A resonance tunable and durable LSPR nano-particle sensor : AL2O3 capped silver nano-disks

Localized surface plasmon resonance (LSPR) biosensors are employed to detect target biomolecules which have particular resonance wavelengths. Accordingly, tunability of the LSPR wavelength is essential in designing LSPR devices. LSPR devices employing silver nano-particles present better efficiencies than those using other noble metals such as gold; however, silver nano-particles are easily oxidized when they come in contact with liquids, which is inevitable in biosensing applications. To attain both durability and tunabilty in a LSPR biosensor, this paper proposes alumina (AL₂O₃) capped silver nano-disks. It is shown that through controlling the thickness of the cap, the LSPR resonance frequency can be finely tuned over a wide range; and moreover, the cap protects silver nano-particles from oxidation and high temperature.

Silver nanoparticles prepared by gamma irradiation across metal-organic framework templates

In this study, we demonstrate for the first time the successful fabrication of well-dispersed ultrafine silver nanoparticles inside metal-organic frameworks through a single step gamma irradiation at room temperature. HKUST-1 crystals are soaked in silver nitrate aqueous solution and irradiated with a Cobalt 60 source across a range of irradiation doses to synthesize highly uniformly distributed silver nano-particles. The average size of the silver nanoparticles across the Ag@HKUST-1 materials is found to vary between 1.4 and 3 nm for dose exposures between 1 and 200 kGy, respectively. The Ag@HKUST-1 hybrid crystals exhibit strong surface plasmon resonance and are highly durable and efficient catalytic materials for the reduction of 4-nitrophenol to 4-aminophenol (up to 14.46 × 10-3 s-1 for 1 kGy Ag@HKUST-1). The crystals can be easily recycled for at least five successive cycles of reaction with a conversion efficiency higher than 99.9%. The gamma irradiation is demonstrated to be an effective and environmental friendly process for the synthesis of nano-particles across confined metal-organic frameworks at room temperature with potential applications in environmental science.