A medium-temperature solar thermal power system and its efficiency optimisation

This paper firstly expounds that the reheat-regenerative Rankine power cycle is a suitable cycle for the parabolic trough collector, a popular kind of collector in the power industry. In a thermal power cycle, the higher the temperature at which heat is supplied, the higher the efficiency of the cycle. On the other hand, for a given kind of collector at the same exiting temperature, the higher the temperature of the fluid entering the collector, the lower the efficiency of the collector. With the same exiting temperature of the solar field and the same temperature differences at the hottest end of the superheater/reheater and at the pinch points in the heat exchangers (e.g., the boiler) in the cycle, the efficiencies of the system are subject to the temperature of the fluid entering the collector or the saturation temperature at the boiler. This paper also investigates the optimal thermal and exergetic efficiencies for the combined system of the power cycle and collector. To make most advantage of the collector, the exiting fluid is supposed to be at the maximum temperature the collector can harvest. Hence, the thermal and exergetic efficiencies of the system are related to the saturation temperature at the boiler here.

Organic ionic plastic crystal electrolytes; a new class of electrolyte for high efficiency solid state dye-sensitized solar cells

Dye-sensitized solar cells are an increasingly promising alternative to conventional silicon solar cells as a method of converting solar energy to electricity and thus providing an effectively inexhaustible energy source. However, the most efficient of these devices currently utilize liquid electrolytes, which suffer from the associated problems of leakage and evaporation. Hence, significant research is currently focused on the development of solid state alternatives. Here we report a new class of solid state electrolyte for these devices, organic ionic plastic crystal electrolytes, that allow relatively rapid diffusion of the redox couple through the matrix, which is critical to the cell performance. A range of different organic ionic plastic crystal materials, utilizing different cation and anion structures, have been investigated and the conductivities, diffusion rates and photovoltaic performance of the electrolytes are reported. The best material, utilizing the dicyanamide anion, achieves efficiencies of more than 5%.

Improved efficiency and stability of flexible dye sensitized solar cells on ITO/PEN substrates using an ionic liquid electrolyte

Flexible dye-sensitized solar cells (DSSCs) built on plastic substrates have attracted great interest as they are lightweight and can be roll-to-roll printed to accelerate production and reduce cost. However, plastic substrates such as PEN and PET are permeable to water, oxygen and volatile electrolyte solvents, which is detrimental to the cell stability. Therefore, to address this problem, in this work, an ionic liquid (IL) electrolyte is used to replace the volatile solvent electrolyte. The initial IL-based devices only achieved around 50% of the photovoltaic conversion efficiency of the cells using the solvent electrolyte. Current-voltage and electrochemical impedance spectroscopy (EIS) analysis of the cells in the dark indicated that this lower efficiency mainly originated from (i) a lack of blocking layer to reduce recombination, and (ii) a lower charge collection efficiency. To combat these problems, cells were developed using a 12 nm thick blocking layer, produced by atomic layer deposition, and 1 μm thick P25 TiO2 film sensitized with the hydrophobic MK-2 dye. These flexible DSSCs utilizing an IL electrolyte exhibit significantly improved efficiencies and a <10% drop in performance after 1000 h aging at 60°C under continuous light illumination.

A solar collector with the absorber divided by rectangular slots

A new solar absorber structure has been proposed and studied in this paper. The metal tubes running perpendicular to a set of parallel rectangular metal fins make the solar absorber with rectangular slots. Studies on the collector were theoretically carried out in the aspects of heat transfer, thermodynamics and . hydrodynamics. The calculating methods for calculating fin efficiency F and efficiency factors of the collector F' were obtained. The results showed that the new solar collector would have the higher efficiency and better performance at higher fluid temperature than that of the traditional flat-plate collectors. A collector prototype with the new structure was built and tested. The testing results agree with our theoretical results.

