Characterization of conductive polyprrole coated wool yarns

Wool yarns were coated with conducting polypyrrole by chemical synthesis methods. Polymerization of pyrrole was carried out in the presence of wool yarn at various concentrations of the monomer and dopant anion. The changes in tensile, moisture absorption, and electrical properties of the yarn upon coating with conductive polypyrrole are presented. Coating the wool yarns with conductive polypyrrole resulted in higher tenacity, higher breaking strain, and lower initial modulus. The changes in tensile properties are attributed to the changes in surface morphology due to the coating and reinforcing effect of conductive polypyrrole. The thickness of the coating increased with the concentration of p-toluene sulfonic acid, which in turn caused a reduction in the moisture regain of the wool yarn. Reducing the synthesis temperature and replacing p-toluenesulfonic acid by anthraquinone sulfonic acid resulted in a large reduction in the resistance of the yarn.

Reducing yarn hairiness with a modified yarn path in worsted ring spinning

The spinning geometry of a ring frame plays an important role, and the twist triangle is the critical region in ring spinning. Changes in the spinning geometry may affect yarn properties. This paper examines the idea of ring spinning with a "diagonal" yarn path, and the effect of such a path on yam properties, particularly hairiness. Both "left diagonal" and "right diagonal" yam arrangements are tried on a 24-spindle Cognetex FLC worsted ring frame. The hairiness results obtained from the Zweigle hairiness meter show that the right diagonal yam path produces yams of lower hairiness than the conventional ring spun yarn in almost all the hair length groups. Yam evenness and tenacity are not as sensitive to the change in yarn path. The mean spindle speed at break is also tested, and there is some deterioration in spinning efficiency with the right diagonal yarn path, particularly at higher spinning speeds. Results from this study may help explain variations in yarns spun on poorly aligned ring frames.

Mill specific prediction of worsted yarn performance

Different spinning mills use different raw materials, processing methodologies, and equipment, all of which influence the quality of the yarns produced. Because of many variables, there is a difficulty in developing a universal empirical/theoretical model. This work presents a multilayer perceptron algorithm (MLP) model for the purpose of building a mill specific worsted spinning performance prediction tool. Sixteen inputs are used to predict key yarn properties and spinning performance, including number of fibers in cross-section, unevenness (U%), thin places, neps, yarn tenacity, elongation at break, thick places, and spinning ends-down. Validation of the model on mill specific commercial data set shows that the general fit to the target values is good. Importantly, the performance of the MLP shows a certain degree of stability to different, random selections of independent test data. Subsequent comparison against the predicted outputs of Sirolan Yarnspec™ confirms the overall performance of the artificial neural network (ANN) method to be more accuratefor mill specific predictions.

The new solo-siro spun process for worsted yarns

The aim of this paper was to explore whether the properties of worsted yarns, especially hairiness, can be improved by combining the Solospun and Sirospun processes into a single Solo-Siro spun process. Wool fibres of 19 and 21 μm in average diameter were spun into 40 tex yarns at different twist levels, using the conventional ring, Sirospun and Solo-Siro spun systems, respectively. These yarns were then tested for a range of properties, including hairiness, tenacity, elongation and evenness, for comparison purposes. The statistical analysis results indicate that the hairiness (S3 value) of Solo-Siro spun yarns was significantly less than that of both Sirospun and normal ring spun yarns. In addition, the tenacity of the Solo-Siro spun yarns was higher than that of the normal ring spun yarns, while changes in yarn breaking elongation were not statistically significant. For the 21 μm wool, it was found that the evenness of Solo-Siro spun yarns deteriorated slightly in comparison with that of Sirospun and conventional ring spun yarns.

High technology nanocomposite fibres: Development of melt spun semi-aromatic polyamide nanocomposite fibres

Novel polyamide nanocomposite fibres have been produced by compounding semi aromatic Poly (m-xylene adipamide) (MXD6) and organophilic Montmorillonite (MMT). Partially orientated fibres (POF) of MXD6 nanocomposite were obtained by melt spinning on a multifilament fibre extrusion system at three different speeds. The effect of the drawing velocity
on the mechanical properties of the filaments has been determined. Tensile measurements indicated that the introduction of the nanoparticies by melt intercalation improves the tenacity and toughness of the resulting polyamide fibres. The microstructure of the nanocomposites was examined by X-ray diffraction and Transmission Electron Microscope (TEM) and shown to
be an exfoliated disordered structure. The thermal stability of MXD6 nanocomposites was analysed by thermo gravimetric analysis (TGA) suggesting stabilisation of the clay and the polymer systems above 450°C.

