GENESIS: an efficient, transparent and easy to use cluster operating system

Present operating systems are not built to support parallel computing––they do not provide services to manage parallelism, i.e., to globally manage parallel processes and computational resources. The cluster operating environments that are used to assist the execution of parallel applications do not provide support for both programming paradigms, message passing (MP) or distributed shared memory (DSM)––they are mainly offered as separate components implemented at the user level as library and independent server processes. Due to poor operating systems users must deal with clusters as a set of independent computers rather than to see this cluster as a single powerful computer. A single system image (SSI) of the cluster is not offered to users. There is a need for an operating system for clusters. We claim and demonstrate in this paper that it is possible to develop a cluster operating system that is able to efficiently manage parallelism; use cluster resources efficiently; support MP in the form of standard MP and PVM, and DSM; offer SSI; and make it easy to use. We show that to achieve these aims this operating system should inherit many features of a distributed operating system and provide new services which address the needs of parallel processes, cluster's resources, and application developers. In order to substantiate the claim the first version of a cluster operating system managing parallelism and offering SSI, called GENESIS, has been developed.

Interoperable and transparent dynamic deployment of web services for service oriented grids

Dynamic deployment of Web services is a term used frequently when describing the selection and deployment of a service to a grid host. Although current grid systems (such as Globus) provide dynamic deployment, the requirements of the service being deployed are not considered. Therefore truly dynamic deployment cannot be achieved as the services deployed are restricted to the grid system used. We present a dynamic deployment mechanism as part of self configuration in a service oriented grid environment. The dynamic deployment mechanism takes the requirements of the service into consideration, including parameters such as the operating system required to execute the service, the required software libraries, any additional required software packages, price and Quality of Service (QoS) parameters.

Transparent and autonomic rollback-recovery in cluster systems

Cluster systems provide an excellent environment to run computation hungry applications. However, due to being created using commodity components they are prone to failures. To overcome these failures we propose to use rollback-recovery, which consists of the checkpointing and recovery facilities. Checkpointing facilities have been the focus of many previous studies; however, the recovery facilities have been overlooked. This paper focuses on the requirements, concept and architecture of recovery facilities. The synthesized fault tolerant system was implemented in the GENESIS system and evaluated. The results show that the synthesized system is efficient and scalable.

Studies with voltammetric microdisk electrodes

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A substantially visibly transparent topical physical sunscreen formulation

A topically applied sunscreen composition is provided, which by use of nano-sized particles of a physical UV screening agent in a dermatologically acceptable carrier, provides a dermatologically acceptable level of SPF and broad-spectrum protection from UVA and UVB radiation without the need to include chemical UV screening agents in the composition.

Visibly transparent UV photoprotective compositions

A broad-spectrum UV photoprotective composition is described. The composition is characterized in that the composition comprises mesoporous zinc oxide aggregates having an average aggregate size of at least 0.8 microns dispersed in a carrier and the composition is visibly transparent. Sufficient zinc oxide is included in the composition to achieve an SPF greater than 15, greater than 25, greater than 30, or greater than 50.

PEDOT-coated counter electrodes for dye-sensitized solar cells

Poly(3,4-ethylenedioxythiophene) (PEDOT)-coated counter electrodes for dye-sensitized solar cells have been prepared at ambient temperature and without the use of iron-based oxidants, using an ionic liquid for the synthesis of the PEDOT. These electrodes show comparable electrocatalytic performance with conventional Pt-coated counter electrodes (solar cell efficiencies >7.5%).

On the role of cyclic unsaturated additives on the behaviour of lithium metal electrodes in ionic liquid electrolytes

Three cyclic vinyl based additives, based respectively on oxygen, sulphur and fluorine, are tested for their ability to improve the cycling of lithium in a hostile ionic liquid medium. Oxygen based vinylene carbonate is found to offer the best protection of the lithium metal whilst allowing very consistent lithium cycling to occur. The vinylene carbonate based system under study is, however, imperfect. Lithium metal is deposited in a dendritic morphology, and vinylene carbonate is rapidly consumed during lithium cycling if it is present in a small quantity. Our results suggest that ionic liquid systems critically relying on a small amount of additive to protect a lithium electrode are not viable for long cycle life secondary batteries. It is suggested that an ionic liquid which itself is lithium metal compatible be used instead.

Transparent uv-shielding films from organic small molecule-intercalated layered double hydroxide nanoplatelets/polymer composite

In this study, layered double hydroxide (LDH) with nitrate as the interlayer anion has been partially exfoliated in dimethyl sulfoxide (DMSO). Atomic force microscopy (AFM) images showed that both the lateral size and the thickness of the LDH nanoplatelets were decreased after DMSO treatment. Formation of transparent LDH suspension in DMSO was observed. Taking this advantage, we have prepared transparent LDH/ethylene-vinyl alcohol copolymer (EVOH) nanocomposite films using DMSO as the processing solvent. Organic small molecules, UV absorbers, were intercalated into the LDH interlayers to incorporate the UV-shielding property into the transparent composite films. The thermal stability of UV absorbers was considerably improved after intercalation, which was attributed to the electrostatic interaction between the guest UV absorbers and the host LDH layers. The prepared composite films were flexible and exhibited excellent UV-shielding capability, but had transmittance as high as 90% in the visible region. The effect of LDH filler on thermal and mechanical properties of the composite films was also examined.