33 resultados para thermal spike model

em Deakin Research Online - Australia


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According to the Intergovernmental Panel on Climate Change the buildings sector has the largest mitigation potential for CO2 emissions. Especially in office buildings, where internal heat loads and a relatively high occupant density occur at the same time with solar heat gains, overheating has become a common problem. In Europe the adaptive thermal comfort model according to EN 15251 provides a method to evaluate thermal comfort in naturally ventilated buildings. However, especially in the context of the climate change and the occurrence of heat waves within the last decade, the question arises, how thermal comfort can be maintained without additional cooling, especially in warm climates. In this paper a parametric study for a typical cellular naturally ventilated office room has been conducted, using the building simulation software EnergyPlus. It is based on the Mediterranean climate of Athens, Greece. Adaptive thermal comfort is evaluated according to EN 15251. Variations refer to different building design priorities, and they consider the variability of occupant behaviour and internal heat loads by using an ideal and worst case scenario. The influence of heat waves is considered by comparing measured temperatures for an average and an exceptionally hot year within the last decade. Since the use of building controls for shading affects thermal as well as visual comfort, daylighting and view are evaluated as well. Conclusions are drawn regarding the influence and interaction of building design, occupants and heat waves on comfort and greenhouse gas emissions in naturally ventilated offices, and related optimisation potential.

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Secondary ion emission from water ice has been studied using Au+, Au3+, and C60+ primary ions. In contrast to the gas phase in which the spectra are dominated by the (H2O)nH+ series of ions, the spectra from ice using all three primary ions are principally composed of two series of cluster ions (H2O)nH+ and (H2O)n+. Dependent on the conditions, the unprotonated series can dominate the spectra. Since in the gas phase (H2O)n+ is unstable with respect to the formation of the protonated ion series, the presence of the solid must provide a means to stabilize their formation. The cluster ion yields under Au+ bombardment are very low and can be understood in terms of sputtering on the borderline between linear cascade and thermal spike behavior. There is a 104 increase in yield across the whole spectrum compared to Au+ when Au3+ and C60+ species are used as primary ions. The character of the spectra differed between these two primary ions, but insights into the mechanism of secondary ion emission for both is discussed within an energy deposition framework provided by the fluid flow-based mesoscale energy deposition footprint (MEDF) model that predicts a cone-shaped zone of activation and emission. C60+ differs from Au3+ in that it delivers its energy closer to the surface, and it is argued this has consequences for the cluster ion distribution and yield. Increasing the ion dose by sputtering suppresses the yield of (H2O)n+ and increases the yield of the protonated ions in the small cluster region, whereas the yield in the large cluster regime is suppressed significantly. The three primary ions show rather different behavior, and this is discussed in the light of the sputtering models. Finally, negative ion spectra including cluster ions have been observed for the first time. C60+ delivers the highest yields, but these are less than 10 times the positive ion yields, probably because the O and OH fragment ions on which the clusters are based are easily neutralized by protons.

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According to the Fourth Assessment Report of the Intergovernmental Panel on Climate Change (IPCC), the construction sector has the greatest potential for climate change mitigation. This work investigates the potential for climate change mitigation in naturally ventilated and mixed mode office buildings, by evaluating the range of influence of building design and occupants on greenhouse gas emissions as well as thermal and visual comfort.

Thermal comfort is evaluated according to the EN 15251 adaptive thermal comfort model, visual comfort is based on daylight autonomy and view. Parametric studies have been conducted based on building simulation for the climate of Athens, Greece. Input data are based on a literature review, and on results from a field study conducted among office occupants and architects in Athens.

The results show that the influence of occupants on greenhouse gas emissions is larger than the influence of building design. Energy saving office equipment, as well as active use of building controls for shading and lighting by occupants are crucial parameters regarding the reduction of CO2 emissions. In mixed mode buildings, the coefficient of performance of the cooling system is an important parameter as well. Regarding thermal and visual comfort, the influence of building design is predominant. A green building, well protected against heat from the sun and able to balance solar and internal heat gains, provides higher comfort levels and is less affected by the influence of occupants. In mixed mode buildings, building design is the predominant influence on the magnitude of cooling loads. A hot summer including heat waves can significantly reduce thermal comfort and increase the resulting greenhouse gas emissions. Green buildings are least affected by these influences.

The EN 15251 adaptive thermal comfort model provides a thermal comfort evaluation method valid throughout Europe. However, for the Mediterranean climate of Athens, Greece, most of the configurations investigated within this study do not meet the requirements according to this model. EN 15251 refers to an adaptive thermal comfort model for naturally ventilated and to a static model for mechanically ventilated buildings. For mixed mode buildings, the static model is recommended, but literature indicates that occupants in those buildings might be more tolerant towards higher temperatures. The hypothetical application of the EN 15251 adaptive thermal comfort model in mixed mode offices, as investigated in this study, shows potential for greenhouse gas emission savings. However, this influence is small compared to that of building design and occupants. Conclusions are drawn regarding the categorisation and exceeding criteria according to EN 15251 adaptive thermal comfort model for offices in a Mediterranean climate.