In-situ tensile properties of a ballooning staple yarn

This study investigated the tensile properties of a rotating or ballooning staple yarn. The results indicated that the effect of rotating speed on the tensile properties of a ballooning staple yarn was significant. As the yarn rotating speed increased, the tenacity of the rotating or ballooning yarn decreased, while the yarn breaking elongation increased. The effect of rotating speed on the tenacity of a ballooning staple yarn varied for different yarns. These results demonstrated that the breaking force of a ballooning yarn was much lower than the yarn breaking force obtained from normal tensile tests. These results provide new insight into the problems of yarn breakage in yarn spinning and twisting processes.

Fabrication of ultrafine powder from eri silk through attritor and jet milling

Fibroin protein derived from silk fibres has been extensively studied with exciting outcomes for a number of potential advanced biomaterial applications. However, one of the major challenges in applications lies in engineering fibroin into a  desired form using a convenient production technology. In this paper, fabrication of ultrafine powder from eri silk is reported. The silk cocoons were degummed and the extracted silk fibres were then chopped into snippets prior to attritor and air jet milling. Effects of process control agents, material load and material to water ratio during attritor milling were studied. Compared to dry and dry–wet attritor milling, wet process emerged as the preferred option as it caused less colour change and facilitated easy handling. Ultrafine silk powder with a volume based particle size d(0.5) of around 700 nm could be prepared following the sequence of chopping ➔ wet attritor milling ➔ spray drying ➔ air jet milling. Unlike most reported powder production methods, this method could fabricate silk particles in a short time without any pre-treatment on degummed fibre. Moreover, the size range obtained is much smaller than that previously produced using standard milling devices. Reduction in fibre tenacity either shortened the milling time even further or helped bypassing media milling to produce fine powder directly through jet milling. However, such reduction in fibre strength did not help in increasing the ultimate particle fineness. The study also revealed that particle density and particle morphology could be manipulated through appropriate changes in the degumming process.

Graphical Abstract:  Fabrication of eri silk powder using attritor and jet milling is reported. Volume based particle size d(0.5) of around 700 nm could be prepared following the sequence chopping ➔ wet attritor milling ➔ spray drying ➔ air jet milling. No pre-treatments were used and the particle size range obtained is much smaller than that previously produced using standard milling devices. Particle density morphology could be manipulated through appropriate changes of cocoon degumming conditions.

Investigation of yarn hairiness

Yarn hairiness affects not only the quality of products, but also the productivity in spinning and weaving. Too much yarn hairiness is undesirable for many end uses as well as the spinning and post spinning processes. The main aims of this project are to examine the hairiness features of various yarns and to reduce yarn hairiness. The thesis covers five related areas – hairiness assessment, factors affecting yarn hairiness, the hairiness of newly developed yarns, yarn hairiness reduction, and effect of yarn hairiness on the energy consumption in ring spinning. The worsted cashmere, pure wool and wool/cashmere blend yarns were employed to investigate the effect of some fibre parameters on the yarn hairiness. A single exponential distribution of the hair-length was confirmed first, using the data from the Zweigle G565 Hairiness Meter. A linear relationship was observed between the blend ratio and the hairiness indexes. In particular, the effect of fibre crimp or curvature on yarn hairiness is examined. The theory of yarn hairiness composition was also developed further. The effect of draft ratio and spindle speed on the hairiness of worsted wool yarn was examined next with a factorial experiment design. Several new hairiness indexes, namely the relative hairiness indexes, have been used to explain the results obtained. In the investigation of the hairiness of newly developed yarns, the hairiness of the Compact Spun and Roller-Jet-Spun yarns was examined first. The composition of the yarn hairiness, the hair-length distribution, and the effect of test speed on yarn hairiness were then studied. An important finding is that for both yarns, the predominant hairiness feature is the looped hairs. A comparison of the hairiness of Solospun yarns and the equivalent ring spun wool yarns was undertaken. The hair-length distribution of the Solospun yarn was examined first. The Solospun yarns used had fewer hairs in most hair-length groups and lower variations in hairiness. In addition, the effect of twist level and spindle speed on the hairiness of Solospun and conventional ring spun yarns has also been discussed. A novel approach of reducing yarn hairiness – spinning with a ‘Diagonal’ yarn path was examined next. Both ‘Left Diagonal’ and ‘Right Diagonal’ yarn arrangements were studied. A new finding is that the ‘Right Diagonal’ yarn path leads to reduced hairiness for the Z-twist yarn, while yarn evenness and tenacity are not as sensitive to the modified yarn path. The mechanism of hairiness reduction with the ‘Diagonal’ yarn path has been discussed. The spinning performance of “Right Diagonal” yarn arrangement has also been evaluated. Finally, the effect of yarn hairiness on the energy consumption in ring spinning has been investigated theoretically and experimentally. A theoretical model has been developed, which represents the first attempt at theoretically investigating the influence of yarn hairiness on energy consumption during the winding stage of ring spinning. The experimental results have generally confirmed predictions of this model. Recommendations for further research in this area have also been made in the concluding chapter of this thesis.

