The voltammetric reduction, deprotonation and surface activity of ruthenium photovoltaic sensitizers in acetone

The reductive voltammetry of the photovoltaic sensitizer [(H2-dcbpy)2Ru(NCS)2] (H2-dcbpy=2,2′-bipyridine-4,4′-dicarboxylic acid) and [(H3-tctpy)Ru(NCS)3]− (H3-tctpy=2,2′:6′,2″-terpyridine-4,4′,4″-tricarboxylic acid) has been investigated in acetone. Significant surface interactions at both platinum and glassy carbon electrodes occur at 0.6 V prior to the reversible potential expected for ligand-based reduction process of the fully protonated acids. The origin of the surface interactions are attributed to the acid–base behaviour of the compounds, combined with overall deprotonation and reduction to hydrogen, since repetitive cycling of the potential reveals well-defined reversible reduction processes in the negative potential range, resulting from formation of doubly deprotonated [(H-dcbpy−)2Ru(NCS)2]2− and singly deprotonated [(H2-tctpy−)Ru(NCS)3]2−, respectively. The extent of the surface interactions has been estimated by electrochemical quartz crystal microbalance and chronocoulometric measurements. Under certain conditions, a thick conducting polymer consisting of several hundred monolayers is formed.

Studio enquiry and new frontiers of research

Given the growing complexity of human existence, there is a need for new ways of representing ideas and of illuminating the world and domains of knowledge. A growing recognition of the limits of traditional ways of representing the world has given rise to a search for alternative approaches to transform and represent the contents of consciousness or what can be known of lived experience. Researchers are recognising that scientific inquiry is just one type of research and that ‘research is not merely a species of social science’ (Eisner 1997: 261). Dissatisfaction with positivism and behaviourism as reductive modes of knowing has also come from within the science disciplines themselves. In his work entitled, The Discontinuous Universe, (1972) Werner Heisenberg states that the knowledge of science is applicable only to limited realms of experience and the scientific method is but a single method for understanding the world. Moreover, the notion of scientifically-based knowledge as statements of ultimate truth contains an inner contradiction since ‘the employment of this procedure changes and transforms its object’ (Heisenberg 1972: 189). The work of Heisenberg and others including: Lincoln and Denzin (2003), Schwandt, (2001) and Schon (1983) reveals that knowledge is relational and that different models of inquiry will yield different forms of knowledge.

The role of supervision in the training of a psychoanalyst

This paper discusses the role of clinical supervision in psychoanalytic training. It also discusses the impact of training modes on the psychoanalytic organisations that use these different models of training. The paper argues that psychoanalytic training consists of a unique combination of personal analysis, study of psychoanalytic theory and research and clinical supervision. Given the variation of these three components and their possible interactions, an overly prescriptive view of training can be detrimental and counterproductive. The effectiveness of psychoanalytic supervision is to a significant degree dependent upon a trainee being engaged in personal analysis. Clinical competency requires extensive clinical experience obtained in a variety of settings and with a broad exposure to patient groups. The detrimental implications of restrictive and reductive views on psychoanalytic training that seek to specify quantitative criteria rather than clearly articulate clinical competencies are discussed.

For goodness sake! Postlogographically de-(dis)positioning education research

How are education researchers and their research now positioned? Where are education research and researchers now positioned in the public/private debate? What is the position of practitioner research in these circumstances? My paper introduces 'post logography' as a researching trope for perturbing structuralist analytic methods towards interpreting post structuralising complexities that challenge the 'positioning' of education/research/researchers.

I discuss interpreting researching with and in (with-in) educating as intertwining ways, for turning the analytical objectivity that 'positions' subjective 'facts' as essentialised 'goods', towards exploring generative states of 'goodness'.

Education and its research are typically cast as separate constructs (like teaching and outcomes) for defining the subjectification of educational objects as valuable 'goods' - especially those with private economic value.