Solar photocatalytic oxidation (PCO) process with a flat-plate reactor

An experimental rig with a flat-plate solar reactor was built to study the effectiveness of degradation using the reactive methylene blue as sensitive objective. The factors that affect the degradation performance, such as dosages of photocatalyst (Ti0₂), initial concentration of reactive methylene blue, flow rate through the flat-plate reactor, solar UV radiation intensity and decolourising efficiency of the solution, have been investigated. The results showed that the solar PCO process with a Flat-plate Reactor could degrade the methylene blue and decolour in methylene blue solution efficiently.

The effect of colour on the thermal performance of building integrated solar collectors

The use of solar collectors with coloured absorbers for water heating is an area of particular interest when considering their integration with buildings. By matching the absorber colour with that of the roof or façade of the building, it is possible to achieve an architecturally and visually pleasing result. Despite the potential for the use of coloured absorbers, very little work has been undertaken in the field.

In this study, the thermal performance of a series of coloured (ranging from white to black), building integrated solar collectors for water heating was examined both theoretically and experimentally. Subsequently, the annual solar fraction for typical water heating systems with coloured absorbers was calculated. The results showed that coloured solar collector absorbers can make noticeable contributions to heating loads. Furthermore, although their thermal efficiency is lower than highly developed selective coating absorbers, they offer the advantage of improved aesthetic integration with buildings.

Effect of load pattern on solar-boosted heat pump water heater performance

The performance of a solar-boosted heat pump water heater (HPWH) operating under full load and part load conditions was determined in an outdoor experimental study. The system utilised flat unglazed aluminium solar evaporator panels to absorb solar and ambient energy. Absorbed energy was transferred to the water tank by means of the heat pump and a wrap around condenser coil on the outside of the tank. The system COP was found to be in the range of 5–7 under clear daytime conditions and 3–5 under clear night-time conditions. Using part load testing of the HPWH system it was found that concentrating the coils in the lower portion of the tank could increase the efficiency of the condenser coil. It was also shown that there exists a generalised linear relationship that can be used to describe the system COP in terms of the temperature difference between the water in the storage tank and the ambient air.

Application of the Hottel-Whillier equations to the analysis of a building integrated photovoltaic/thermal solar collector

The idea of combining photovoltaic and solar thermal collectors (PVT collectors) to provide electrical and heat energy is not new, however it is an area that has received only limited attention. With concern growing over energy sources and their usage, PVTs have become an area receiving more attention. Although PVTs are not as prevalent as solar thermal systems, the integration of photovoltaic and solar thermal collectors into the walls or roofing structure of a building could provide greater opportunity for the use of renewable solar energy technologies in domestic, commercial and industrial applications. As such, the design of a novel building integrated photovoltaic/thermal (BIPVT) solar collector is theoretically analysed through the use of a modified Hottel-Whillier model. The thermal and electrical efficiency under a range of conditions are subsequently determined and results showing how key design parameters influence the performance of the BIPVT system are presented.

Improved electrical efficiency by active cooling of building integrated photovoltaic panels

The electrical efficiency of photovoltaic devices can be directly related to the temperature of the photovoltaic cells.Tn this study a BIPVT solar collector was analysed and key parameters affecting its electrical efficiency were identified.

Solar thermal aided power generation

Fossil fuel based power generation is and will still be the back bone of our world economy, albeit such form of power generation significantly contributes to global CO2 emissions. Solar energy is a clean, environmental friendly energy source for power generation, however solar photovoltaic electricity generation is not practical for large commercial scales due to its cost and high-tech nature. Solar thermal is another way to use solar energy to generate power. Many attempts to establish solar (solo) thermal power stations have been practiced all over the world. Although there are some advantages in solo solar thermal power systems, the efficiencies and costs of these systems are not so attractive. Alternately by modifying, if possible, the existing coal-fired power stations to generate green sustainable power, a much more efficient means of power generation can be reached. This paper presents the concept of solar aided power generation in conventional coal-fired power stations, i.e., integrating solar (thermal) energy into conventional fossil fuelled power generation cycles (termed as solar aided thermal power). The solar aided power generation (SAPG) concept has technically been derived to use the strong points of the two technologies (traditional regenerative Rankine cycle with relatively higher efficiency and solar heating at relatively low temperature range). The SAPG does not only contribute to increase the efficiencies of the conventional power station and reduce its emission of the greenhouse gases, but also provides a better way to use solar heat to generate the power. This paper presents the advantages of the SAPG at conceptual level.

