The effect of solvent uptake on the relaxation behaviour, morphology and mechanical properties of a poly(ether ether ketone)/poly(etherimide) blend

The effects of solvent uptake on the relaxation behaviour, morphology and mechanical properties of poly(ether ether ketone) (PEEK), poly(etherimide) (PEI) and a 50/50 PEEK/PEI blend have been investigated. Amorphous films were immersed in acetone at 25°C, 35°C and 45°C until equilibrium uptake was achieved. The films were then examined by wide angle X-ray scattering (WAXS), differential scanning calorimetry (d.s.c.), dynamic mechanical relaxation spectroscopy and mechanical testing. WAXS and d.s.c. revealed that the degree of solvent induced crystallinity in PEEK is constant with immersion temperature, whereas the degree of induced crystallinity in the 50/50 blend is strongly temperature dependent. The dynamic mechanical studies confirmed that a significant decrease in glass transition temperature results from the plasticizing effect of the solvent and that solvent and thermally crystallized samples have different relaxation characteristics. Mechanical property tests showed that the yield stress and tensile strength of the blend are dominated by PEEK and the degree of crystallinity, while the modulus is more sensitive to the extent of plasticization.

Evaluation of the mechanical performance of short concrete column confined with CFRP and GFRP

Concrete has been successfully used to build strong and economic structures. However severe environmental exposures slowly deteriorate concrete strength until complete failure reducing its designed service life. Fiber Reinforced Polymer “FRP” has been recently introduced in the construction industry to strengthen and retrofitting several structural elements including columns. In this research two types of FRP have been used to wrap concrete column in order to increase its capacity; these are Carbon Fiber Reinforced Polymer “CFRP” and Glass Fiber Reinforced Polymer “GFRP”. Twelve short concrete columns have been wrapped with one and two FRP layers including CFRP and GFRP to evaluate their mechanical performance. Mechanical testing has shown that, in general, concrete columns wrapped with FRP produced higher modulus of elasticity compared to the control sample. Results showed that one layer of CFRP have 85.8% increases where as one layer of GFRP showed an increase of 64.5%. Furthermore, two layers of CFRP and GFRP showed 112.5% and 77.2% increase respectively.

Strain rate effects on the energy absorption of rapidly manufactured composite tubes

Quasi-static and intermediate rate axial crush tests were conducted on tubular specimens of Carbon/Epoxy (Toray T700/G83C) and Glass/Polypropylene (Twintex). The quasi-static tests were conducted at 10 mm/min (1.67 x 10¯⁴ m/s); five different crush initiators were used. Tests at intermediate rates were performed at speeds of 0.25, 0.5, 0.75, 1, 2, and 4m/s. Modes of failure and specific energy absorption (SEA) values were studied. The highest SEA measured was 86 kJ/kg. This value was observed using Carbon/Epoxy samples at quasi static rates with a 45° chamfer initiator. The highest energy absorption for Twintex tubes was observed to be 57.56 kJ/kg during 45° chamfer initiated tests at 0.25 m/s. Compared with steel and aluminium, SEA values of 15 and 30 kJ/kg, respectively, the benefits of using composite materials in crash structures become apparent.

Characteristics of electron beam welded Ti & Ti alloys

Similar and dissimilar butt joint welds comprising combinations of commercially pure grade 4 titanium (CP-Ti), Ti-6Al-4V (Ti-64) and Ti-5Al-5V-5Mo-3Cr (Ti-5553) were created using the electron beam process. The resultant welds were studied by means of metallography, optical microscopy, mechanical testing and scanning electron microscopy. Mechanical testing was performed on welded samples to study the joint integrity and fracture characteristics. A scanning electron microscope investigation was performed on the fracture surface to reveal their fracture modes. While all weldments were crack free and most weldments exhibited mechanical properties comparable to the base metal, negligible ductility was exhibited during tensile testing joints of Ti- 5553 welded to either Ti-64 or Ti-5553.