I argue that researched educational 'goods' are mostly teaching and outcomes focussed, and mainly privately positioned, whereas researching with-in educating for 'goodness' concerns a public disposition of exploring-learning-generativity for social knowing-acting.

I am theorising that through postlogographically de-positioning the predominance of 'facts' as private 'goods', and thereby recognising interpretive states concerning and generating 'goodness', the reductive polarisation of education/research, public/private, theorist/practitioner turns towards understanding complex continua for exploring-learning-generativity, which introduce new horizons of significance for social knowing-acting.

The global classroom

The nature of pedagogy and the collaboration between international parties in subject design ameliorates some of the more negative characteristics of globalized education. I argue that the nature of globalization is to be found in the small and ongoing practices that constitute collaboration between differing parties. In this way, what globalization means is in fact a constantly negotiated contingent and never settled. My argument is that reductive critiques of internationalization are far too simplistic. The example of EME 150 and the uptake through the Malaysian educational system of some of its components is an example not of 'imposition' or 'imperialism' but rather of a more negotiated and collaborative pedagogy that points to some of the benefits of cooperation, collaboration and by inference of globalization.

The global classroom : effective subject and pedagogy design as positive aspects of globalization

The nature of pedagogy and the collaboration between international parties in subject design ameliorates some of the more negative characteristics of globalized education. I argue that the nature of globalization is to be found in the small and ongoing practices that constitute collaboration between differing parties. In this way, what globalization means is in fact constantly negotiated contingent and never settled. My argument is that reductive critiques of internationalization are far too simplistic. The example of EME 150 and the uptake through the Malaysian educational system of some of its components is an example not of ‘imposition’ or ‘imperialism’ but rather of a more negotiated and collaborative pedagogy that points to some of the benefits of cooperation, collaboration and by inference of globalization.

Comprehension strategies of above average English as a foreign language (EFL) readers

The study reported in this thesis is a single-shot case study, which aims to provide a detailed description ofthe reading comprehension strategies used by fifteen student teachers ofEnglish from Indonesian- and Javanese-speaking backgrounds in the last year of their four-year Strata-One study at a university In Yogyakarta, Indonesia. These readers were above average among their peers in that their average indexes of grades in Reading and Speaking classes were 3.22 and 3,34 respectively, while the average indexes ofthe peer group were 271 and 2.63, respectively, out ofa scale of 0 to 400. In addition, while students in this university may complete their study by course work or by research, these readers were all enrolled as research students. As studying comprehension strategies involves complex issues, a multi-method approach is required, not only for breadth of coverage, but also to allow for a check on the validity of individual methods. To achieve the goal of the study, thinka1oud tasks, retellings, a reading comprehensIon test, indepth interviews and observations were employed to explore the strategies used. An analysis of the recorded data indicates that these readers used thirty strategies classified under five clusters: infomiation gathering, information processing, text interpretation, comprehension monitoring, and comprehension utilisation. In general, readers started gathering information by silent reading, interpreted the text by an inference or a paraphrase, and ended the task by making selfreflections relevant to the text. Most readers managed to identify problems when they occurred, and monitored their comprehension when they doubted their interpretation, as could be seen from their rereading the text or vocalising its pail(s). When direct interpretation was difficult, readers associated the text with prior knowledge or interrelated parts of the text, The readers in this study share characteristics of both poor and good native readers, in the sense that there was evidence ofgood strategy use butthe readers did not manage to maintain it consistently. As a result, even the successful readers were not able to maximise their potential. The implication is that in order to develop students into independent readers, strategy instruction should be part of and appropriately embedded in, the reading instruction. There is a need not merely to teach strategies as such, but rather to teach flexibility in strategy use. While there was sufficient evidence that thinkaloud tasks and their complementary methods worked to achieve the goals ofthe present study, similar studies with different cohorts are suggested for crosschecks.