The results of this work show, that not only green buildings, but also green occupants can significantly contribute to the mitigation of the climate change. Mechanisms of the real estate market as well as the lifestyle of occupants are important influences in this context. Sustainability therefore refers to finding the right balance between occupant’s comfort expectations and resulting greenhouse gas emissions for a specific building, rather than optimisation of single parameters

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Thermo-Electrochemical cells (Thermocells/TECs) transform thermal energy into electricity by means of electrochemical potential disequilibrium between electrodes induced by a temperature gradient (ΔT). Heat conduction across the terminals of the cell is one of the primary reasons for device inefficiency. Herein, we embed Poly(Vinylidene Fluoride) (PVDF) membrane in thermocells to mitigate the heat transfer effects - we refer to these membrane-thermocells as MTECs. At a ΔT of 12 K, an improvement in the open circuit voltage (Voc) of the TEC from 1.3 mV to 2.8 mV is obtained by employment of the membrane. The PVDF membrane is employed at three different locations between the electrodes i.e. x = 2 mm, 5 mm, and 8 mm where 'x' defines the distance between the cathode and PVDF membrane. We found that the membrane position at x = 5 mm achieves the closest internal ΔT (i.e. 8.8 K) to the externally applied ΔT of 10 K and corresponding power density is 254 nWcm-2; 78% higher than the conventional TEC. Finally, a thermal resistivity model based on infrared thermography explains mass and heat transfer within the thermocells.

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 The control of energy distribution or energy intensity inside a laser spot using a defocusing method enables the formation of high-quality microchannels of multiple cross-sections in polycarbonate. Moreover, a thermal mathematical model of the process was developed to aid understanding of the process and to allow channel topology prediction.

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A novel model for calculating dehydrochlorination kinetics at a lower temperature of chlorinated natural rubber (CNR) is presented. It has been observed that dehydrochlorination is complex and involves three different stages. A model that accounts for dehydrochlorination at lower temperature is proposed. The kinetic parameters are obtained from dehydrochlorination experiments at 60-90 °C. The results of the kinetic calculation show that the apparent activation energy decreases with an increment of chlorine content. Higher chlorine content CNR makes it easier to remove hydrochloric acid when heated, but its dehydrochlorination rate affected by temperature is significantly less than that of the sample with a lower chlorine content. The thermogravimetric/derivative thermogravimetry results show that the beginning temperature of thermo-oxidative degradation rises with the increment of chlorine content. During the heating process, the higher chlorine content CNR is more stable than the lower one. The results suggest the storage conditions and basis for selection of appropriate temperature for the preparation of CNR from latex.

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This note is directed to one major aspect of the comfort of building occupants – namely, thermal comfort. Even though it may be difficult to isolate thermal sensations from the whole of comfort itself, humans have a strong physiological connection with their thermal environment. Our thermal perceptions and sensations often vary greatly, especially between our indoor and outdoor environments. We may be totally comfortable lounging under a shade cloth on a 35°C day with a stiff breeze enveloping our body, but would never tolerate similar conditions indoors. Such divergent perceptions of the same thermal stimulus across differing contexts raise countless questions about just what the determinants of thermal comfort actually are, and how they may be managed against the demands for an environmentally responsive architecture.

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A practical experiment is described which was used to help university students increase their understanding of the effect of construction methods and window design on passive solar heating and electrical heating. A number of one tenth scale model rooms were constructed by students and sited out-of-doors in the late autumn. The models were fabricated to mimic available commercial construction techniques with careful consideration being given to window size and placement for solar access. Each model had a thermostatically controlled electric heating element. The temperatures and electricity use of the models were recorded using data-loggers over a two week period. The performances of the models based on energy consumption and internal temperature were compared with each other and with predictions based upon thermal mass and R-values. Examples of questions used by students to facilitate this process are included. The effect of scaling on thermal properties was analysed using Buckingham’s p-theorem.

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A 2100 m2 (GFA) two-storey rammed earth building was built on the Thurgoona campus of Charles Sturt University in 1999. The building is novel both in the use of materials and equipment for heating and cooling. The climate at Wodonga can be characterised as hot and dry, so the challenge of providing comfortable working conditions with minimal energy consumption is considerable. This paper describes a thermal model of one of the second-storey offices on the west-end of the building. The simulation software, TRNSYS, has been used to predict office temperatures and comparisons are made between these and measurements made over a typical week in summer. Reasonable agreement has been achieved under most conditions. The model has been used to investigate key building parameters and strategies, including night flushing, to improve the thermal comfort in the office.

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Seasonal storage systems have been operating in various European countries since 1985. Combined with solar collectors, these systems are known as ‘central solar heating plants with seasonal storage’ (CSHPSS). While these systems have been shown to be technically feasible, their cost is still too high to make them competitive with fossil fuels.

In Australia, we have quite different conditions to those countries where CSHPSS have been trialled. In general, we experience higher radiation levels, ambient temperatures and cooling loads. Our heating loads and energy prices are also usually lower. As a result, any evaluation of CSPSS operating in a European context may not be valid for Australian conditions. To the authors’ knowledge, no evaluation of these systems has been carried out for Australia.

