Narrowed bandgaps and stronger excitonic effects from small boron nitride nanotubes

The bandgap of boron nitride nanotubes (BNNTs) is generally considered to be independent on tube radius and chirality. However, we have observed that the bandgaps of BNNTs do depend on the tube size. Photoluminescence excitation spectroscopy with variable photon energies in vacuum ultraviolet (VUV) range revealed that the bandgap becomes smaller when the tube diameter decreases. This is consistent with red-shifted luminescent emissions. The strong interactions between excitons and phonons are possibly responsible for the bandgap narrowing as the function of nanotube size. 2009 Elsevier B.V. All rights reserved.

Estimating relative disulfide energies : an accurate ab initio potential energy surface

Disulfide torsional energy, a good predictor of disulfide redox potential in proteins, may be estimated by interpolation on a potential energy surface (PES) describing the twisting of diethyl disulfide through its three central dihedral angles. Here we update PES calculations at the M05-2X level of theory with the 6-31G(d) basis set. Although the surface shows no qualitative differences from an earlier MP2(full) PES, energy differences greater than 1 kJ mol^–1 were seen for conformations with χ₂ between –60° and 30°, or with χ₃ below 60° or above 130°. This is particularly significant for highly strained disulfides that are likely to be spontaneously reduced by mechanical means. In benchmarking against the high-level G3X method, M05-2X showed significantly reduced root mean squared deviation compared with MP2(full) (1.0 versus 2.0 kJ mol^–1 respectively). Results are incorporated into a web application that calculates relative torsional energies from disulfide dihedral angles (http://www.sbinf.org/applications/pes.html).

Modeling and simulation of a periodic grating coupled configuration for surface plasmon excitation

The deficiencies in the design of surface plasmon resonance (SPR) systems that are reported in numerous published works consistently identify the optics assembly as the main problem in the miniaturization of SPR sensors for integration into biosensor systems. This paper presents a novel design of a grating coupled optical waveguide surface plasmon (SP) excitation mechanism, investigated with the intention of addressing the problems associated with using the traditional prism input-output light coupling approach. Computational multiphysics modeling and simulation of the design is carried out. The results are presented and discussed.

Photochemical formation of silver nanodecahedra : structural selection by the excitation wavelength

Silver decahedra have been successfully synthesized with high yield via a photochemical reaction using blue light-emitting diodes (LEDs) as the exciting light source. The decahedra display distinct properties with respect to the ability of light scattering. The photochemical growth process of silver decahedra was monitored by both extinction and scattering spectral evolution. A suggested formation mechanism of silver decahedron is discussed.

Selective excitation of concomitant electrochemiluminophores : tuning emission color by electrode potential

ECL in 3D: Selective electrogenerated chemiluminescence (ECL) of several ruthenium and iridium complexes simultaneously in solution can be controlled by electrode potential (see picture; λem=emission wavelength). These luminescent redox systems create a range of new possibilities for multi-analyte ECL detection, assessment of interdependent electrochemical/spectroscopic properties, and color tuning in light-emitting devices.

A potential-controlled switch on/off mechanism for selective excitation in mixed electrochemiluminescent systems

We demonstrate the complete, rapid, and reversible switching between the emissions from two electrogenerated chemiluminescence (ECL) systems contained within the same solution, controlled by simple modification of the applied potential. The fundamental bases of the approach are the ability to selectively 'switch on' luminophores at distinct oxidation potentials, and an intriguing observation that the emission from the well-known electrochemiluminescent complex, fac-Ir(ppy)3, (where ppy is 2-phenylpyridinato), can be selectively 'switched-off' at high overpotentials. The dependence of this phenomenon on high concentrations of the co-reactant implicates quenching of the excited [Ir(ppy)3]* state by electron transfer. Rapid spectral scanning during modulation of the applied potential reveals well resolved maxima for mixtures comprising either green and red or green and blue luminophores, illustrating the vast potential of this approach for multiplexed ECL detection.

Enhancement of transient stability limit and voltage regulation with dynamic loads using robust excitation control

In stressed power systems with large induction machine component, there exist undamped electromechanical modes and unstable montonic voltage modes. This article proposes a sequential design of an excitation controller and a power system stabiliser (PSS) to stabilise the system. The operating region, with induction machines in stressed power systems, is often not captured using a linearisation around an operating point, and to alleviate this situation a robust controller is designed which guaruntees stable operation in a large region of operation. A minimax linear quadratic Gaussian design is used for the design of the supplementary control to automatic voltage regulators, and a classical PSS structure is used to damp electromechanical oscillations. The novelty of this work is in proposing a method to capture the unmodelled nonlinear dynamics as uncertainty in the design of the robust controller. Tight bounds on the uncertainty are obtained using this method which enables high-performance controllers. An IEEE benchmark test system has been used to demonstrate the performance of the designed controller

