Electrochemical performance of polyaniline nanofibres and polyaniline/multi-walled carbon nanotube composite as an electrode material for aqueous redox supercapacitors

Polyaniline (PANI) nanofibres are synthesized by interfacial polymerization and their electrochemical performance is evaluated in an aqueous redox supercapacitor constituted as a two-electrode cell. The initial specific capacitance of the cell is 554 F g−1 at a constant current of 1.0 A g−1, but this value rapidly decreases on continuous cycling. In order to improve the cycleability of the supercapacitor, a composite of polyaniline with multi-walled carbon nanotubes (CNTs) is synthesized by in situ chemical polymerization. Its capacitive behaviour is evaluated in a similar cell configuration. A high initial specific capacitance of 606 F g−1 is obtained with good retention on cycling. In both supercapacitors, the effect of charging potential on cycling performances is investigated.

Ionic liquid-assisted synthesis of polyaniline/gold nanocomposite and its biocatalytic application

In this report, a novel chemical synthesis of polyaniline/gold nanocomposite is explored using ionic liquid (IL) 1-Butyl-3-methylimidazolium hexafluorophosphate. The direct chemical synthesis of polyaniline/gold nanocomposite was initiated via the spontaneous oxidation of aniline by AuCl4 − in IL. A nearly uniform dispersion of polyaniline/Au particles with a diameter of 450 ± 80 nm was produced by this method, which indicates that this method is more suitable for controlling particle dimensions. It was also found that the electrical conductivity of the polyaniline/gold nanocomposite was more than 100 times higher than that of the pure polyaniline nanoparticles. The polyaniline/gold nanocomposite displays superior function in the biocatalytic activation of microperoxidase-11 because of the high surface area of the assembly and the enhanced charge transport properties of the composite material. We also report the possible application of polyaniline/gold nanocomposite as a H2O2 biosensor.

One-dimensional polyelectrolyte/polymeric semiconductor core/shell structure : sulfonated poly(arylene ether ketone)/polyaniline nanofibers for organic field-effect transistors

A polyelectrolyte/polymeric semiconductor core/shell structure is developed for organic field-effect transistors (OFETs) based on sulfonated poly(arylene ether ketone)/polyaniline core/shell nanofibers via electrospinning and solution-phase selective polymerization. The polyelectrolyte does not work as a gate dielectric, but can provide an internal modulation from the nanointerface of the 1D core/shell nanostructure. The transistor devices display very high mobilities.

Au-doped polyacrylonitrile-polyaniline core-shell electrospun nanofibers having high field-effect mobilities

Au-doped polyacrylonitrile–polyaniline core–shell nanofibers are fabricated via electrospinning and subsequent gas-phase polymerization, providing a very high field-effect mobility of up to 11.6 cm² V⁻¹ s⁻¹. This method is also suitable for other conducting polymers and may eventually lead to a new and simplified fabrication of high-performance polymer organic field-effect transistors.