Beyond the road : Beat writing and its socio-cultural contexts

This study looks at the contribution of Beat Generation writers to the post-World-War II reinvigoration of the American literary tradition. It challenges the reductive judgements of many critics and demonstrates that the Beat phenomenon was as much an expression of its historical moment as a rebellion against it.

N-methyl-N-alkylpyrrolidinium bis(perfluoroethylsulfonyl)amide ([NPf2]–) and tris(trifluoromethanesulfonyl)methide ([CTf3]–) salts : synthesis and characterization

Novel salts based the pyrrolidinium cation [C_nmpyr]⁺ (where n denote the number of carbons in the straight alkyl chain) and either the [NPf₂]^– or [CTf₃]^– anions have been synthesized and characterized to determine their thermal behaviour, stability, and conductivity. [C₁mpyr][NPf₂], [C₂mpyr][NPf₂], and [C₁mpyr][CTf₃] exhibit behaviour indicative of a plastic crystal phase. Both [C₃mpyr][NPf₂] and [C₄mpyr][NPf₂] are RTILs, while all of the [CTf₃]^– salts, have melting points above 60°C. [C₃mpyr][NPf₂] exhibited the widest electrochemical window of 5.5 V. The [NPf2]– salt exhibited similar reductive limits to the [NTf₂]^– anion, –3.2 V versus Fc⁺|Fc, while [CTf₃]^– had lower reductive stability. The [CTf₃]^– salts were more stable towards oxidation, +2.5 V versus Fc⁺|Fc, compared to the [NPf₂]^– and [NTf₂]^– salts.

Cycling performance of lithium metal polymer cells assembled with ionic liquid and poly(3-methyl thiophene)/carbon nanotube composite cathode

A poly(3-methylthiophene) (PMT)/multi-walled carbon nanotube (CNT) composite is synthesized by in situ chemical polymerization. The PMT/CNT composite is used as an active cathode material in lithium metal polymer cells assembled with ionic liquid (IL) electrolytes. The IL electrolyte consists of 1-ethyl-3-methylimidazolium tetrafluoroborate (EMIBF4) and LiBF4. A small amount of vinylene carbonate is added to the IL electrolyte to prevent the reductive decomposition of the imidazolium cation in EMIBF4. A porous poly(vinylidene fluoride-co-hexafluoropropylene) (P(VdF-co-HFP)) film is used as a polymer membrane for assembling the cells. Electrochemical properties of the PMT/CNT composite electrode in the IL electrolyte are evaluated and the effect of vinylene carbonate on the cycling performance of the lithium metal polymer cells is investigated. The cells assembled with a non-flammable IL electrolyte and a PMT/CNT composite cathode are promising candidates for high-voltage–power sources with enhanced safety.

Iraq's December 2005 election : reporting democratisation in the Australian and Middle Eastern print media

Throughout the coverage of Iraq since the Iran-Iraq War of the 1980s and especially since September 11, the Western mainstream Media have eschewed key historical and contextual data about Iraq, thereby serving to reduce and homogenize the complexity of the issues surrounding the region and the conflicts therein. In so doing, the media has tended towards Orientalism (Said, 1978) by trivialising Iraq and its people and thereby reinforcing the hegemony of the West over the ‘backward, barbaric’ East. Building on earlier research (Isakhan, 2005a), this paper further examines the reductive and homogenising reporting of Iraq in the Western media by using both quantitative and qualitative assessment methods to compare and contrast the discursive practices used to construct the Iraqi election of December 15, 2005 in Australia’s leading daily newspapers with newspapers from the Middle East. In essence, it finds that while the Australian media propagates Orientalism through its one-eyed coverage, the Middle Eastern papers are more contemplative, focusing on the impact that this election could have throughout the region.