Multi-point and multi-level solar integration into a conventional coal-fired power plant

Solar-aided power generation (SAPG) is capable of integrating solar thermal energy into a conventional thermal power plant, at multi-points and multi-levels, to replace parts of steam extractions in the regenerative Rankine cycle. The integration assists the power plant to reduce coal (gas) consumption and pollution emission or to increase power output. The overall efficiencies of the SAPG plants with different solar replacements of extraction steam have been studied in this paper. The results indicate that the solar thermal to electricity conversion efficiencies of the SAPG system are higher than those of a solar-alone power plant with the same temperature level of solar input. The efficiency with solar input at 330 °C can be as high as 45% theoretically in a SAPG plant. Even the low-temperature solar heat at about 85 °C can be used in the SAPG system to heat the lower temperature feedwater, and the solar to electricity efficiency is nearly 10%. However, the low-temperature heat resource is very hard to be used for power generation in other types of solar power plants. Therefore, the SAPG plant is one of the most efficient ways for solar thermal power generation.

Dye-sensitized nanocrystalline solar cells incorporating ethylmethylimidazolium-based ionic liquid electrolytes

High-performance dye-sensitized solar cells incorporating electrochemically stable non-volatile electrolytes are especially desirable devices. In particular, ionic liquid systems based on ethylmethylimidazolium dicyanamide seem to be promising for this purpose. These have triggered our interest in the properties of further ethylmethylimidazolium-based ionic liquids with anions which are close relatives of dicyanamide. In this study, the effect of three different anions, tricyanomethanide, dicyanamide and thiocyanate, on the performance of dye-sensitized solar cells have been investigated. Both the short circuit photocurrent and conversion efficiency are increased with decreasing viscosity of the ionic liquids under comparable conditions. A conversion efficiency of 2.1% at 30% light intensity was observed for the cell containing the tricyanomethanide salt, which has lowest viscosity among the three ionic liquids, while efficiencies of 0.7% and 1.7% at the same light intensity were observed in the case of dicyanamide and thiocyanate salts, respectively, as an electrolyte.

Performance of building integrated solar hot water systems

The integration of solar energy systems into buildings has been the subject of considerable commercial and academic research, particularly building integrated photovoltaics. However, the integration of solar hot water systems into roofing systems has had far less attention. This paper presents the theoretical and experimental results of a novel building integrated solar hot water system developed using existing long run roofing materials.

This work shows that it is possible to achieve effective integration that maintains the aesthetics of the building and also provides useful thermal energy. The results of an unglazed 108m2 swimming pool heater and 8m2 glazed domestic hot water systems are presented.

The experimental results show that the glazed system performs close to the theoretical model and is an effective provider of hot water in certain climates. However it was also found that for larger scale building integrated solar water heating systems, special attention must be paid to the configuration and arrangement of the collectors in order to minimise problems with respect to flow distribution and its effect on collector and system efficiency.

In situ photopolymerization of a gel ionic liquid electrolyte in the presence of iodine and its use in dye sensitized solar cells

We report for the first time an in situ photopolymerization of model co-monomers, 2-hydroxyethyl methacrylate (HEMA) and tetra (ethylene glycol) diacrylate (TEGDA), in an IL electrolyte containing I₂ for DSSCs. TiO₂ nanoparticles were used as the photo-initiator and co-gelator in a charge transfer polymerization reaction. The gel-IL polymer obtained was characterized in terms of the diffusion properties of the electrolyte. Preliminary results from DSSCs assembled using the gel-IL electrolyte showed energy conversion efficiency of 3.9% at 1 sun (AM1.5) and 5.0% at 0.39 sun illumination.