Effects of fibre parameters on the ultraviolet protection of fibre assemblies

Ultraviolet (UV) radiation protection is becoming increasingly necessary for human health, and textiles play an important role. The interaction between UV light and textiles is a complex one, involving fibre, yarn and fabric parameters. In this study, an optical model is presented for examining the influences of fibre parameters on the UV protection offered by a bundle of fibres with a given mass. The effects of mean fibre diameter and fibre type on UV absorption were examined. The model was verified with results of UV–visible diffuse reflectance measurements on natural and synthetic fibres. When the mass of fibres was kept constant, within the measurement range in this study, a bundle of fibres with coarser fibres had a lower UV reflectance than that with finer ones. The model accurately predicted factors influencing UV protection, including fibre diameter, fibre transmittance, porosity and refractive index.

Research on the influence of yarn parameters on the ultraviolet protection of yarns

Considering both the yarn parameters and the light interaction (reflectance and transmittance) between two adjacent yarns, an optical model was presented to understand the ultraviolet (UV) light penetrating a single undyed yarn and a lot of yarns. The optical model was verified with results of diffuse reflectance spectra measurement on wool yarn samples. This optical model was used to predict the factors influencing UV protection, including fibre diameter, yarn linear density, yarn twist, transmittance index and refractive index. The statistical predictive model was also set up to show the relationship between the yarn parameters and the UV protection (UPF values) of the yarns. Yarns with the fine diameter, large yarn linear density and low yarn twist had the high UV protection.

UV interactions with fibres and fibrous structures

 In this research, the effects of fibre, yarn and fabric parameters on the UV protective properties were studied, and the results were interpreted by various developed models. An optimised knitted fabric for a lightweight spring/summer application with high UV protection and good thermal comfort was proposed from this systematic investigation.

Nano zinc oxide for UV protection of textiles

This paper describes the effect on the fading of dyed polyester fabrics in artificial sunlight, when the Ultra Violet (UV) component of the radiation was blocked by coating the fabric with zinc oxide nanoparticles, dispersed in an acrylic polymer. Zinc oxide is photoactive and generates superoxide and hydroxyl radicals (Reactive Oxygen Species; ROS) when irradiated with UV in the presence of oxygen and water. The results for the four dyes studied show that different dye chromophores interact differently with ROS. Selection of dyes with anti oxidant properties or addition of other anti oxidants may reduce the adverse effects of ROS

Polymer coatings containing nano particles of zinc oxide for the UV protection of dyed polyester fabrics

The useful life of many outdoor textile products is limited by degradation caused by exposure to sunlight, in particular by the ultra violet component (below 400 nm). The degradation results in fading of colours and also loss of physical properties, such as tear strength and abrasion resistance. Degradation can be decreased with UV absorbers, often used in conjunction with antioxidants or free radical quenchers. The protection afforded by these organic compounds is, however, limited as they are ultimately destroyed by the UV radiation they absorb.
An alternative approach is to coat fabrics with a polymer containing an inorganic UV absorber, such as zinc oxide. The inherent stability of zinc oxide would be expected to provide a protective effect over a much longer period than can be achieved with an organic UV absorber. A possible disadvantage of zinc oxide when applied in a polymer film is that absorption and scattering of visible light can produce hazy films and, hence, an unacceptable change in fabric appearance.
This poster paper examines the possibility of using nano particles of zinc oxide dispersed in acrylic polymers for protecting dyed polyester fabrics against sunlight fading. Factors affecting both UV absorbance and film clarity will be discussed. The possibility will also be examined that the protective effect may be reduced in some circumstances by reactive oxygen species, generated by the interaction of UV with zinc oxide in the presence of air and water.

Reduction of the photocatalytic activity of ZnO nanoparticles for UV protection applications

The detrimental effects of UV radiation are having a significant impact on our life and environment. The development of effective UV shielding agents is therefore of great importance to our society. ZnO nanoparticles are considered to be one of the most effective UV blocking agents. However, the development of ZnO-based UV shielding products is currently hindered due to the adverse effects of the inherent photocatalytic activity exhibited by ZnO. This paper reports our recent study on the possibility of reducing the photoactivity of ZnO nanoparticles via surface modification and impurity doping. It was found that the photoactivity was drastically reduced by SiO2-coatings that were applied to ZnO quantum dots using the Stöber method and a microemulsion technique. The effect of transition metal doping on the photoactivity was also studied using mechanochemical processing and a co-precipitation method. Cobalt doping reduced the photoactivity, while manganese doping led to mixed results, possibly due to the difference in the location of dopant ions derived from the difference in the synthesis methods.

The influence of yarn parameters on the ultraviolet protection of yarns

 Improving ultraviolet (UV) protection of textiles is essential to protect wearers against UV radiation induced risks. In addition to fabric parameters, yarn parameters are important factors affecting UV protection of textiles. This work is to examine the influence of yarn parameters on UV protection in order to set up a statistical model for predicting the UV protection of yarns. Wool yarns with different variables were used to test the ultraviolet protection factor (UPF) values for data analysis and the model verification. The model provides the optimized parameters for the UV protective fabric design. This work is helpful as a pre-cursor to the development of a more advanced optical model, which will look at understanding the penetration of UV light through fibres, yarns and fabrics.