Affective energies : Sensory bodies on the beach in Darwin, Australia

Emerging debates on anti-racism within white majority cultures centre emotion and affect to explore the visceral nature of racialised encounters that unfold in public spaces of the city. This paper builds on such understandings by conceptualising whiteness as a force that exerts affective pressures on bodies of colour who are hypervisible in public spaces. I show that these pressures have the potential to wound, numb and immobilise bodies affecting what they can do or what they can become. This paper argues, however, that affective energies from human and non-human sources are productive forces that are also sensed in public spaces such as the suburban beach. These energies entangle sensuous bodies with the richness of a more-than-human world and have the potential to offer new insights into exploring how racially differentiated bodies live with difference. The paper draws on ethnographic research conducted in Darwin, a tropical north Australian city at the centre of politicised public debates on asylum seeker policy, migrant integration and Indigenous wellbeing. My attention to affective pressures and affective energies contributes to understanding how bodies with complex histories and geographies of racialisation can inhabit a world of becoming. © 2014 Elsevier Ltd. All rights reserved.

Control of excitation and quenching in multi-colour electrogenerated chemiluminescence systems through choice of co-reactant

We demonstrate a new approach to manipulate the selective emission in mixed electrogenerated chemiluminescence (ECL) systems, where subtle changes in co-reactant properties are exploited to control the relative electron-transfer processes of excitation and quenching. Two closely related tertiary-amine co-reactants, tri-n-propylamine and N,N-diisopropylethylamine, generate remarkably different emission profiles: one provides distinct green and red ECL from [Ir(ppy)3] (ppy=2-phenylpyridinato-C2,N) and a [Ru(bpy)3](2+) (bpy=2,2'-bipyridine) derivative at different applied potentials, whereas the other generates both emissions simultaneously across a wide potential range. These phenomena can be rationalized through the relative exergonicities of electron-transfer quenching of the excited states, in conjunction with the change in concentration of the quenchers over the applied potential range.

A nonlinear adaptive backstepping approach for coordinated excitation and steam-valving control of synchronous generators

Steam-valving and excitation systems play an important role to maintain the transient stability of power systems with synchronous generators when power systems are subjected to large disturbances and sudden load changes. This paper presents a nonlinear adaptive backstepping approach for controlling excitation and steam-valving systems of synchronous generators. In this paper, the proposed excitation and steam-valving controllers are designed in a coordinated manner so that they can work under several and most severe operating conditions. Both excitation and steam-valving controllers are designed by considering some critical parameters as unknown. The effectiveness of the proposed coordinated control scheme is evaluated on a single machine infinite bus system under different operating conditions such as load changes and three-phase short circuit faults at the generator terminal. Finally, performance of the proposed scheme is compared to that of a similar nonlinear adaptive backstepping excitation controller without any coordination and simulation results demonstrate the superiority of the proposed one.

Robust adaptive backstepping excitation controller design for simple power system models with external disturbances

This paper presents a nonlinear robust adaptive excitation controller design for a simple power system model where a synchronous generator is connected to an infinite bus. The proposed controller is designed to obtain the adaption laws for estimating critical parameters of synchronous generators which are considered as unknown while providing the robustness against the bounded external disturbances. The convergence of different physical quantities of a single machine infinite bus (SMIB) system, with the proposed control scheme, is ensured through the negative definiteness of the derivative of Lyapunov functions. The effects of external disturbances are considered during formulation of Lyapunov function and thus, the proposed excitation controller can ensure the stability of the SMIB system under the variation of critical parameters as well as external disturbances including noises. Finally, the performance of the proposed scheme is investigated with the inclusion of external disturbances in the SMIB system and its superiority is demonstrated through the comparison with an existing robust adaptive excitation controller. Simulation results show that the proposed scheme provides faster responses of physical quantities than the existing controller.

Nonlinear excitation control of synchronous generators based on adaptive backstepping method

n this paper, the design of a nonlinear excitation control of a synchronous generator is presented where the generator is connected to a single machine infinite bus (SMIB) system. An adaptive backstepping method is used to design the excitation controller with an objective of enhancing the overall dynamic stability of the SMIB system under different contingencies. In this paper, two types of contingencies are considered- i) unknown parameters and physical quantities during the controller design process and ii) controller performance evaluation under different system configurations such as three-phase short circuit faults. The adaption law, which is mainly based on the formulation of Lyapunov function, is used to estimate the unknown parameters which guarantee the convergence of different physical quantities of synchronous generators, e.g., the relative speed, terminal voltage, etc. The effectiveness of the proposed scheme is evaluated under different system configurations as mentioned in the second contingency and compared to that of an existing adaptive backstepping controller and a conventional power system stabilizer (PSS). Simulation results demonstrate the superiority of the proposed control scheme over the existing controllers.