Removal of ametryn using membrane bioreactor process and its influence on critical flux

Compared to the Conventional Activated Sludge Process (ASP), Membrane Bioreactors (MBRs) have proven their superior performance in wastewater treatment and reuse during the past two decades. Further, MBRs have wide array of applications such as the removal of nutrients, toxic and persistent organic pollutants (POPs), which are impossible or difficult to remove using ASP. However, fouling of membrane is one of the main drawbacks to the widespread application of MBR technology and Extra-cellular Polymeric Substances (EPS) secreted by microbes are considered as one of the major foulants, which will reduce the flux (L/m2/h) through the membrane. Critical flux is defined as the flux above which membrane cake or gel layer formation due to deposition of EPS and other colloids on the membrane surface occurs. Thus, one of the operating strategies to control the fouling of MBRs is to operate those systems below the critical flux (at Sub-Critical flux). This paper discusses the critical flux results, which were obtained from short-term common flux step method, for a lab-scale MBR system treating Ametryn. This study compares the critical flux values that were obtained by operating the MBR system (consisting of a submerged Hollow-Fibre membrane with pore size of 0.4μm and effective area of 0.2m2) at different operating conditions and mixed liquor properties. This study revealed that the critical flux values found after the introduction of Ametryn were significantly lower than those of obtained before adding Ametryn to the synthetic wastewater. It was also revealed that the production of carbohydrates (in SMP) is greater than proteins, subsequent to the introduction of Ametryn and this may have influenced the membrane to foul more. It was also observed that a significant removal (40-60%) of Ametryn from this MBR during the critical flux determination experiments with 40 minutes flux-step duration.

The use of artificial biofilms to strip nutrients from an industrial smelters waste water under conditions of low temperature and high pH

The Victorian Environment Protection Authority (EPA) has identified Alcoa’s Point Henry aluminium smelter as being a major source of recognized pollutant input due to its disposal of effluent into Corio Bay. Historically, the water quality parameters that have most often exceeded Point Henry’s EPA limits have been pH and suspended solids from the smelter’s discharge points. These waste water discharges also experience high nitrogen and phosphorus concentrations which result in algal blooms that occur at the onset of warm weather. The main hypothesis of this study was that “prevention of algal blooming with the onset of warm weather by removal of nutrients during the cooler months, and continued removal thereafter, is better than curing the problems chemically”. Biofilms have been used to remove nutrients from waste waters, but not under the conditions experienced at Point Henry. The aim of this study, therefore, was to determine if significant biofilm growth would be observed on floating structures suspended in the Point Henry waste water stream during the cooler, winter months of the year. Statistically significant biofilm growth occurred on all suspended structures in all discharge ponds during the winter and early spring of 2000. The use of suspended structures, such as AquaMatTM, as an artificial substrate to attract and support periphyton and bacterial communities (biofilms), which are then able to out-compete phytoplankton communities for available nutrients, is therefore a viable option for the Point Henry smelter. However, further research on the competitive performance of biofilms in the Point Henry ponds during the summer months is required before adequate biofilm management strategies can be developed.

Sustainable aquaculture through water recycling

The discharge of nutrient rich effluent from aquaculture systems into coastal waters is cause for concern. Direct filtration of aquaculture wastewater, using floating medium and sand with in line flocculation, and biological filtration using activated carbon, has the potential to improve water quality for recycling within aquaculture systems. This study looked at the performance of laboratory scale dual media and activated carbon filters in suspended solids and nutrient removal in the treatment of aquaculture wastewater. The dual media filter, with flocculant FeCl3 of 9mg/L, functioned best at a velocity of 7mJh with low headloss, and good turbidity and phosphorus removal (80% and 53% respectively). The activated carbon filter removed ammonia (84%) and nitrite (71 %) in the process of nitrification with a five-hour hydraulic retention time. This paper reports preliminary results from a longer term sustainable aquaculture project.

Biodegradation of pentachlorophenol in a membrane bioreactor

Pentachlorophenol (PCP) is a toxic chemical, often used in the formulation of pesticide, herbicide, anti fungal agent, bactericide and wood preservative. This study is aimed at evaluating the potential of membrane bioreactor (MBR) to treat PCP contaminated wastewater. Synthetic wastewater with COD of 600 mg/L was fed into the MBR at varied PCP loading rate of 12–40 mg/m3/d. A PCP removal rate of 99% and a COD removal rate of 95% were achieved at a hydraulic retention time of 12 hs and a mixed liquor suspended solids (MLSS) concentration of 10,000 mg/L. When sodium pentachlorophenol (NaPCP), which has higher solubility in water, was used in the second phase of the study, at loading rates varying from 20 to 200 mg/m3·d, the removal rate of NaPCP was higher than 99% and the removal rate of COD was more than 96%. It was also found that at higher biomass concentrations, biosorption played an important role besides the biodegradation process. Batch experiments conducted in this study revealed that the sorption capacity to be 0.63 (mg PCP/g biomass) and occurred rapidly within 60 min. This phenomenon could enhance the PCP degradation through increased contact between microorganism and PCP. Further, the membrane resistance was low (trans-membrane pressure of 14 kPa) even after more than 100 ds of operation. In addition, the toxic level of PCP in the influent could have induced the microorganisms to secrete more extra-cellular polymeric substances (EPS) for their protection, which in turn must have increased the viscosity of the mixed liquor.

