HAZARD AREAS ASSOCIATED WITH MAJOR VOLCANOES IN THE CASCADE MOUNTAIN RANGE

http://digitalcommons.colby.edu/atlasofmaine2005/1014/thumbnail.jpg

Involvement of free radicals in peroxidatic reactions catalyzed by chloroperoxidase

The mechanism of chloroperoxidase (CPO)-catalyzed peroxidatic reactions of several substituted hydroquinones was studied at various hydrogen peroxide concentrations. The pathway was studied using cytochrome c as the radical trapping agent. As the hydroquinones became more hindered there was a difference in the amount of radicals trapped. For hydroquinone, 59.3% radical pathway, and methylhydroquinone, 81.4% radical, the difference in radicals trapped is due to a difference in pathway. For 2,3-dimethylhydroquinone (75.4%), trimethylhydroquinone (44.5%), and t-butylhydroquinone (0%) other non-peroxidatic reactions are noticed. Thus, for the more substituted hydroquinones the difference in radicals trapped can not be assigned to a difference in radical pathway. Also, there were problems drawing conclusions for this system due to the catalytic reaction of hydrogen peroxide. The radical trapping ability of 2,4,6-trimethylphenol was investigated for various other substrates. TMP reacted with the radicals generated in the enzymatic reactions of phenol, resorcinol, and m-methoxyphenol. Thus, this TMP system offers further potential as another radical trapping agent for use in these studies.

Hazard Areas Associated with Major Volcanoes in the Cascade Mountain Range

The Cascade Mountain Range in Washington State is the site of several active volcanoes that have the potential to erupt which would deeply affect the lives of those who live near them. This study explores the hazard areas associated with the five largest volcanoes in the region: Mt. Baker, Glacier Peak, Mt. Rainier, Mt. Adams and Mt. St. Helens. It was determined which geographic regions would be affected by tephra, pyroclastic blasts and lahar flows and the associated populations that live in each of these areas. The level of emergency preparedness necessary for a volcanic eruption could be better determined based on the findings of this study.