPSZ. This two periods of the thermal history of the BP are completely registered in the apatites samples just one age groups of the fission-track, that it is the most ancient age groups. This one suggest it has happened in response to heating before 75 M.y and it has erased the last report of the first moment relief evolution of the BP. The NNE-SSW and E-W structure reativation can have created ideal condictions for heating and local elevations of the geothermal gradients. The equilibrium between the apatites temperatures of this groups and the regionais temperatures took place about 50 M.y., when the samples of the two ages groups had a simillar evolution to present surfaces temperatures

Evolução estrutural e termocronológica meso-cenozóica da Zona de Cisalhamento Portalegre, Nordeste do Brasil

The Portalegre shear zone (ZCPa), which is located in the Rio Grande do Norte and Paraíba states (Northeastern Brazil), is na important right-lateral, northeast-trending lineament formed during the Brazilian Orogenic Cicle). The ZCPa experienced na important brittle reactivation from the Mesozoic until the present. This reactivation led to the formation of the Gangorra, Pau dos Ferros, Coronel João Pessoa, Icozinho and Rio do Peixe basins. The reactivation northern parto f the ZCPa that marks the boundary of the Potiguar Basin is denominated Carnaubais Fault. Several fracture patterns were mapped along the ZCPa. Samples were collected in Neoproterozoic granite outcrops, along the ZCPa. These samples yielded AFT ages from 86±13 to 376±57 Ma, and the mean track length from 10.9±0.8 to 12.9±1.5 mm. Samples from the East block yielded mean ages of 103 Ma, mean track lengtn 12,1mm, and mean altitude 250m, whereas samples from West block yielded mean ages of 150 Ma, which reach 345 Ma and 220 Ma in the Pau dos Ferros and Coronel João Pessoa basins, respectively. Thermal history models were sorted out for each crustal block. Samples from West block recorded a thermal history from Carboniferous Period until the Permiano, when the block experienced gradual uplift until the Cretaceous, when it underwent downfaulting and heating until the Tertiary, and it eventually experienced a rapid uplift movement until recent times. Samples from the East block presented the same cooling and heating events, but at they occurred different times. The East block thermal record started ~140 Ma, when this block experienced cooling until ~75 Ma. Both blocks show a denundacion/erosional history more similar in the Tertiary. The AFT data indicate an important tectonic event ~140 Ma, when the West block experienced downfaulting and the East block experienced uplift. This tectonic process led to the generation of several sedimentary basins in the region, including the Potiguar basin. This tectonic event is also interpreted as a rift process caused by an E-W-trending extension. It the Tertiary, some heating events can be tentatively attributed to the macau volcanic event