Performance of an oxidation ditch retrofitted with a membrane bioreactor during the start-up

The objective of this study is to elucidate the full-scale characteristics of an oxidation ditch (OD) retrofitted with a membrane bioreactor (MBR). Domestic wastewater entering an oxidation ditch at a flow rate of 86 m3/d was directed to a MBR retrofitted into the original secondary sedimentation tank. The MBR contained flat sheet membranes. The data collected for 2 months during the start-up of the system showed that pH was maintained at 7.2 and 6.7 in OD and MBR, respectively. Dissolved oxygen (DO) in MBR remained stable at 7.8 mg/L, while fluctuated in OD. The mixed liquor suspended solids (MLSS) in the OD remained steady at a concentration about 1000 mg/L, but it was gradually building up from 500 mg/L to 2400 mg/L in the MBR during this period. Measurements of carbohydrate and protein were made by extracting the extra cellular polymeric substances (EPS) with sodium hydroxide (NaOH) from the mixed liquor obtained from both OD and MBR. Carbohydrate was predominant in the EPS and the ratios between carbohydrate and protein converged to fixed values from the fourth week; in this case the ratio was 4.5 for OD and 5 for MBR. The variation in EPS contents showed similar trends in both OD and MBR. The integrated treatment facility removed ammonia, COD and BOD at 100, 91.6 and 97.0%, respectively. However, efficiency of nitrate and phosphate removal has not been realized yet.

Mathematical modelling of downflow floating medium filter (DFF) with in-line flocculation arrangement

A laboratory-scale set-up consisting of rapid mixing device and floating medium filter was used to study the use of a downflow floating medium filter (DFF) with an in-line flocculation arrangement as a static flocculator and a prefilter. The semi-empirical mathematical model formulated incorporates flocculation within the filter, particle/floc attachment onto the filter and the detachment of flocs from the medium. The mathematical model for filtration takes into account the expansion of the filter bed. The removal efficiency of DFF and headless development were successfully simulated for different conditions of filtration velocity, filter depth and influent suspended solids (SS). The values of attachment coefficient a(p)β and headless coefficient β1 were found to be independent of filtration velocity, filter depth and influent SS concentration.

Performance of the Giant Reed (Arundo donax) in experimental wetlands receiving variable loads of industrial stormwater

Two emergent macrophytes, Arundo donax and Phragmites australis, were established in experimental subsurface flow, gravel-based constructed wetlands (CWs) and challenged by untreated stormwater collected from the hard-pan and other surfaces of a dairy processing factory in south-west Victoria, Australia. The hydraulic loading rate was tested at two levels, sequentially, 3.75 and 7.5 cm day -1. Some of the monitored variables were removed more efficiently by the planted beds in comparison to unplanted CWs (biochemical oxygen demand (BOD), total nitrogen (TN) and total phosphorus (TP); p<0.007) but there was no significant difference between the A. donax and P. australis CWs in removal of BOD, suspended solids (SS) and TN (p>0.007) at 3.75 cm day -1 or SS and TN at 7.5 cm day -1. At 3.75 cm day -1, BOD, SS, TN and TP removal in the A. donax and P. australis CWs was 71%, 61%, 78% and 75% and 65%, 60%, 73% and 41%, respectively. Nutrient removal at 7.5 cm day -1 in the A. donax and P. australis beds was 87%, 91%, 84% and 71% and 96%, 94%, 87% and 55%, respectively. As expected, the A. donax CWs produced considerably more biomass (10±1.2 kg wet weight) than the P. australis CWs (2.7±1.2 kg wet weight). This equates to approximately 107 and 36 tonnes ha -1 year -1 biomass (dry weight) for A. donax and P. australis, respectively (assuming 250 days of growing season and singlecut harvest). The performance similarity of the A. donax- and P. australis-planted CWs indicates that either may be used in HSSF wetlands treating dairy factory stormwater, although the planting of A. donax provides additional opportunities for secondary income streams through utilisation of the biomass produced.

Evaluation of the giant reed (Arundo donax) in horizontal subsurface flow wetlands for the treatment of dairy processing factory wastewater