This paper therefore attempts an initial assessment of these systems and their viability for Australia. The paper first describes the various types of CSHPSS and then reviews their current status. The performance of one type of CSHPSS operating in several locations of Australia has been predicted using a TRNSYS model. The simulations indicated that the design guidelines for Europe are inappropriate for Australia and would result in greatly over-sized systems.

An indication of the financial viability of the system was determined by calculating a simple payback period for a variety of fossil fuels. This type of seasonal storage systems appears to be financially attractive in areas of southern Australia where the solar system is displacing LPG.

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A two-storey rammed earth building was built on the Thurgoona Campus of Charles Sturt University in Albury-Wodonga, Australia, in 1999. The building is novel both in the use of materials and equipment for heating and cooling. The climate at Wodonga can be characterised as hot and dry, so the challenge of providing comfortable working conditions with minimal energy consumption is considerable. This paper describes an evaluation of the building in terms of measured thermal comfort and energy use. Measurements, confirmed by a staff questionnaire, found the building was too hot in summer and too cold in winter. Comparison with another office building in the same location found that the rammed earth building used more energy for heating. The thermal performance of three offices in the rammed earth building was investigated further using simulation to predict office temperatures. Comparisons were made with measurements made over typical weeks in summer and winter. The validated model has been used to investigate key building parameters and strategies to improve the thermal comfort and reduce energy consumption in the building. Simulations showed that improvements could be made by design and control strategy changes.

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Using renewable energy sources for onsite cogeneration from structural building elements is a relatively new concept and is gaining considerable interest. In this study the design, development, manufacturing and testing of a novel building integrated photovoltaic/thermal (BIPVT) solar energy cogeneration system is discussed.

Adhesives (ADH), resistance seam welding (RSW) and autoclaving (ATC) were identified as the most appropriate for fabricating BIPVT roofing panels. Of these manufacturing methods ADH was found to be most suitable for low volume production systems due to its low capital cost.

A prototype panel, fabricated using ADH methods, exhibited good thermal performance. It was also shown that BIPVT performance could be theoretically predicted using a one dimensional heat transfer model and showed excellent agreement with experimental data. The model was used to suggest further design improvements. Finally, a transient simulation of the BIPVT was performed in TRNSYS and is used to illustrate the benefits of the system.

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The use of onsite renewable energy cogeneration from structural building elements is a relatively new concept, and one that is gaining considerable interest in the building industry. In this study the design, development, testing and production methods for a novel building integrated photovoltaic/thermal (BIPVT) solar energy cogeneration system are examined and discussed.

During the analysis of the design, adhesives (ADH), resistance seam welding (RSW) and autoclaving (ATC) were identified as the most appropriate for fabricating BIPVT panels for roofing and façade applications. Of these manufacturing methods ADH was found to be most suitable for low volume production systems due to its low capital cost.

Furthermore, a prototype panel was fabricated using ADH methods and exhibited good thermal performance. In addition it was shown, using experimental testing, that the performance of a BIPVT could be theoretically predicted using a one-dimensional heat transfer model. Furthermore, the model was used to suggest further improvements that could be made to the design. Finally, a transient simulation of the BIPVT was performed in TRNSYS and was used to illustrate the long term benefits of the system.

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The idea of combining photovoltaic and solar thermal collectors (PVT collectors) to provide electrical and heat energy is not new, however it is an area that has received only limited attention. With concern growing over energy sources and their usage, PVTs have become an area receiving more attention. Although PVTs are not as prevalent as solar thermal systems, the integration of photovoltaic and solar thermal collectors into the walls or roofing structure of a building could provide greater opportunity for the use of renewable solar energy technologies in domestic, commercial and industrial applications. As such, the design of a novel building integrated photovoltaic/thermal (BIPVT) solar collector is theoretically analysed through the use of a modified Hottel-Whillier model. The thermal and electrical efficiency under a range of conditions are subsequently determined and results showing how key design parameters influence the performance of the BIPVT system are presented.

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The thermal stability of electrochemically prepared polypyrrole (PPy) films with p-toluenesulfonate (pTS) or perchlorate (ClO4) counterion (PPy/pTS and PPy/ClO4) is improved by simple treatment with aqueous sulfuric acid, sodium sulfate or sodium bisulfate. The degree of stabilization achieved depends on the solution, temperature and duration of treatment. Although the mechanism for improved stability is not yet clear, it is apparent that the level of ion exchange and the original polymer microstructure are important. A model for the conductivity decay as a function of thickness has been proposed. The early stages of ion exchange are not symmetrical, and diffusion is facilitated at the electrode side of the film. Furthermore, X-ray diffraction shows no evidence of morphological change after treatment of PPy/pTS (43 μm), but in PPy/pTS (12 μm) and PPy/ClO4 (41 μm) films an additional peak is indicative of more ordered structure following treatment. The glass transition temperature, Tg, of PPy/pTS and PPy/ClO4 films obtained by modulated differential scanning calorimetry is approximately 155°C.