Variation of yield loci in finite element analysis by considering texture evolution for AA5042 aluminum sheets

 Yield function has various material parameters that describe how materials respond plastically in given conditions. However, a significant number of mechanical tests are required to identify the many material parameters for yield function. In this study, an effective method using crystal plasticity through a virtual experiment is introduced to develop the anisotropic yield function for AA5042. The crystal plasticity approach was used to predict the anisotropic response of the material in order to consider a number of stress or strain modes that would not otherwise be evident through mechanical testing. A rate-independent crystal plasticity model based on a smooth single crystal yield surface, which removes the innate ambiguity problem within the rate-independent model and Taylor model for polycrystalline deformation behavior were employed to predict the material’s response in the balanced biaxial stress, pure shear, and plane strain states to identify the parameters for the anisotropic yield function of AA5042.

Uniform elongation and the stress-strain flow curve of steels calculated from hardness using empirical correlations

An empirical relationship between the hardness and uniform elongation of non-Austenitic hypoeutectoid steels has been developed. This new hardness-elongation relationship was combined with previously developed correlations of hardness and strength (yield and ultimate tensile strength) to predict the stressstrain flow curve from a single hardness test. The current study considers both power law hardening behavior and exponential hardening behavior. Reasonable agreement was observed between the experimental and predicted flow curves of a high strength, low alloy steel. Additionally, an empirical correlation of the flow strength at instability with hardness is provided. © ASM International.

Thermomechanical properties of Ni-Ti shape memory wires containing nanoscale precipitates induced by stress-assisted ageing.

This paper systematically examines the thermomechanical properties and phase transformation behaviour of slightly Ni-rich Ni-Ti biomedical shape memory wires containing homogeneously distributed nanoscale precipitates induced by stress-assisted ageing. In contrast to previous studies, particular attention is paid to the role of precipitates in impeding twin boundary movement (TBM) and its underlying mechanisms. The size and volume fraction of precipitates are altered by changing the ageing time. The martensitic transformation temperatures increase with prolonged ageing time, whereas the R-phase transformation temperature remains relatively unchanged. The stress-strain behaviour in different phase regions during both cooling and heating is comprehensively examined, and the underlying mechanisms for the temperature- and thermal-history-dependent behaviour are elucidated with the help of the established stress-temperature phase diagram. The effect of precipitates on TBM is explored by mechanical testing at 133K. It is revealed that the critical stress for TBM (σcr) increases with increasing ageing time. There is a considerable increase of 104MPa in σcr in the sample aged at 773K for 120min under 70MPa compared with the solution-treated sample, owing to the presence of precipitates. The Orowan strengthening model of twinning dislocations is insufficient to account for this increase in σcr. The back stress generation is the predominant mechanism for the interactions between precipitates and twin boundaries during TBM that give rise to the increase in σcr. Such results provide new insights into the thermomechanical properties of precipitate containing Ni-Ti biomedical shape memory wires, which are instructive for developing high-performance biomedical shape memory alloys.

Strain partitioning in dual-phase steels containing tempered martensite

Tempering has been used as a method to develop a range of dual phase steels with the same martensite morphology and volume fraction, but containing phases with different relative strengths. These steels were used to examine the strain partitioning between the two constituent phases experimentally through mechanical testing and numerically through finite element modelling. It was found that increasing the differential in strength between the two phases not only produces regions of high strain, but also regions of low strain. On average, a larger difference in strength between the phases increased the strain carried by the softer phase. There was no discernible preferential strain localisation to the ferrite/martensite interface, with the regions of strain localisation being determined by the morphology of the microstructure. A direct correlation between the average strain in the ferrite, and the measured ductility has been found. © 2014 Elsevier B.V.