Two emergent macrophytes, Arundo donax and Phragmites australis, were established in experimental horizontal subsurface flow (HSSF), gravel-based constructed wetlands (CWs) and challenged by treated dairy processing factory wastewater with a median electrical conductivity of 8.9 mS cm−1. The hydraulic loading rate was tested at 3.75 cm day−1. In general, the plants grew well during the 7-month study period, with no obvious signs of salt stress. The major water quality parameters monitored (biological oxygen demand (BOD), suspended solids (SS) and total nitrogen (TN) but not total phosphorus) were generally improved after the effluent had passed through the CWs. There was no significance different in removal efficiencies between the planted beds and unplanted gravel beds (p > 0.007), nor was there any significant difference in removal efficiencies between the A. donax and P. australis beds for most parameters. BOD, SS and TN removal in the A. donax and P. australis CWs was 69, 95 and 26 % and 62, 97 and 26 %, respectively. Bacterial removal was observed but only to levels that would allow reuse of the effluent for use on non-food crops under Victorian state regulations. As expected, the A. donax CWs produced considerably more biomass (37 ± 7.2 kg wet weight) than the P. australis CWs (11 ± 1.4 kg wet weight). This standing crop equates to approximately 179 and 68 tonnes ha−1 year−1 biomass (dry weight) for A. donax and P. australis, respectively (assuming a 250-day growing season and single-cut harvest). The performance similarity of the A. donax and P. australis planted CWs indicates that either may be used in HSSF wetlands treating dairy factory wastewater, although the planting of A. donax provides additional opportunities for secondary income streams through utilisation of the biomass produced.

Storm water harvesting and reuse in Australia : enhanced sand filtration for the treatment of storm water

This study details the removal of common storm water pollutants along with heavy metals by enhanced sand filtration. Three filtration flow rates were trialled: 5, 10 and 20 m/h. The performance of each filter was rated on the ability to remove turbidity, suspended solids, dissolved solids, phosphorus, nitrogen, lead, copper and Zinc. Conventional sand filter was used as a performance benchmark, and compared with four sand filters that are enhanced with a nylon carpet fibre, polypropylene carpet fibre, Syrian carpet fibre-enhanced and alum sludge-enhanced sand filter. Carpet fibre-enhanced sand filtration was highly effective at filtering simulated storm water and in most cases performing well above the conventional sand filters. The carpet fibre-enhanced sand filters had no drop in flow rates over the 4 h filtration period with following removal rates: up to 90% total suspended solids, 70% zinc, 60% turbidity, 25% phosphorus, 15% nitrogen and 10% total dissolved solids. However, results showed that alum sludge-enhanced sand filter performed the highest, with removal rates up to 100% for total suspended solids, 80% zinc, 90% turbidity, up to 80% phosphorus, up to 40% nitrogen and 3% total dissolved solids. But the flow rates dropped approximately two-thirds of the original flow rates within the first hour. © 2014 © 2014 Balaban Desalination Publications. All rights reserved.

Reuse of car wash wastewater by chemical coagulation and membrane bioreactor treatment processes

Car wash wastewater contains significant concentrations of contaminants such as nutrients, organics, particulate matter, sand, oil, grease, diesel detergents and so on. A range of treatment processes such as a membrane bioreactor (MBR), coagulation and ozonation were investigated to treat car wash wastewater. Ozonation was effective in removing the chemicals and suspended solids; the removal efficiency was greater than the coagulation process. Once the MBR system was acclimatised, 100% of suspended solids, 99.2% of COD, 97.3% of TOC and 41% of ammonia were removed. This study demonstrates that MBR is a potentially promising treatment system for recycling car wash wastewater which could be reused in the same car wash station.

Spatial analysis of urban stormwater quality

Urban stormwater non-point source pollutants are recognized as a major cause of receiving waters quality deterioration. To date most research has focused on specifying temporal variations of stormwater quality parameters which includes high uncertainties and also increases the risk of pollution control structures failure. Traditionally, the temporal variations of quality parameters in forms of either pollutograph or Event Mean Concentration (EMC) is obtained by sampling stormwater at the outlet of urban catchments for quality analysis in addition to measurement of flow rate over years. Spatial variations of the runoff quality are the key factor in non-point source pollution studies. This research investigates spatial variability of urban runoff quality parameters such as Total Phosphorous (TP), Total Nitrogen (TN), Suspended Solids (SS) and Biochemical Oxygen Demands (BOD) in relation to land use of urban catchments. In spatial analysis, stormwater will be sampled over the whole catchment area for a number of rainfall events during a year without any requirement to measure flow rate. This research showed comparable results for average pollutant concentrations with those of other urban catchments in Australia where traditional sampling method was used. The research outcomes will reliably estimate pollutants concentration for improved and efficient design of pollution control structures for each land use.

Experimental study of abattoir wastewater treatment from an economic perspective

The most cost effective treatment scheme for effluent from Midfield Meats, an abattoir in Warrnambool, Australia, was evaluated via a series of laboratory and commercial scale experiments. Effectiveness was measured in terms of suspended solids (SS) and biological oxygen demand (BOD) reduction. Economic assessment was based on predicted reduction in trade waste charges versus infrastructure and running costs. From the range of potential treatment technologies, those deemed most appropriate for trialling included pre-screening, sedimentation, coagulation and flocculation treatment and dissolved air floatation (DAF). Prior to evaluation of treatment types, flow, loads and contaminant characterisation of the waste streams was conducted to aid in selection of treatment type and capacity. Prescreening was found to be the most cost effective, followed by sedimentation, coagulation and flocculation treatment and finally DAF. The most economical treatment scheme that satisfied the requirements of Midfield Meats included a combination of prescreening and sedimentation. DAF and coagulation and flocculation treatment satisfactorily treated the wastewater, however were not cost effective under the current trade waste agreement.