Evolution of ethyl carbamate during Madeira wine ageing by GC-MS: a new methodology

Recently, ethyl carbamate (EC) was reclassified by the International Agency for Research on Cancer (IARC) as "probably carcinogenic to humans" and occurs mainly in fermented beverages. Nowadays many countries have set limit values for EC in alcoholic beverages. In this sense and taking into account the low concentrations found in alcoholic beverages, the scientific community has shown interest for the development of new analytical methods, whereby its simplification plays an important role in the EC control and prevention. Firstly, a simple, rapid and sensitive methodology was developed for the EC quantification in fortified wines by microextraction by packed sorbent (MEPS) with gas chromatography coupled with a mass spectrometer detector (GC-MS). This method showed good linearity (R2 = 0.999) and sensitivity (LOD = 1.5 μg/L). The accuracy of the method was assessed by means of repeatability and reproducibility (RSD < 7%). Moreover, a good recovery has been demonstrated (97 – 106%) as well as its applicability (16 fortified wines). Thus, the developed methodology has proven to be an excellent approach for routine quantification of EC in fortified wines. The EC evolution was also evaluated during a year and half of Madeira wine ageing submitted to two traditional ageing methods, estufagem and canteiro, in order to evaluate the formation kinetic. The results revealed that estufagem process increased the formation kinetic and promoted a linear increase of the EC concentration (R2 ≥ 0.977), proportionally to the ageing time (4 months). However, when the wines are firstly submitted to estufagem and then undergo canteiro ageing, the EC values remain almost constant during the following 14 months. The results suggest that estufagem does not seem to be the critical factor in the EC formation, but instead the amount of precursors in the medium.

Predição da criatividade e saúde mental

A criatividade tem sido mencionada desde há muito tempo pela literatura. A forma de a conceptualizar tem dependido em muito dos investigadores e da sua visão sobre o que é criatividade, porém as suas potencialidades têm tomado cada vez mais interesse pela comunidade científica. Os seus benefícios estendem-se a diversas áreas da vida humana, como sentimentos de satisfação, bem-estar e saúde mental. A investigação aqui apresentada procura encontrar modelos preditivos de comportamentos criativos, pressupondo que estes poderão ser de grande auxílio para o desenvolvimento de um melhor bem-estar psicológico. Assim a investigação comportou o uso de quatro variáveis: a pessoa, o processo, o produto e o ambiente criativo. A amostra contou com 215 estudantes universitários e os resultados revelaram o encontro de quatro modelos preditivos de comportamentos criativos, com uma maior ênfase nas artes visuais e manuais. Conclui-se com a ideia de que a predição de produtos criativos é possível e que tal poderá ser preponderante para um bom desenvolvimento da saúde mental.