Computational inverse analysis of static recrystallization kinetics

© 2015 Published by Elsevier Ltd. All rights reserved. Accurate static recrystallization (SRX) models are necessary to improve the properties of austenitic steels by thermo-mechanical operations. This relies heavily on a careful and accurate analysis of "the interrupted test data" and conversion of the heterogeneous deformation data to the flow stress. A "computational-experimental inverse method" was presented and implemented here to analyze the SRX test data, which takes into account the heterogeneous softening of the post-interruption test sample. Conventional and "inverse" methods were used to identify the SRX kinetics for a model austenitic steel deformed at 1273 K (with a strain rate of 1 s-1) using the hot torsion test assess the merits of each method. Typical "static recrystallization distribution maps" in the test sample indicated that, at the onset of the second pass deformation with less than a critical holding time and a given pre-strain, a "partially-recrystallized zone" existed in the cylindrical core of the specimen near its center line. For the investigated scenario, the core was confined in the first half of the gauge radius when the holding time and the maximum pre strain were below 29 s and 0.5, respectively. For maximum pre strains smaller than 0.2, the specimen did not fully recrystallize, even at the gauge surface after holding for 50 s. Under such conditions, the conventional methods produced significant error.

Rapidly cured epoxy/anhydride composites: effect of residual stress on laminate shear strength

The drive towards rapid cure thermosetting composites requires a better understanding of the residual stresses that develop during curing. This study investigates the impact of residual stresses on the interlaminar shear strength of resin-infused epoxy/anhydride carbon-fibre laminates. The magnitude of the residual stress was varied by changing the initial injection cure temperature between 75 °C and 145 °C. The corresponding cycle times and the final glass transition temperature of the resin were also measured. The experimentally measured chemical shrinkage and thermal expansion properties of the resin after vitrification were used as inputs to a finite element analysis to calculate the peak residual stresses in the composite. An increase in the initial cure temperature from 85 to 135 °C resulted in an increase of 25% in the residual stress, which led to an experimentally measured reduction in the composite's short beam shear strength of approximately 16% (8 MPa), in good agreement with model prediction.

The mechanical characterization of low work hardening, high strength steel

One of the major challenges in assessing the mechanical properties of recovery annealed steel is the strain localization that occurs almost immediately on the formation of the first Lüders band, such that no or limited propagation of the Lüders band occurs along the tensile coupon. The stress raiser associated with the geometry of the standard tensile coupon means that this plastic deformation is often completely outside the standard extensometers on the coupon. Hence, no strain is measured during the test. While this is not important for assessing the tensile strength of the steel, it does mean that the strain related properties, such as the elastic limit of the steel, cannot be measured using standard testing techniques.This work addresses this issue by examining three techniques for ensuring that the strain occurs inside the extensometer. It is shown that the best technique is the extended extensometer, where the gauge length covers slightly more than the tensile coupon parallel length. While this leads to some variation in the width of the material being measured, compensation can be be made by adjusting the strain to correct the Young's Modulus.This technique has direct implications not just for recovery annealed steels, but for other high strength, low work hardening materials such as ultrafine ferrite. A particular requirement of these high strength steels in structural applications is a high elastic limit; hence, measurement of the strain related properties for these high strength materials must be considered vital in their mechanical assessment.

Nano- and macro-scale characterisation of the mechanical properties of bovine bone

In the present study, nano- and macro-scale characterisations on the mechanical properties of bovine cortical bones have been performed by using nanoindentation and conventional compressive tests. Nanoindentation results showed that the elastic modulus for the osteons and the interstitial lamellae in the longitude direction were 24.7 ± 2.5 GPa and 30.1 ± 2.4 GPa. As it’s difficult to distinguish osteons from interstitial lamellae in the transverse direction, the average elastic modulus for cortical bovine bone in the transverse direction was 19.8 ± 1.6 GPa. Significant differences were found in the modulus values between different microstructures of bone tissue and in different testing direction. It was found that the elastic modulus of bone bovine material in nano-level was higher than that in macro-level. The elastic modulus and
ultimate stress of large bone samples were 12.5 ± 1.9 GPa and 195 ± 19 MPa respectively from the compression test.

Fine grained AZ31 produced by conventional thermo-mechanical processing

The magnesium alloy AZ31 was processed by severe hot rolling and annealing. This processing was optimised to produce recrystallised grain sizes as small as 2.2 μm. The texture of the processed plate was similar to that of the as-received material, with a strong basal alignment in the normal direction. Tensile testing of the fine grained material showed an increase in the strength and elongation compared to the as-received plate. It is  concluded that the improved mechanical properties of the fine grained material results from a refinement in the grain size and the elimination of shear bands that pre-exist in the as-received material.