Characterisation of gold electrodes modified with self-assembled monolayers of l-cysteine for the adsorptive stripping analysis of copper

Electrochemical sensors for copper ions in environmental samples were prepared by modifying gold electrodes with l-cysteine by self-assembly. The adsorption of l-cysteine on gold electrodes was studied by electrochemical reductive desorption in 0.5 M KOH, and the interaction of l-cysteine with copper ions was investigated by cyclic voltammetry, chronoamperometry and X-ray photoelectron spectroscopy. At low concentrations the ratio of l-cysteine to bound Cu(II) is 2:1. At higher concentrations (0.1 M) copper reacts with adsorbed cysteine forming copper sulfide on the electrode surface. On a modified l-cysteine gold electrode, Osteryoung square wave voltammetric determination of Cu(II) with a detection limit below 5 ppb has been demonstrated.

Student attitudes toward professional practices in science

There has been anecdotal evidence that students from various cultures have different perspectives toward professional practices, including (1) how to use quotations, (2) occupational health and safety and (3) recording data, but there has been a lack of hard evidence to either confirm or contradict this belief. This paper presents a snapshot of student attitudes toward professional practices in Australia. The survey group consisted of students enrolled in an undergraduate 1st year, 2nd semester, chemistry subject. Students generally agreed that they should paraphrase and should cite sources of information. However, there was confusion about the use of extensive quotations and occupational health and safety. There was no significant difference in the responses by the country of secondary schooling or family background, but were some significant differences by the respondents’ age, number of years in university and by the discipline area of study.

Electrochemistry at negative potentials in Bis(trifluoromethanesulfonyl)amide ionic liquids

The bis(trifluoromethanesulfonyl)amide (TFSA) anion is widely studied as an ionic liquid (IL) forming anion which imparts many useful properties, notably electrochemical stability. Here we present electrochemical and spectroscopic evidence indicating that reductive decomposition of the bis(trifluoromethanesulfonyl)amide (TFSA) anion begins at ~ −2.0 V vs. Fc+/Fc, well before the reported cathodic limit for many of these ILs. These processes are shown to be dependent upon the electrode substrate and are influenced by the water content of the IL. Supporting ab initio calculations are presented which suggest a possible mechanism for the anion decomposition. The products appear to passivate the electrode surface and the implications of this behaviour are discussed.

An impaired mitochondrial electron transport chain increases retention of the hypoxia imaging agent diacetylbis(4-methylthiosemicarbazonato)copper II

Radiolabeled diacetylbis(4-methylthiosemicarbazonato)copper^II [Cu^II(atsm)] is an effective positron-emission tomography imaging agent for myocardial ischemia, hypoxic tumors, and brain disorders with regionalized oxidative stress, such as mitochondrial myopathy, encephalopathy, and lactic acidosis with stroke-like episodes (MELAS) and Parkinson’s disease. An excessively elevated reductive state is common to these conditions and has been proposed as an important mechanism affecting cellular retention of Cu from Cu^II(atsm). However, data from whole-cell models to demonstrate this mechanism have not yet been provided. The present study used a unique cell culture model, mitochondrial xenocybrids, to provide whole-cell mechanistic data on cellular retention of Cu from Cu^II(atsm). Genetic incompatibility between nuclear and mitochondrial encoded subunits of the mitochondrial electron transport chain (ETC) in xenocybrid cells compromises normal function of the ETC. As a consequence of this impairment to the ETC we show xenocybrid cells upregulate glycolytic ATP production and accumulate NADH. Compared to control cells the xenocybrid cells retained more Cu after being treated with Cu^II(atsm). By transfecting the cells with a metal-responsive element reporter construct the increase in Cu retention was shown to involve a Cu^II(atsm)-induced increase in intracellular bioavailable Cu specifically within the xenocybrid cells. Parallel experiments using cells grown under hypoxic conditions confirmed that a compromised ETC and elevated NADH levels contribute to increased cellular retention of Cu from CuII(atsm). Using these cell culture models our data demonstrate that compromised ETC function, due to the absence of O2 as the terminal electron acceptor or dysfunction of individual components of the ETC, is an important determinant in driving the intracellular dissociation of Cu^II(atsm) that increases cellular retention of the Cu.