Processing and quality of cashmere tops for ultra-fine wool worsted blend fabrics

This study has focussed on three main areas. First, an evaluation of the physical attributes of cashmere tops available to commercial spinners; second, the influence of processing variables on the efficiency of producing cashmere tops from raw Australian cashmere; and third, the influence of design of cashmere ultrafine wool blends on the fibre curvature of tops. Testing the physical attributes of cashmere tops from traditional and new sources of supply, was followed by statistical analyses based on factors of origin, processor and other determinants. The analyses demonstrated important processor effects and also that cashmere from different origins shows commercially important variations in fibre attributes. It was possible to efficiently produce Australian cashmere tops with Hauteur, tenacity, extension, softness and residual guard hairs quality attributes equivalent to those observed in the best cashmere tops. The blending of cashmere with wool resulted in a reduction of the mean fibre curvature of the blend compared with the unblended wool. The present work demonstrated that the fibre curvature properties of blended low crimp ultrafine wool tops were closer to the properties of pure cashmere tops than were tops made from blended standard high crimp ultrafine wool. The attributes of textiles made from the relatively rare Australian low curvature cashmere could enhance the marketability of both Australian cashmere and low curvature wool.

Twist distribution in staple fibre yarns

Staple fibre yarns vary quite markedly in linear density (tex) along their length and the degree to which twist redistributes from thick to thin places will affect the strength, torque and extension behaviour of the yarn. Theory suggests that twist along worsted yarns should vary as 1/(tex)2 if fibres were locked in the structure, whereas themean torque of worsted yarns reported in the literature implies that twist should be proportional to 1/tex. This article examines twist distribution in ring-spun marl yarns, down to 5 mm resolution, as a function of linear density measured using a high-resolution capacitive sensor. It is found for moderate twist-level worsted yarns that twist is approximately proportional to 1/(tex)1.6. The results and theory provide a guide as to the effect the observed large variations in linear density will have on yarn properties such as tenacity and torque.

Effects of ultrasonic treatment on wool fibre and fabric properties

The protein structures of wool, treated in fabric form with ultrasonics for different time durations, were analysed by X-ray diffraction (XRD) and Fourier transform infrared (FTIR), in comparison with the wool without ultrasonic treatment. Fabric water absorption and tensile properties were measured in addition to the fibre micro-structure analysis. It is shown that while the ultrasonic treatment had little effect on the fibre crystallinity, some chemical structures in the protein were altered to some extent during the process. Disruption of fibre internal waxy lipids upon ultrasonic treatment provided the fibres with increased water absorption. Protein chains in the macro fibrils were shown to be rearranged to a more regular and less flexible structure, as a result of the ultrasonic treatment. Fabric tensile tests showed an increased tenacity and a reduced extensibility to the ultrasonically treated fabric. Prolonged ultrasonic treatment, however, significantly reduced both fabric tenacity and extensibility.

Production, properties and processing of American bison (Bison bison) wool grown in southern Australia

American bison grow a thick coat of fibres which assists them to withstand severe climatic conditions. Bison fibre was traditionally used in textiles by native North Americans. This study aimed to quantify the production, fibre attributes and dehairing processing of bison fibre produced from bison grazed in north-eastern Victoria. Three age/sex classes were sampled (n = 16) at seven body positions in spring. The fibre growing area was measured. Fibre was tested for diameter distribution, clean washing yield, proportion of fine fibres <36µm and fine fibre length, and processed by cashmere dehairing. Bison were 12 years of age, liveweights 160450 kg and had mean fibre growing area of 1.4 m². They produced an average 1184 g (range 5301640 g) of fine fibre with mean fibre diameter 18.5µm, clean washing yield 76.5%, wax content 9.8%, suint content 14.5%, clean fine fibre yield 56.4%, fine fibre length 37 mm and fibre curvature was 93/mm. Mid-side fibre had a crimp frequency of 6.5/cm and mean resistance to compression of 6.6 kPa. Fibre had a tenacity of 8.7 cN/tex and an extension of 39.3%. Restricted maximum likelihood mixed model analysis showed age/sex class and sampling site significantly affected all fibre attributes. Finer and longer fibre was produced in anterior sites and in younger bison. Fibre curvature declined 5.3°/mm for each 1-µm increase in mean fibre diameter. Dehaired fibre had a mean fibre diameter of 17.8 µm and mid-length of 28 mm, suitable for woollen spinning. The production by bison of coats containing significant amounts of fibre indicates that careful harvesting of fibre could form an important source of income in bison enterprises.

