Possible influence of Gondwanan glaciation on low-latitude carbonate sedimentation and trans-equatorial faunal migration: the lower Permian of South China

Peculiar Early Permian palaeontological and sedimentological features are reviewed from South China, including characteristic Early Permian cold-water Gondwanan brachiopod taxa and faunas from Sichuan and Guizhou provinces, widespread rosettes and irregular aggregates of calcite prisms ('Chrysanthemum Stones') within the Qixia limestones, and lack of significant Early Permian reef buildups. The occurrences of these features are at odds with the currently widely held view that South China was located in a palaeotropical, warm-water setting throughout the Permian and hence harboured a highly diverse shallow marine biota. In this paper, I propose a working hypothesis, suggesting that influence of at least cool water masses may have intermittently occurred in South China during the Early Permian, which facilitated the formation of the cool water-influenced palaeontological and sedimentological features and promoted the interchanges of cool to cold water marine faunas between the Gondwanan and Boreal Realms. These cool water masses may have been transported to low-latitude regions as deep currents from northern and eastern shelves of Gondwanaland and upwelled along the western coast of South China as well as within the relatively deep-water basins of central South China. Prevalence of these meridional, north-directed deep cold water currents during the Early Permian may have been related to the glaciation event of Gondwanaland. An alternative and/or additional source of cooling may have also originated from strong easterly palaeoequatorial boundary currents operating within the Palaeotethys at times during the Early Permian, inducing and/or enhancing upwelling of cool to cold water masses in the eastern Palaeotethys. This latter scenario is analogous to the occasional 'La Nina' effect (opposite to the 'El Nino' effect) at the equatorial belt of the modern Pacific Ocean.

A dimeric tellurastannoxane carbonate cluster, tetra-tert-butyl-di-µ3-carbonato-tetrakis-[4-(N,N-dimethylamino)phenyl]di-µ-oxo-ditelluriumditin chloroform tetrasolvate

The title compound, [Sn₂Te₂(C₄H₉)₄(CO₃)₂O₂(C₈H₁₀N)₄]·4CHCl₃ or [(p-Me₂NC₆H₄)₂TeOSn^tBu₂CO₃]₂·4CHCl₃, contains an almost planar centrosymmetric inorganic Sn₂Te₂O₈C₂ core and hypercoordinated Sn and Te atoms. The structure features four secondary intramolecular Te...O contacts.

Ionic conductivity in poly(diethylene glycol-carbonate)/sodium triflate complexes

New polymer electrolytes were synthesized and characterized based on a new polymer host. The motivation was to produce a host polymer with a high dielectric constant which should reduce ion clustering with an attendant increased conductivity. The new polymer host, poly(diethylene glycol carbonate) and its sodium triflate complexes were characterized by thermal analysis and AC impedance measurements. The polycarbonate backbone appears less flexible than the polyether hosts as evidenced by the higher glass transition temperatures. The conductivity for the sodium triflate complexes was measured as ~ 10⁻⁵ S cm⁻¹ at 55 °C and the dielectric constant of the host polymer was found to be 3.6 at 3 GHz. The low conductivity is attributed to rigidity of the polycarbonate.

Surface-sensitive method to determine calcium carbonate filler contents in cellulose matrices

This paper describes a method using attenuated total reflectance infra-red spectroscopy to determine the surface concentration of calcium carbonate in paper samples, by applying the linear relationship between the relative infra-red absorption integrals and the concentration. The method was able to detect micro-variations in the surface concentration and could also distinguish between different sheets as well as between the top and bottom side of one sheet. The samples were also split and the calcium carbonate concentration was determined within and compared to bulk calcium carbonate concentration determined from ash testing. The surface results were also compared with analysed scanning electron microscopy images generated from back-scattering electrons. The comparison shows that both sets of results are in excellent agreement. Depending on the sample, large errors (95% confidence) were observed. These, however, are caused by micro-variations of the surface concentration, rather than by inaccuracies of the technique, which is estimated to be less than 1%. Furthermore, measurements of various sample orientations suggest that anisotropic polarisation effects can be neglected. The method can be applied to paper and cellulose matrices having calcium carbonate filler contents of less than 50%. Due to spectral overlaps it is not suitable to determine kaolin filler contents.

Mechanism of a green graphene oxide reduction with reusable potassium carbonate

 A green method for the deoxygenation of graphene oxide (GO) was developed using K2CO3 as a reusable reduction agent. The size and thickness of the reduced GO are less than 1 μm and around 0.85 nm, respectively. Carbon dioxide is the only byproduct during this process. The reduction mechanism of the graphene oxide includes two reduction steps. On the one hand, ionic oxygen generated from the electrochemical reaction between hydroxyl ions and oxygen in the presence of K2CO3 reacts with carbonyl groups attached to the GO layers at 50°C. On the other hand, ionic oxygen attacks hydroxyl and epoxide groups, which become carbonyl groups and then are converted to carbon dioxide by K2CO3 at 90°C. These oxygenous groups are finally converted to CO2 from graphene layers, leading to the formation of graphene sheets. Headspace solid-phase microextraction and gas chromatography-mass spectrometry detected the existence of n-dodecanal and 4-ethylbenzoic acid cyclopentyl ester during the reduction, suggesting that oxygen functional groups on the GO layers are not only aligned, but randomly dispersed in some areas based on the proposed mechanism.