Changes in wool protein structure and fabric properties with ultrasonic treatment

Wool fabrics, ultrasonically treated for different time durations, were analysed by Fourier transform infrared (FTIR), differential scanning calorimeter (DSC), and thermo-gravimetric analysis (TGA), in comparison with the wool without ultrasonic treatment. Fabric tensile and thermal properties were measured in addition to the fibre micro structure analysis. Wool protein chains in the macro fibrils were shown to be rearranged to a more regular and less flexible structure, as a result of the ultrasonically treated fabric. Prolonged ultrasonic treatment, however, significantly reduced both fabric tenacity and extensibility. Wool treated with ultrasonics was found to have less mass loss and a higher thermal degradation temperature than that of without ultrasonic treatment and prolonged treated. DSC analysis showed that while ultrasonic treatment has little effect on the fibre crystallinity, an appropriate treatment can provide wool with increased water absorption.

Relationships between skin follicle characteristics and fibre properties of Suri and Huacaya alpacas and Peppin Merino sheep

We aimed to quantify the number, type and arrangement of skin follicles in Huacaya and Suri alpaca skin and correlate their follicle characteristics with fibre traits of harvested fibre and compared these relationships with those of Merino sheep. Fibre and skin samples were collected from the mid-side of 12 Huacaya alpacas, 24 Suri alpacas and 10 Merino sheep. The mean fibre diameter (MFD ± s.e.) of the Huacaya and Suri were: 35.5 ± 0.9 and 28.3 ± 1.0 μm, respectively. The follicle groups found for alpacas were very different from the normal trio of primary follicles found in sheep and goats. The follicle group of the alpacas consisted of a single primary follicle surrounded by a variable number of secondary follicles. The mean ± s.e. primary follicle density was 3.1 ± 0.3 and 2.7 ± 0.1 follicles/mm² for Huacaya and Suri, respectively. The mean ± s.e. secondary follicle density (SFD) was 13.7 ± 1.2 and 17.5 ± 0.6 follicles/mm² for Huacaya and Suri, respectively. The mean ± s.e. ratio of secondary to primary follicles (S/P ratio) was 5.1 ± 0.5 for the Huacaya and 7.3 ± 0.2 for the Suri alpacas. The sheep had higher S/P ratios and SFD, lower MFD and produced significantly heavier fleeces. The key correlations found between traits in alpacas include a negative correlation between SFD and MFD (r = –0.71, P = 0.001) and a negative correlation between S/P ratio and MFD (r = –0.44, P = 0.003) and a positive correlation between S/P ratio and total follicle density (r = 0.38, P = 0.010). The study revealed that important relationships exist between alpaca skin follicle characteristics and fibre characteristics. It was the number of secondary follicles in a group that imparts density and a corresponding reduced MFD.

Performance comparison of abrasion resistant textile motorcycle clothing

 Falling at speed onto a tarmac surface during cycling can cause abrasion and laceration of the skin and body tissue. Motorcycle clothing designed to reduce or avoid this type of injury has traditionally been made of animal leather as it has well known resistance to abrasion. In the last 20 years there has been an emergence of textile clothing reinforced with high performance/tenacity fibres such as those made from polyamides, aramids, ultra high molecular weight polyethylene and liquid crystal. Almost no comparative work has been undertaken to provide insight into the level of protection these clothing layers can provide.
This work has used a CE standard test method to evaluate a number of abrasion resistant textile pant products and compare them with a leather race product. It analysed the protective fabric layer structure for mass, thickness, construction method and resistance to abrasion.
Structures manufactured from high tenacity fibres performed better than those from lower tenacity ones. Fabric construction method and mass per unit area were the two key variables in providing an abrasion protective layer. Structures manufactured from knitted para-aramid fibres performed better than their woven counterparts due to the method of fabric failure. Several well designed protective layers performed at a similar level to that of leather; however, most garments tested failed to meet the lower level European standard of abrasion resistance (CE level 1), which may put their wearer at risk in the advent of a collision.